High ionic conductivity solid electrolyte and preparation method thereof as well as application of high ionic conductivity solid electrolyte in all-solid-state lithium ion battery
A technology of solid electrolyte and conductivity, which is applied to the preparation of solid electrolyte with high ion conductivity, solid electrolyte with high ion conductivity, and the application field of solid electrolyte with high ion conductivity in all solid-state lithium-ion batteries, which can solve the problem that solid-state batteries do not have Too many competitive advantages, large interface impedance, slow charging speed and other issues
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Embodiment 1
[0020] A solid electrolyte with high ionic conductivity, the solid electrolyte layer includes lithium salt, ceramic powder, adhesive and solvent, the mass ratio of lithium salt, ceramic powder, adhesive and solvent is 10:1:10:79 ;
[0021] The lithium salt is one or more of lithium hexafluorophosphate, lithium bistrifluoromethanesulfonylimide, lithium perchlorate, lithium tetrafluoroborate and lithium dioxalate borate, preferably bistrifluoromethanesulfonylimide lithium.
[0022] The ceramic particles include one or more of LiLaZrO, LiLaTiO, LiLaZrTaO, preferably LiLaZrO.
[0023] The adhesive is composed of one or more of polyacrylonitrile, polypropylene oxide, polysiloxane, polyvinylidene fluoride, polymethyl methacrylate and polyvinylidene fluoride-hexafluoropropylene , preferably polyvinylidene fluoride and polyvinylidene fluoride-hexafluoropropylene, wherein the mass ratio of polyvinylidene fluoride to polyvinylidene fluoride-hexafluoropropylene is 0.5:9.5.
[0024] Th...
Embodiment 2
[0033] A solid electrolyte with high ionic conductivity, the solid electrolyte layer includes lithium salt, ceramic powder, adhesive and solvent, the mass ratio of lithium salt, ceramic powder, adhesive and solvent is 2:4:2:90 ;
[0034] The lithium salt is one or more of lithium hexafluorophosphate, lithium bistrifluoromethanesulfonimide, lithium perchlorate, lithium tetrafluoroborate and lithium dioxalate borate, preferably lithium hexafluorophosphate.
[0035] The ceramic particles include one or more of LiLaZrO, LiLaTiO, and LiLaZrTaO, preferably LiLaTiO.
[0036] The adhesive is composed of one or more of polyacrylonitrile, polypropylene oxide, polysiloxane, polyvinylidene fluoride, polymethyl methacrylate and polyvinylidene fluoride-hexafluoropropylene , preferably polymethyl methacrylate.
[0037] The solvent is one of N-methylpyrrolidone, dimethylformamide, ethanol, ethyl acetate, preferably dimethylformamide.
[0038] A method for preparing a high-ionic-conductivit...
Embodiment 3
[0046] A solid electrolyte with high ionic conductivity, the solid electrolyte layer includes lithium salt, ceramic powder, adhesive and solvent, the mass ratio of lithium salt, ceramic powder, adhesive and solvent is 20:10:20:50 ;
[0047] The lithium salt is one or more of lithium hexafluorophosphate, lithium bistrifluoromethanesulfonimide, lithium perchlorate, lithium tetrafluoroborate and lithium dioxalate borate, preferably lithium tetrafluoroborate.
[0048] The ceramic particles include one or more of LiLaZrO, LiLaTiO, LiLaZrTaO, preferably LiLaZrTaO.
[0049] The adhesive is composed of one or more of polyacrylonitrile, polypropylene oxide, polysiloxane, polyvinylidene fluoride, polymethyl methacrylate and polyvinylidene fluoride-hexafluoropropylene , preferably polypropylene oxide.
[0050] The solvent is one of N-methylpyrrolidone, dimethylformamide, ethanol and ethyl acetate, preferably ethyl acetate.
[0051] A method for preparing a high-ionic-conductivity soli...
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