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A kind of preparation method and application of urease gel microspheres used as urea scavenger

A technology of gel microspheres and scavengers, applied in biochemical equipment and methods, medical preparations containing non-active ingredients, medical preparations containing active ingredients, etc., to achieve uniform size, good safety, and good reusability Effect

Active Publication Date: 2021-07-27
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, most studies on the immobilization of urease focus on the catalytic activity of immobilized urease, and there are few reports on its application to the removal of urea in hemoperfusion.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] A preparation method for urease gel microspheres used as a urea scavenger, comprising the following steps:

[0051] 1. Take 9 parts of polyethersulfone and 90 parts of N,N-dimethylacetamide and mix them mechanically until the polyethersulfone is completely dissolved to obtain a mixed solution. Add 2 parts of acrylic acid and 0.15 parts of N- Vinylpyrrolidone, 0.03 part of initiator azobisisobutyronitrile (AIBN), 0.2 part of cross-linking agent N,N'-methylenebisacrylamide (MBA) to obtain a mixture; the above mixture is deoxygenated under nitrogen atmosphere 30min; then placed in an oil bath at 70°C under nitrogen atmosphere, with continuous mechanical stirring, reacted for 24h, then exposed to air to terminate the reaction, and finally a clear slightly yellow polymer solution was obtained.

[0052] 2. Transfer the polymer solution prepared above to a 10mL syringe, install the electrostatic ball spraying device, and through the action of voltage, make the polymer solution...

Embodiment 2

[0056] A preparation method of urease gel microspheres used as a urea scavenger, the preparation method consists of the following steps:

[0057] A. Preparation of polymer solution: using acrylic acid and N-vinylpyrrolidone as monomers, and in-situ cross-linking with polyethersulfone to prepare a polymer solution; the raw materials for preparing the polymer solution in the step A are as follows in parts by weight Component composition: 6 parts of polyethersulfone; 2 parts of acrylic acid; 0.3 part of N-vinylpyrrolidone; 0.02 part of initiator; 0.2 part of crosslinking agent and 86 parts of solvent; Polyethersulfone is dissolved in a solvent, and then acrylic acid, N-vinylpyrrolidone, initiator and crosslinking agent are added to the above polyethersulfone solution to form a reaction raw material solution; A2, the reaction raw material solution is placed in a nitrogen atmosphere After reacting for 24 hours at a constant temperature of 70° C. in an oil bath, a reaction solution ...

Embodiment 3

[0064] The difference between this example and Example 2 is that: the raw materials for preparing the polymer solution in the step A are composed of the following components in parts by weight: 12 parts of polyethersulfone; 2 parts of acrylic acid; 0.3 parts of N-vinylpyrrolidone; 0.02 part of initiator; 0.2 part of crosslinking agent and 92 parts of solvent; all the other are the same as Example 2.

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PUM

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Abstract

The invention belongs to the technical field of urea scavengers, and discloses a preparation method and application of urease gel microspheres used as urea scavengers. The preparation method consists of the following steps: A. Preparation of a polymer solution: using acrylic acid and N - Vinylpyrrolidone is a monomer, and in-situ cross-linking with polyethersulfone is carried out to prepare a polymer solution; B. Preparation of gel microspheres: the polymer solution is sprayed into a non-solvent to undergo a phase transition to form a gel microsphere; spheres; C. Preparation of urease gel microspheres: urease is fixed on the gel microspheres by chemical grafting to obtain urease gel microspheres. Use of the prepared urease gel microspheres as a urea scavenger. The urease gel microsphere of the present invention has good storage stability and good blood compatibility; does not cause coagulation reaction and the hemolysis rate is far lower than the international standard; in addition, the present invention does not cause other immune reactions, and has good safety sex.

Description

technical field [0001] The invention belongs to the technical field of urea scavengers, in particular to a preparation method and application of urease gel microspheres used as urea scavengers. Background technique [0002] Chronic renal failure is a syndrome in which the kidneys cannot purify the blood. This syndrome can lead to the accumulation of urinary toxins, endangering human health. In 2010, almost 600,000 Americans received a kidney transplant and 400,000 received dialysis, according to 2012 data from the United States Renal Database (USRDS). Due to the increasing number of patients with renal failure, the need for renal treatment is also increasing. Kidney transplantation may be the ultimate treatment for kidney failure, but it is limited by factors such as shortage of donors, immune rejection, and high treatment costs. Hemodialysis and hemoperfusion are commonly used methods for removing urea toxins. Urea is a major urea toxin and the main product of protein m...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A61K38/50A61K47/58A61K9/16A61P39/02A61P13/12
CPCA61K9/1635A61K38/50A61P13/12A61P39/02C12Y305/01005
Inventor 赵伟锋张珏赵长生钱一晖宋昕纪海锋
Owner SICHUAN UNIV