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PC/PMMA/PETG ternary alloy material and preparation method thereof

A ternary alloy and raw material technology, applied in the field of PC/PMMA/PETG ternary alloy material and its preparation, can solve the problems of abnormal water-marked silver wire injection molding, easy decomposition of small molecules, low bending elastic modulus, etc. Low cost, good practical prospects and social and economic benefits, the effect of improving bending elasticity

Active Publication Date: 2018-10-19
佛山国能钢业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, PC / PMMA alloy, which combines the excellent mechanical strength and high temperature resistance of PC, and the high gloss and scratch resistance of PMMA, is widely used in many industries such as automobiles and home appliances; Injection molding is easy to decompose small molecules, resulting in the occurrence of injection molding abnormalities such as water streaks, and severe stress cracking in low temperature environments, and is not resistant to corrosion by chemical solvents, which limits its application.
For example, in the PC / PETG alloy, PETG not only makes up for the shortcomings of PC's poor fluidity and easy stress cracking, but also solves the problem of PC's resistance to chemical solvents, and at the same time greatly reduces the cost of materials. However, due to the soft texture of PETG, it makes Insufficient rigidity of the alloy, low flexural modulus of elasticity, and high molding shrinkage rate limit its application range

Method used

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  • PC/PMMA/PETG ternary alloy material and preparation method thereof
  • PC/PMMA/PETG ternary alloy material and preparation method thereof
  • PC/PMMA/PETG ternary alloy material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] The preparation method of PC / PMMA / PETG ternary alloy material, it comprises the following steps:

[0034] Step 1) Weigh the raw material components according to the following mass percentages: polycarbonate 50.4%, polymethyl methacrylate 12.6%, polyethylene terephthalate-1,4-cyclohexanedimethanol 27% , ABS-g-MAH 3%, butadiene content greater than or equal to 55% ABS high rubber powder 3%, organic montmorillonite 3%, pentaerythritol 0.2%, styrene-acrylonitrile-glycidyl methacrylate copolymer 0.5% tetrakis[β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid]pentaerythritol ester 0.2%, tris(2,4-di-tert-butyl)phenyl phosphite 0.1%.

[0035] The polycarbonate is a high-molecular-weight polycarbonate resin recycled material after sorting, purification, crushing, cleaning, and drying. It does not contain flame retardants, and its melt index is ≤15g / 10min; the drying environment is 95°C, and the drying time is 1.5 hours.

[0036] The polymethyl methacrylate is an injection gr...

Embodiment 2

[0042] The preparation method of PC / PMMA / PETG ternary alloy material, it comprises the following steps:

[0043] Step 1) Weigh the raw material components according to the following mass percentages: polycarbonate 43.2%, polymethyl methacrylate 10.8%, polyethylene terephthalate-1,4-cyclohexanedimethanol 36% , AS-g-MAH 5%, methyl methacrylate-butadiene-styrene terpolymer 2%, fumed nano-silica 2%, glycerin 0.2%, styrene-acrylonitrile-methacrylic acid shrink Glyceride copolymer 0.5%, β-(3,5-di-tert-butyl-4-hydroxyphenyl) n-octadecyl propionate 0.2%, tris(2,4-di-tert-butyl)phenylphosphite Esters 0.1%.

[0044] The polycarbonate is a high-molecular-weight polycarbonate resin recycled material after sorting, purification, crushing, cleaning, and drying. It does not contain flame retardants, and its melt index is ≤15g / 10min; the drying environment is 95°C, and the drying time is 1.5 hours.

[0045] The polymethyl methacrylate is an injection grade polymethyl methacrylate resin reg...

Embodiment 3

[0051] The preparation method of PC / PMMA / PETG ternary alloy material, it comprises the following steps:

[0052] Step 1) Weigh the raw material components according to the following mass percentages: polycarbonate 37.8%, polymethyl methacrylate 16.2%, polyethylene terephthalate-1,4-cyclohexanedimethanol 36% , PS-g-MAH 4%, polyolefin thermoelastomer 1%, nano calcium carbonate 4%, glyceryl monostearate 0.2%, styrene-acrylonitrile-glycidyl methacrylate copolymer 0.5%, 0.2% n-octadecyl β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate, 0.1% trinonylphenyl phosphite.

[0053] The polycarbonate is a high-molecular-weight polycarbonate resin recycled material after sorting, purification, crushing, cleaning, and drying. It does not contain flame retardants, and its melt index is ≤15g / 10min; the drying environment is 95°C, and the drying time is 1.5 hours.

[0054] The polymethyl methacrylate is an injection grade polymethyl methacrylate resin regenerated material after sorting, purif...

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Abstract

The invention relates to a PC / PMMA / PETG ternary alloy material, which is prepared from the following raw materials by mass: 40-60% of polycarbonate, 10-30% of polymethyl methacrylate, 20-40% of polyethylene terephthalate-1,4-cyclohexanedimethanol ester, 1-10% of a compatibilizer, 1-10% of a toughening agent, 1-10% of a reinforcing agent, 0.1-1% of a polyhydroxyl chemical coupling agent, 0.1-2% ofa chain extender, and 0.1-0.5% of an antioxidant. According to the present invention, the PC / PMMA / PETG ternary alloy material has advantages of excellent comprehensive performance, organic solvent resistance, strong-acid corrosion resistance and strong-alkali corrosion resistance. The invention further relates to a preparation method of the PC / PMMA / PETG ternary alloy material.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a PC / PMMA / PETG ternary alloy material and a preparation method thereof. Background technique [0002] With the development of society, the application of polymer materials is becoming more and more extensive, and the amount of use is also increasing, and the resulting plastic waste is also increasing. The molecular structure of plastic resin materials is stable, and it is difficult to decompose naturally when discarded in nature, which seriously damages the ecological environment. Therefore, the recycling of plastic resin materials has increasingly received social attention. At present, the recycling of waste plastics is mostly based on the process of melting, extruding and granulating after simple sorting. This process relies too much on the purity of sorting, and the degradation of plastic resin materials will lead to large performance differences, resulting in the p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08L33/12C08L67/02C08K13/06C08K3/34C08K5/053C08K5/134C08K5/526C08K13/02C08K3/36C08K3/26C08K5/103
CPCC08L69/00C08K2003/265C08K2201/011C08L2205/035C08L33/12C08L67/02C08K13/06C08K3/346C08K5/053C08K5/1345C08K5/526C08K13/02C08K3/36C08K3/26C08K5/103C08K3/34Y02W30/62
Inventor 何礼俊陈楚芝
Owner 佛山国能钢业有限公司
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