Carbon nanotube paper and preparation method thereof

A carbon nanotube paper, carbon nanotube technology, applied in paper, papermaking, textiles and papermaking, etc., can solve the problems of reducing carbon nanotube paper properties, poor mechanical properties, increasing costs, etc., to improve flexibility and bendability. , high cleanliness, stable structure

Active Publication Date: 2018-08-10
柔电(武汉)科技有限公司
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  • Application Information

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Problems solved by technology

And the traditional carbon nanotube paper has a fluffy structure and poor mechanical properties
According to the above deficiencies, many methods of making carbon paper come to the fore. As described in Chinese Patent Publication No. 106396680A, carbon tubes and dispersants are mixed in a solvent, ultrasonically dispersed, and then pulp is added for high-speed shear dispersion and mixing. Use ordinary papermaking process to shape, then carry out high-temperature modification treatment on carbon paper, then carry out carbonization treatment, and finally roll forming; another example is Chinese Patent Publication No. 102877367A, also first mix carbon tubes and dispersant, stir and disperse treatment, and then add Short fiber, high-speed shear dispersion, and then use tape-casting papermaking process to form, and finally take out the dispersant after post-processing to obtain the target product; there are many processes in this way, on the one hand, it increases the cost, on the other hand, the dispersant is easy to affect the carbon nanotubes conductivity, thereby reducing the performance of carbon nanotube paper

Method used

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  • Carbon nanotube paper and preparation method thereof
  • Carbon nanotube paper and preparation method thereof
  • Carbon nanotube paper and preparation method thereof

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preparation example Construction

[0035] The present invention also provides a kind of preparation method of above-mentioned carbon nanotube paper, and this method comprises the steps:

[0036] Step 1, dispersion: put carbon nanotubes in an alcohol solvent for ultrasonic dispersion to obtain a carbon nanotube dispersion; place chemical fibers in an alcohol solvent for high-speed dispersion to obtain a chemical fiber dispersion;

[0037] Step 2, mixing: mixing the chemical fiber dispersion and the carbon nanotube dispersion, and stirring at a high speed to obtain a uniform mixture;

[0038] Step 3, filtering: the mixed solution prepared in step 2 is placed in a corresponding filter device to filter, and carbon nanotube wet paper with uniform thickness is formed on the filter membrane;

[0039] Step 4, baking: Put the carbon nanotube wet paper and the filter membrane into the oven to bake to remove the solvent;

[0040] Step 5, tableting: peel the dried carbon nanotube paper from the filter membrane, and use a ...

Embodiment 1

[0052] Place carbon nanotubes in isopropanol solvent, the ratio of the mass (mg) of carbon nanotubes to the volume (mL) of isopropanol solvent is 0.01mg / mL, and disperse in the isopropanol solvent by ultrasonic method Carbon nanotubes, ultrasonic power 60W, ultrasonic time 0.5h; dissolve polyethylene fibers in isopropanol solvent, disperse at 5000rpm for 1h, the ratio of the mass (mg) of chemical fibers to the volume (mL) of isopropanol solvent is 0.1 mg / mL; the molecular weight of polyethylene fiber is 3×10 4 , 70 nanometers in diameter, 350 microns in length; after the dispersion, the two dispersions were mixed and stirred at a high speed at 5000 rpm for 1 hour to obtain a uniform mixture; in the mixture, the mass ratio of carbon nanotubes to polyethylene fibers was 98:2; Transfer the uniform mixed solution into the filter device for vacuum filtration. The pumping rate of the vacuum pump is 1L / s, and the filter membrane is a polyethylene filter membrane; after the suction fi...

Embodiment 2

[0054] Place carbon nanotubes in ethanol and ethylene glycol solvent, the volume ratio (mL) of ethanol to ethylene glycol is 1:2, the ratio of the mass (mg) of carbon nanotubes to the volume (mL) of alcohol mixed solvent is 0.5mg / mL, use ultrasonic method to disperse carbon nanotubes in the alcohol mixed solvent, ultrasonic power 100W, ultrasonic time 0.5h; dissolve polypropylene fiber in ethanol solvent, disperse at 6000rpm for 1.5h, chemical fiber mass (mg) The ratio to the volume (mL) of ethanol solvent is 1mg / mL, in which polyethylene fiber, molecular weight 20×10 4 , with a diameter of 50 nanometers and a length of 300 microns; after the dispersion, mix the two dispersions and stir at a high speed of 8000rpm for 0.5h to obtain a uniform mixture; in the mixture, the mass ratio of carbon nanotubes to polypropylene fibers is 99.5:0.5 ;Transfer the uniform mixed solution into the filter device for pressure filtration, the pressure is 2MPa, and the filter membrane is a polytet...

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Abstract

The invention belongs to the technical field of carbon nano materials, and particularly to carbon nanotube paper. The carbon nanotube paper comprises carbon nanotubes and chemical fibers. The invention also relates to a preparation method of the carbon nanotube paper, and the preparation method comprises the following steps: step one, placing the carbon nanotubes in an alcohol solvent, conductingultrasonic dispersion, placing the chemical fibers in an alcohol solvent, and conducting high-speed dispersion; step two, mixing the chemical fiber dispersion liquid with the carbon nanotube dispersion liquid to obtain a uniform mixed solution; step three, placing the uniform mixed solution in a corresponding filter device, conducting filtering, and forming carbon nanotube wet paper with uniform thickness on a filter membrane; step four, placing the carbon nanotube wet paper and the filter membrane into a drying oven together, and carrying out baking; and step five, stripping dried carbon nanotube paper from the filter membrane, and carrying out roll pressing by using a roller press. The carbon nanotube paper provided by the invention is low in cost, high in purity, and convenient in transfer; and the preparation method has few preparation processes, and is suitable for large-scale production.

Description

technical field [0001] The invention belongs to the technical field of carbon nanometer materials, in particular to a carbon nanotube paper and a preparation method thereof. Background technique [0002] Carbon nanotubes, also known as bucky tubes, are one-dimensional quantum materials with a special structure (the radial dimension is on the order of nanometers, the axial dimension is on the order of microns, and both ends of the tube are basically sealed). The carbon atoms arranged in hexagon form several to tens of layers of coaxial tubes. Carbon nanotubes have a very high aspect ratio structure, good electrical conductivity, excellent mechanical properties, and a large specific surface area. Carbon nanotubes can be regarded as curled graphene sheets, so they can be divided into single-walled carbon nanotubes and multi-walled carbon nanotubes according to the number of layers of graphene sheets. Commonly used carbon nanotube preparation methods mainly include: arc discha...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21J7/00D21H13/02D21H17/00
CPCD21H13/02D21H17/00D21J7/00
Inventor 吴迪胡韬解明
Owner 柔电(武汉)科技有限公司
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