The invention relates to an online measurement
system and method for organic chemical components in particulate matter. The
system comprises a particulate matter cutter, an
activated carbon diffusion pipe, a
diffusion drying pipe, an electric three-way valve, a collection-
thermal desorption device, a constant-temperature four-way valve, a sampling pump, a low-temperature
cold trap, a gas chromatograph and other assemblies. In the measuring process, a sampling mode, a purging mode, a
thermal desorption mode, an analysis mode and a
temperature drop mode are adopted in sequence, the five working
modes are switched automatically, continuously and cyclically, online
trapping,
thermal desorption and organic chemical component enrichment of the particulate matter are realized, and finally the gas chromatograph is adopted for conducting separation detection on the organic chemical components. The online measurement
system and method have the advantages that online measurement is adopted; measuring
time resolution is 30-60 minutes; a filter membrane used for particulate matter collection can be replaced, so that influences of residual matter during measurement are avoided; by the adoption of the 40 DEG C low-temperature
cold trap, high-volatility organic components can be measured; the online measurement system and method are compact in structure, easy and convenient to operate, reliable in result and capable of being applied to measurement of the
atmosphere and other particulate matter systems.