Organosilicon pressure sensitive adhesive and preparation method thereof, composite film structure, vibration film and sound generating device
A technology of silicone and silicone rubber, applied in the direction of pressure-sensitive films/sheets, adhesives, etc., can solve the problems of damping rubber layer rigidity and damping performance degradation, diaphragm polarization, sound quality of sound-generating devices and poor listening stability, etc.
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[0089] The present invention also provides a preparation method of the silicone pressure-sensitive adhesive, comprising the following steps:
[0090] By weight, mix 20-80 parts of silicone resin, 5-55 parts of silicone rubber, and 30-60 parts of organic solvent to obtain a mixture;
[0091] adding 0.1-5 parts of a catalyst to the mixture, and heating the mixture to which the catalyst was added to obtain a colloid; and
[0092] The colloid is dried to obtain a silicone pressure-sensitive adhesive.
[0093] In an embodiment of the present invention, the silicone rubber is at least one of methyl hydroxy silicone rubber, vinyl silicone rubber, and phenyl silicone rubber.
[0094] The organic solvent is at least one of benzene, toluene, ethyl acetate, xylene, N-methylpyrrolidone and butanone. The silicone resin and silicone rubber can be dissolved in this organic solvent for uniform mixing.
[0095] The catalyst is an organic complex of platinum or an organic tin compound.
[0...
Embodiment 1
[0153] Provide 5 parts by weight of methyl hydroxy silicone rubber, 15 parts of silicone resin, 30 parts of benzene, dissolve methyl hydroxy silicone rubber and silicone resin in benzene to obtain a mixture; wherein, methyl hydroxy silicone rubber and organic The mass ratio of the silicone resin is 1:4, the quantity ratio of the M chain segment and the Q chain segment in the silicone resin is 1:0.7, the R 1 is methyl, and the range of m is 15.
[0154] Provide 2 parts of chloroplatinic acid diethyl phthalate complex, add chloroplatinic acid diethyl phthalate complex to the mixture, add chloroplatinic acid diethyl phthalate complex The mixture of chloroplatinic acid phthalate is heated at a temperature of 80 °C and a time of 70 minutes, and the diethyl chloroplatinate phthalate complex is used as a catalyst to promote the interaction between methyl hydroxy silicone rubber and silicone resin. Condensation reaction occurs to obtain colloid;
[0155] After the colloid is cooled,...
Embodiment 2
[0159] In parts by weight, 15 parts of methyl hydroxy silicone rubber, 30 parts of silicone resin, and 54 parts of toluene are provided, and the methyl hydroxy silicone rubber and silicone resin are dissolved in toluene to obtain a mixture; wherein, methyl hydroxy silicone rubber and organic The mass ratio of the silicone resin is 1:2, the quantity ratio of the M chain segment and the Q chain segment in the silicone resin is 1:0.75, the R 1 is a hydrogen radical, and the range of m is 17.
[0160] 0.5 part of dibutyltin dilaurate is provided, the dibutyltin dilaurate is added to the mixture, the mixture added with the dibutyltin dilaurate is heated, and the dibutyltin dilaurate is used as a catalyst, It can promote the condensation reaction between methyl hydroxy silicone rubber and silicone resin to obtain colloid. The temperature of this heating treatment is 85℃ and the time is 60min;
[0161] After the colloid is cooled, provide 0.5 part of benzoyl peroxide, add benzoyl pe...
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Abstract
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