A method for treating circulating cooling water
A technology of circulating cooling water and treatment cycle, which is applied in natural water treatment, multi-stage water treatment, non-polluted water treatment, etc. It can solve the problems of high concentration and uneconomical dosage of chemicals, and achieve low dosage of chemicals and easy Control and improve the effect of scaling and corrosion
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[0022] The second agent can be the same or different from the first agent, and can be used in the art (i.e., a pharmaceutical agent mainly having corrosion inhibition performance), however, in order to achieve better scale inhibition resistance and further reduce the drug According to a preferred embodiment of the present invention, the second agent comprises (to) phosphate and / or polyphosphate, the second agent in PO 4 3- The investment volume is 2-4 mg / L (more preferably 2.2 to 3.8 mg / L).
[0023] The phosphate can be a variety of water-soluble phosphates commonly used in the art, as long as it is added to the water, PO can be produced. 4 3- I.e. More preferably, the phosphate is selected from the group consisting of sodium phosphate, potassium phosphate, sodium hydrogen phosphate, potassium hydrogen phosphate, phosphate, and one or more of potassium dihydrogen phosphate.
[0024] The polyprophosphate can be a water-soluble polyspiosphate and / or a water-soluble polyvas...
Embodiment 1
[0049] Take the test raw water, zinc sulfate, HEDP and acrylic acid / 2-methyl-2'-acrylamide propane sulfonic acid copolymer, so that Zn in water 2+ The concentration of Hedp and acrylic / 2-methyl-2'-acrylamide propylenesulfonic acid copolymer is 0.45 mg / L, 0.8 mg / L, 1.6mg / L, and then 20 # The carbon steel test piece is suspended in the water, followed by in the water. 2 2h, pass N 2 After the end, the sampling should be calcium calcium concentration (recorded as CA 1 ), Followed by N 2 The post-test water is placed in a thermostat of 5 ° C, and the calcium calcium ion concentration is taken after 18h (remember to CA) 2 ), At the same time # Corrosion rate of carbon steel test (Remembling F 1 );
[0050] Sodium phosphate is added to water 1-1 in the test, so that in water PO 4 3- The concentration was (2.2 / 5) mg / L, then concentrated in a water bath in an 80 ° C to concentrate, and the calcium ion concentration in the water after cooling (recorded as CA) 3 );
[0051] T...
Embodiment 2
[0053] Take the test raw water 1, zinc sulfate and zinc chloride, PBTCA, acrylic / 2-methyl-2'-acrylamide propane sulfonic acid copolymer, to make the water Zn 2+ , PBTCA, acrylic / 2-methyl-2'-acrylamide propylenesulfonic acid copolymer concentration is 0.65 mg / L, 1.2mg / L, 1.8mg / L, and then 20 # The carbon steel test piece is suspended in the water, followed by in the water. 2 2h, pass N 2 After the end, the sampling should be calcium calcium concentration (recorded as CA 1 ), Followed by N 2 The post-test water is placed in a thermostat of 5 ° C, and the calcium calcium ion concentration is taken after 18h (remember to CA) 2 ), At the same time # Corrosion rate of carbon steel test (Remembling F 1 );
[0054] Add sodium hexamphosphate in the test water 1-1, so that the water is po 4 3- The concentration was (3.8 / 5) mg / L, then concentrated in a water bath in an 80 ° C to concentrate, and the calcium ion concentration in the water was then subjected to the water. 3 );
...
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