Antibacterial and flame-retardant polypropylene pipe fitting and preparing method thereof
A flame retardant polypropylene and polypropylene technology is applied in the field of antibacterial and flame retardant polypropylene pipes and their preparation. , the effect of prolonging the service life
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Embodiment 1
[0032] Embodiment 1 compound antibacterial agent preparation one
[0033] Hollow Mesoporous SiO 2 preparation:
[0034]Add 1g of polystyrene pellets to 100ml of ammonia water, stir evenly, add 50ml of absolute ethanol, stir at room temperature for 0.5h, add dropwise 1.5ml of tetraethyl orthosilicate, stir at room temperature for 12h, centrifuge and wash 5 times , placed in an oven at 40°C to dry to obtain hollow mesoporous SiO 2 .
[0035] Polyhexamethyleneguanidine hydrochloride / SiO 2 Core-shell structure preparation:
[0036] Disperse 2 g of polyhexamethyleneguanidine hydrochloride in 80 ml of aqueous solution, and stir at room temperature for 1 hour to completely dissolve the polyhexamethyleneguanidine hydrochloride. Weigh 1g of hollow mesoporous SiO 2 Disperse in an aqueous solution of polyhexamethyleneguanidine hydrochloride, stir at room temperature for 48 hours; centrifuge the reacted solution, wash, and dry in an oven at 50°C to obtain polyhexamethyleneguanidine ...
Embodiment 2
[0039] Embodiment 2 Composite antibacterial agent prepares two
[0040] Hollow Mesoporous SiO 2 preparation:
[0041] Add 1g of polystyrene pellets to 100ml of ammonia water, stir evenly, add 50ml of absolute ethanol, stir at room temperature for 1h, add dropwise 2ml of tetraethyl orthosilicate, stir at room temperature for 12h, centrifuge, wash 5 times, place Dry in an oven at 80°C to obtain hollow mesoporous SiO 2 .
[0042] Polyhexamethyleneguanidine hydrochloride / SiO 2 Core-shell structure preparation:
[0043] Disperse 2 g of polyhexamethyleneguanidine hydrochloride in 80 ml of aqueous solution, and stir at room temperature for 1 hour to completely dissolve the polyhexamethyleneguanidine hydrochloride. Weigh 1g of hollow mesoporous SiO 2 Disperse in an aqueous solution of polyhexamethyleneguanidine hydrochloride, stir at room temperature for 36 hours; centrifuge the reacted solution, wash, and dry in an oven at 40°C to obtain polyhexamethyleneguanidine hydrochloride...
Embodiment 3
[0046] Embodiment 3 composite antibacterial agent preparation three
[0047] Hollow Mesoporous SiO 2 preparation:
[0048] Add 1g of polystyrene pellets to 100ml of ammonia water, stir evenly, add 50ml of absolute ethanol, stir at room temperature for 1h, add dropwise 1.8ml of tetraethyl orthosilicate, stir at room temperature for 12h, centrifuge and wash 6 times, Dry in an oven at 60°C to obtain hollow mesoporous SiO 2 .
[0049] Polyhexamethyleneguanidine hydrochloride / SiO 2 Core-shell structure preparation:
[0050] Disperse 2g of polyhexamethyleneguanidine hydrochloride in 100ml of aqueous solution and stir at room temperature for 2h to completely dissolve the polyhexamethyleneguanidine hydrochloride. Weigh 1g of hollow mesoporous SiO 2 Disperse in an aqueous solution of polyhexamethyleneguanidine hydrochloride, stir at room temperature for 40 hours; centrifuge the reacted solution, wash, and dry in an oven at 45°C to obtain polyhexamethyleneguanidine hydrochloride / S...
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