Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Film-grade nylon 6 pellets and production method thereof

A production method and slicing technology, applied in the field of nylon 6 industrial production, can solve the problems of affecting storage and transportation, general filtration effect, prone to crystal point and membrane rupture, etc., and achieve high quality, avoid crystal point and membrane rupture.

Inactive Publication Date: 2018-09-28
ZHONGLUN PLASTIC IND FUJIAN
View PDF0 Cites 6 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The existing membrane-grade nylon 6 slices are prone to crystal points and membrane rupture during the film-drawing process. The reason is that the impurity components in the nylon 6 slices cannot meet the deformation requirements during the film-drawing process. These components are mainly cyclic dimers, Polymers, carbides and gels, etc.
During the film rolling process, the film products that are in contact with each other are easy to stick, which affects storage and transportation. Usually, a filter is added when the film is pulled, and the filtering effect is average, which affects the output.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Film-grade nylon 6 pellets and production method thereof
  • Film-grade nylon 6 pellets and production method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] The production method of membrane-grade nylon 6 chips comprises the following steps:

[0036] Step 1): crush the solid caprolactam and heat it to melt to obtain fresh caprolactam and send it to a large caprolactam storage tank; add 50% by weight of solid caprolactam to the extraction concentrate, stir and dissolve in the purification tank, and pump the external Circulation, the circulation system is equipped with a steam heat exchanger for heating, and a filter with a pressure difference alarm device is installed at the outlet of the pump to control the heating temperature of the steam heat exchanger to 120°C, and the pressure difference alarm device controls the pressure at 50kpa. A packed tower is installed on the top to remove moisture by condensation and reflux, and the water content of the mixture coming out of the purification kettle is controlled at 5% by weight, and the caprolactam content is 90% by weight. into the large storage tank of caprolactam; the homogen...

Embodiment 2

[0044] The preparation process of membrane-grade nylon 6 chips is the same as in Example 1, the difference is that step 1) adds 70% by weight of solid caprolactam to the extraction concentrate, the temperature heated by the steam heat exchanger is 140° C., and the differential pressure alarm device controls the pressure at 45-55kpa, the purified mixture is obtained from the purification kettle, the mixture from the purification kettle: the mass ratio of fresh caprolactam is 1:2, and sent to the large caprolactam storage tank to obtain liquid A, and the additives include 1% of the total weight of liquid A Chain terminator benzoic acid, the conventional nucleating agent accounting for 1% of the total weight of liquid A, and the anti-blocking agent active titanium dioxide accounting for 1% of the total weight of liquid A; the preheater is heated to 150°C in step 2), and the resulting material is sent to cracking Reactor, at 230 DEG C, under 200kpa, the material ring-opening and po...

Embodiment 3

[0046] The preparation process of membrane-grade nylon 6 slices is the same as in Example 1, the difference is that step 1) adds 30% by weight of solid caprolactam to the extraction concentrate, the temperature heated by the steam heat exchanger is 100°C, and the differential pressure alarm device controls the pressure at 45-55kpa, the water content of the mixture from the purification kettle is controlled at 15% by weight, and the purified mixture is obtained from the purification kettle. The mixture from the purification kettle: the fresh caprolactam mass ratio is 1:2 and sent to the caprolactam large storage tank. Obtain liquid A, additive comprises and accounts for the chain terminator benzoic acid of liquid A gross weight 0.03%, accounts for the conventional nucleating agent of liquid A gross weight 0.01%, accounts for the antiblocking agent talcum powder of liquid A gross weight 0.01%; step 2) The middle preheater is heated to 120°C, and the obtained material is sent into...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to film-grade nylon 6 pellets and a production method thereof. After a recovered extraction concentrated solution is purified, the extraction concentrated solution is mixed withsolid raw materials, homogenization is carried out, an additive is added, the mixture is preheated and then fed into a depolymerizing reactor using gas self-stirring, after high-temperature and high-pressure depolymerization, high-pressure prepolymerization and post-polymerization pressure reduction are carried out, after underwater pelletizing, extraction, drying and cooling are carried out, andthe film-grade nylon 6 pellets are obtained. The relative viscosity of the obtained film-grade nylon 6 pellets can be controlled to be 3.2+ / -0.030, the viscosity deviation can be controlled to be smaller than or equal to + / -0.030, and the content of hot-water extract is smaller than or equal to 0.3 wt%, wherein the content of cyclic dimer is smaller than or equal to 0.05 wt%, the content of residual water is smaller than or equal to 0.04 wt%, and the chromaticity is -5--3.5+ / -1, so that the film-grade nylon 6 pellets have high quality.

Description

technical field [0001] The invention relates to the industrial production technology of nylon 6, in particular to a film-grade nylon 6 slice and a production method thereof. Background technique [0002] With the rapid development of our country's economy, the per capita consumption level and living standard are increasing day by day, thus promoting the popularity of supermarkets and the rapid development of tourism, and the packaging consumption of various commodities has increased sharply. [0003] The BOPA biaxially stretched nylon 6 film made of nylon 6 is biaxially stretched during the film forming process, which strengthens the orientation of the molecular chain, increases the crystallinity, improves the mechanical properties, and the gloss, transparency and The gas barrier properties are improved accordingly, and the polymer molecules of BOPA film are in a plane orientation state, so compared with other packaging films, it has high puncture resistance, high rupture re...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C08G69/14C08G69/16
CPCC08G69/14C08G69/16
Inventor 简锦炽陈志强许爱林
Owner ZHONGLUN PLASTIC IND FUJIAN
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products