The invention relates to an electrified cleaning agent for high-pressure jet cleaning and a preparation method of the electrified cleaning agent. The electrified cleaning agent comprises the followingcomponents in parts by weight: 2-8 parts of a cleaning material, 50-60 parts of dipropylene glycol, 5-10 parts of ethanol, 10-20 parts of dimethyl silicone oil, 8-15 parts of a nonionic surfactant, 0.1-0.5 part of a mildew preventive and 0.2-0.8 part of an antistatic agent. The electrified cleaning agent disclosed by the invention is widely applied to maintenance of equipment such as high- and low-voltage power distribution cabinets, insulators, transformers, motors, large electromagnetic valves, electric welding machines, various electric equipment tools and the like; various comprehensive pollutants such as greasy dirt, dust and carbon powder attached to electric and electrical mechanical equipment can be rapidly removed; the volatilization speed is high, oil stains can be thoroughly dissolved, complete volatilization can be achieved, no residue is left, and no flash point exists; and the electrified cleaning agent is harmless to metals, coating veneers, insulating covering layers,alloys, dissolution-resistant rubber, plastics and the like.