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A flexible silicon-based thin film solar cell and preparation method thereof

A technology of solar cells and silicon-based thin films, which is applied in the field of solar cells, can solve problems such as complex preparation processes, restrictions on the development of integration of thin-film cells, and high requirements on process conditions, so as to reduce production time, save raw materials, and reduce costs. Effect

Inactive Publication Date: 2019-01-15
DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] At present, silicon-based thin-film solar cells all use toughened glass as the substrate, and the cell structure adopts a pin structure, with p-layer and n-layer as electrodes to build a built-in electric field. The preparation process is relatively complicated, and the process conditions are relatively high. The non-rollability of thin-film batteries limits the development of integration of thin-film batteries and buildings

Method used

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  • A flexible silicon-based thin film solar cell and preparation method thereof
  • A flexible silicon-based thin film solar cell and preparation method thereof
  • A flexible silicon-based thin film solar cell and preparation method thereof

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Embodiment 1

[0027] Attached below figure 1 , attached figure 2 , attached image 3 , the present invention will be further described by embodiment. The preparation process of the novel battery of embodiment 1 is as follows:

[0028] 1. The purchased 30 micron thick flaky stainless steel substrate 1 is cleaned, the cleaning method is ultrasonic cleaning, and the cleaning solution is a neutral solution (mainly composed of alkali, emulsifier is used to remove oil stains, and the op-10 of Sinopharm is used) , measure 8-10mL, then weigh potassium carbonate and KOH, the concentration of potassium carbonate is 1-5mol / L, 3mol / L here, and the concentration of KOH is also 1-5mol / L, 3mol / L here), The solvent is prepared with deionized water, the solution cleaning time is 30 minutes, and then cleaned with deionized water for 30 minutes;

[0029] 2. Prepare a high-temperature silver layer 2 with a thickness of 250nm at 255°C by thermal evaporation on the cleaned stainless steel substrate; at room...

Embodiment 2

[0034] 1. The purchased 30 micron thick flaky stainless steel substrate 1 is cleaned, the cleaning method is ultrasonic cleaning, and the cleaning solution is a neutral solution (mainly composed of alkali, emulsifier is used to remove oil stains, and the op-10 of Sinopharm is used) , measure 8-10mL, then weigh potassium carbonate and KOH, the concentration of potassium carbonate is 1-5mol / L, here 3mol / L, the concentration of KOH is also 1-5mol / L, here 3mol / L), The solvent is prepared with deionized water, the solution cleaning time is 30 minutes, and then cleaned with deionized water for 30 minutes;

[0035]2. Prepare a high-temperature silver layer 2 with a thickness of 250nm at 255°C by thermal evaporation on the cleaned stainless steel substrate; at room temperature, use an aluminum-doped zinc oxide target to prepare an AZO layer by magnetron sputtering 3. The thickness is 60nm; then use plasma-enhanced chemical vapor deposition of silicon film: n-type silicon film, doped w...

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Abstract

The invention discloses a novel structure of a silicon-based thin film solar cell and a preparation method thereof, belonging to the technical field of solar cells. A technical scheme comprise that following step of: (1) depositing a high-temperature silver film (Ag) on a flexible substrate; 2, preparing an aluminum doped zinc oxide film (AZO) on Ag; 3, preparing an n-type silicon film layer on AZO; 4) depositing an intrinsic-type i-layer silicon thin film layer on that n-type silicon thin film lay; 5) depositing a p-type thin film doped lay on that intrinsic layer silicon thin film; (6) Spraying conductive metal film on P-type thin film doping layer by spraying gun, and then putting it into oven to evaporate organic reagent in conductive liquid film, so that conductive ink can replace TCOthin film electrode with traditional battery structure. A new type of thin film solar cell is formed by the built-in electric field between the p-type silicon film doping layer and the conductive film.

Description

technical field [0001] The invention belongs to the field of solar cells, and is a novel flexible silicon thin-film solar cell prepared by a flexible substrate / Ag / AZO / n / i / p / conductive metal paste spraying method and a preparation method thereof. Background technique [0002] As a new energy source, solar cells have important strategic significance to solve the energy crisis and environmental pollution, and silicon-based thin-film solar cells have attracted widespread attention due to their advantages such as simple preparation process and low energy consumption. [0003] At present, the way of tempered glass to decorate buildings is very common, and the application of solar panels in this field has attracted widespread attention, which has promoted the development of photovoltaic building integration. Flexible thin-film solar cells are undoubtedly the best choice due to their low cost, high power-to-mass ratio, good flexibility, and the ability to generate electricity. [0...

Claims

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Application Information

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IPC IPC(8): H01L31/0224
CPCH01L31/022425H01L31/022466H01L31/0445Y02E10/50
Inventor 刘生忠张豆豆王辉曹越先秦炜
Owner DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI