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High-strength high-temperature-resistant flame-retardant concrete viscosity modifier as well as preparation method and application thereof

A viscosity modifier and concrete technology, applied in the field of concrete admixtures, can solve the problems of concrete workability, poor bleeding and wrapping properties, poor thermal stability and flame retardant properties, affecting the overall strength of buildings, etc. , to achieve the effect of good inhibition of combustion and flame retardant properties, improved strength and thermal properties, and less investment

Active Publication Date: 2018-12-07
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the effective way to improve the performance of concrete is mainly through the introduction of water-reducing agents to improve some of its performance by reducing the amount of water; however, a lot of practice has proved that in the actual construction process, the addition of a single water-reducing agent is often not well coordinated. The comprehensive excellent performance of concrete is exerted, but the workability, bleeding and wrapping performance of concrete are still not good, which leads to many defects in concrete during construction, such as: honeycomb, pockmarked surface, cavity, exposed reinforcement, etc., and then Seriously affect the comprehensive performance of concrete, making it difficult to exert good mechanical strength, etc., and finally affect the overall strength of the building; It is easy to decompose and support combustion in the presence of an open flame, which makes it a potential dangerous factor after being used in construction

Method used

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  • High-strength high-temperature-resistant flame-retardant concrete viscosity modifier as well as preparation method and application thereof
  • High-strength high-temperature-resistant flame-retardant concrete viscosity modifier as well as preparation method and application thereof
  • High-strength high-temperature-resistant flame-retardant concrete viscosity modifier as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] Add 50g of acrylic acid, 50g of propylenesulfonic acid, 20g of sodium hydroxide, and 2000g of water into the reaction kettle, react at a temperature of 20°C for 10 minutes, then add 28g of bisphenol S, 20g of acrylamide, azobisisobutyronitrile + FeCl 3 (1+1)g was reacted at 50°C for 120min to obtain a light yellow viscous solution; add 1g of 1,3-butadiene monomer and stir at 60°C for 60min, filter a very small amount of insoluble residue, and collect the filtrate ; Then add double bond photocatalyst (PI-184+PI-127: 0.1g+0.05g) to the filtrate, and disperse it evenly to obtain the finished high-strength, high-temperature-resistant, flame-retardant concrete viscosity modifier.

[0045] Using a rotational viscometer at a temperature of 30.0±0.1°C, the apparent viscosity is measured to be 750 Pas, the limiting oxygen index (LOI) of pure resin is 39, and the flame retardancy is excellent. The raw materials of each component are shown in Table 1. The obtained viscosity modif...

Embodiment 2

[0047] Add 70g of methacrylic acid, 50g of methacrylic acid, 25g of lithium hydroxide, water+ethanol (4000+10)g into the reaction kettle, and react at a temperature of 25°C for 20min; then add BP+DTBT(5+20) g, methacrylamide 20g, ammonium persulfate+potassium thiosulfate (0.2+0.1)g react at a temperature of 50°C for 120min to obtain a light yellow viscous solution; then add 1,3-octadiene monomer 5g Stir and react at 50°C for 80 minutes; filter a very small amount of insoluble residue, collect the filtrate, then add double bond photocatalyst (PI-BDK: 0.01g) to the filtrate, and disperse it evenly to prepare the finished high-strength, high-temperature-resistant, flame-retardant concrete Viscosity modifier.

[0048] Using a rotational viscometer at a temperature of 30.0±0.1°C, the apparent viscosity was measured to be 780 Pas, and the limiting oxygen index (LOI) of the pure resin was 39, showing excellent flame retardancy. The raw materials of each component are shown in Table ...

Embodiment 3

[0050] Add acrylic acid + itaconic acid (40+20) g, methacrylic acid + styrene sulfonic acid (40 + 5) g, potassium hydroxide 30 g, and water 5000 g into the reaction kettle, and react at a temperature of 10 ° C for 15 min; Then add BHPPE+DOPO-HQ(10+15)g, acrylamide 50g, potassium persulfate+vitamin C(1+0.7)g and react at 35°C for 100min to obtain a light yellow viscous solution; then add 1, React 3g of 3-pentadiene monomer at a temperature of 45°C for 100min; filter a very small amount of insoluble residue, collect the filtrate, and then add a double-bond photocatalyst (PI-TPO: 0.05g) to the filtrate to disperse it evenly. The finished high-strength, high-temperature-resistant, flame-retardant concrete viscosity modifier was obtained.

[0051] Using a rotational viscometer at a temperature of 30.0±0.1°C, the apparent viscosity is measured to be 820 Pas, the limiting oxygen index (LOI) of pure resin is 40, and the flame retardancy is excellent. The raw materials of each compone...

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PUM

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Abstract

The invention belongs to the field of concrete admixtures and relates to a concrete viscosity modifier and preparation thereof. The concrete viscosity modifier provided by the invention comprises a polymer containing double bonds and a double-bond photocatalyst, wherein the polymer containing double bonds is prepared from the following raw material components in parts by weight: 5-50 parts of bisphenol compounds, 5-100 parts of carboxyl-containing monomers, 5-100 parts of monomers containing sulfonic groups, 1-50 parts of unsaturated monomers, 0.1-10 parts of 1,3-diene monomer, 10-300 parts ofalkali, 100-5000 parts of a solvent and 0.1-20 parts of a catalyst, wherein the total addition amount of the carboxyl-containing monomers and the monomers containing sulfonic groups is not less than50 parts by weight. The prepared concrete viscosity modifier has the advantages of being soluble, easy to construct and excellent in cohesiveness; and when the concrete viscosity modifier is added into cement and other materials to prepare concrete, the obtained concrete has high strength and aging resistance.

Description

technical field [0001] The invention belongs to the field of concrete admixtures, and in particular relates to a high-strength, high-temperature-resistant, flame-retardant concrete viscosity modifier and a preparation method thereof. Background technique [0002] With the country's increasing emphasis on the environment and building quality, how to further optimize and improve the comprehensive performance of concrete (such as construction flexibility, mechanical strength, flame retardancy, etc.) under the premise of green environmental protection has become the focus of attention. Since the end of the 20th century, people have been looking for an effective way to improve the comprehensive performance of concrete. At present, the effective way to improve the performance of concrete is mainly to improve some of its performance by introducing water reducing agent and reducing the amount of water; however, a lot of practice has proved that the addition of a single water reducin...

Claims

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Application Information

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IPC IPC(8): C08F220/06C08F228/02C08F220/56C08F220/54C08F236/06C08F236/04C08F222/02C08F212/14C08F220/58C08F220/04C08F283/06C04B24/16C04B103/44
CPCC04B24/163C04B24/165C04B2103/44C08F220/06C08F220/58C08F220/585C08F228/02C08F283/065C08F220/56C08F236/06C08F220/54C08F236/045C08F222/02C08F212/14C08F220/04
Inventor 张刚杨杰宋颖琦叶诚诚
Owner SICHUAN UNIV
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