High ionic conductivity solid electrolyte and preparation method thereof as well as application of high ionic conductivity solid electrolyte in all-solid-state lithium ion battery

A technology of solid electrolyte and conductivity, which is applied to the preparation of solid electrolyte with high ion conductivity, solid electrolyte with high ion conductivity, and the application field of solid electrolyte with high ion conductivity in all solid-state lithium-ion batteries, which can solve the problem that solid-state batteries do not have Too many competitive advantages, large interface impedance, slow charging speed and other issues

Active Publication Date: 2018-10-09
SUZHOU QINGTAO NEW ENERGY TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the disadvantage of solid-state batteries is that the interface impedance between the solid-state electrolyte and the positive and negative electrodes is relatively large, resul

Method used

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  • High ionic conductivity solid electrolyte and preparation method thereof as well as application of high ionic conductivity solid electrolyte in all-solid-state lithium ion battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A solid electrolyte with high ionic conductivity, the solid electrolyte layer includes lithium salt, ceramic powder, adhesive and solvent, the mass ratio of lithium salt, ceramic powder, adhesive and solvent is 10:1:10:79 ;

[0021] The lithium salt is one or more of lithium hexafluorophosphate, lithium bistrifluoromethanesulfonylimide, lithium perchlorate, lithium tetrafluoroborate and lithium dioxalate borate, preferably bistrifluoromethanesulfonylimide lithium.

[0022] The ceramic particles include one or more of LiLaZrO, LiLaTiO, LiLaZrTaO, preferably LiLaZrO.

[0023] The adhesive is composed of one or more of polyacrylonitrile, polypropylene oxide, polysiloxane, polyvinylidene fluoride, polymethyl methacrylate and polyvinylidene fluoride-hexafluoropropylene , preferably polyvinylidene fluoride and polyvinylidene fluoride-hexafluoropropylene, wherein the mass ratio of polyvinylidene fluoride to polyvinylidene fluoride-hexafluoropropylene is 0.5:9.5.

[0024] Th...

Embodiment 2

[0033] A solid electrolyte with high ionic conductivity, the solid electrolyte layer includes lithium salt, ceramic powder, adhesive and solvent, the mass ratio of lithium salt, ceramic powder, adhesive and solvent is 2:4:2:90 ;

[0034] The lithium salt is one or more of lithium hexafluorophosphate, lithium bistrifluoromethanesulfonimide, lithium perchlorate, lithium tetrafluoroborate and lithium dioxalate borate, preferably lithium hexafluorophosphate.

[0035] The ceramic particles include one or more of LiLaZrO, LiLaTiO, and LiLaZrTaO, preferably LiLaTiO.

[0036] The adhesive is composed of one or more of polyacrylonitrile, polypropylene oxide, polysiloxane, polyvinylidene fluoride, polymethyl methacrylate and polyvinylidene fluoride-hexafluoropropylene , preferably polymethyl methacrylate.

[0037] The solvent is one of N-methylpyrrolidone, dimethylformamide, ethanol, ethyl acetate, preferably dimethylformamide.

[0038] A method for preparing a high-ionic-conductivit...

Embodiment 3

[0046] A solid electrolyte with high ionic conductivity, the solid electrolyte layer includes lithium salt, ceramic powder, adhesive and solvent, the mass ratio of lithium salt, ceramic powder, adhesive and solvent is 20:10:20:50 ;

[0047] The lithium salt is one or more of lithium hexafluorophosphate, lithium bistrifluoromethanesulfonimide, lithium perchlorate, lithium tetrafluoroborate and lithium dioxalate borate, preferably lithium tetrafluoroborate.

[0048] The ceramic particles include one or more of LiLaZrO, LiLaTiO, LiLaZrTaO, preferably LiLaZrTaO.

[0049] The adhesive is composed of one or more of polyacrylonitrile, polypropylene oxide, polysiloxane, polyvinylidene fluoride, polymethyl methacrylate and polyvinylidene fluoride-hexafluoropropylene , preferably polypropylene oxide.

[0050] The solvent is one of N-methylpyrrolidone, dimethylformamide, ethanol and ethyl acetate, preferably ethyl acetate.

[0051] A method for preparing a high-ionic-conductivity soli...

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Abstract

The invention discloses application of a high ionic conductivity solid electrolyte layer in an all-solid-state lithium ion battery. An assembling step of the battery comprises the following steps: cutting a composite positive electrode and a composite negative electrode which are coated with films, uniformly coating the composite positive electrode or the composite negative electrode with electrolyte slurry, laminating the composite positive electrode and the composite negative electrode, drying the electrodes by blast air, then drying the electrodes in vacuum, baking the electrodes, welding tabs, performing vacuum packaging and cold-thermal pressing to realize close connection between electrolyte layers, and completing preparation of the all-solid-state lithium ion battery. The application has the advantages that the surfaces of the composite positive and negative electrodes are coated with the high ionic conductivity solid electrolyte layer and then are dried and sliced, and the surface of the cut composite positive electrode or composite negative electrode is uniformly coated with the electrolyte layer; before baking, the positive and negative electrodes are assembled, then dried by the blast air and assembled into the battery; and by twice coating of the electrolyte slurry, the problem of a micro short circuit of the full-solid-state battery and the problem of a relativelyhigh interface impedance between the electrolyte and composite positive and negative pole pieces as well as between one electrolyte layer and the other electrolyte layer can be effectively solved.

Description

technical field [0001] The present invention relates to the field of lithium ion batteries, relates to a high ion conductivity solid electrolyte, designs a preparation method of a high ion conductivity solid electrolyte, and also relates to a high ion conductivity solid electrolyte in an all-solid lithium ion battery application. Background technique [0002] Lithium-ion battery has been widely used as an energy storage device in the digital field because of its high operating voltage, high energy density, non-toxic and non-polluting to the environment. Due to the rapid development of pure electric vehicles and hybrid electric vehicles, there are higher requirements for the energy density and safety of lithium-ion batteries. [0003] The electrolyte used in lithium-ion batteries widely used in the market is an organic liquid electrolyte, which also brings a series of problems. At present, the amount of liquid electrolyte used in liquid lithium-ion batteries is difficult to...

Claims

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Application Information

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IPC IPC(8): H01M10/0562H01M10/0565H01M10/0525
CPCH01M10/0525H01M10/0562H01M10/0565H01M2300/0065H01M2300/0085Y02E60/10
Inventor 李峥冯玉川何泓材陈玉华纪岩龙王明辉杨帆南策文
Owner SUZHOU QINGTAO NEW ENERGY TECH CO LTD
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