Automobile battery shell rubber coating material, and preparation method

An automotive battery and encapsulation technology, applied in the field of materials, can solve the problems of poor low temperature impact performance and poor shock resistance, and achieve the effects of high fluidity, low manufacturing cost, and excellent low temperature resistance.

Pending Publication Date: 2019-02-15
NANJING JULONG SCI&TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, the present invention adopts micro-foaming technology to improve the quality and appearance of the product such as serious shrinkage, and also has excellent low temperature resistance, excellent cushioning property, flame retardant properties, etc., and solves the problems of poor low temperature impact performance and poor shock resistance of the product.

Method used

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  • Automobile battery shell rubber coating material, and preparation method
  • Automobile battery shell rubber coating material, and preparation method
  • Automobile battery shell rubber coating material, and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A preparation method of an automotive battery housing rubber covering material, comprising the following steps:

[0030] Step 1: 90 parts of thermoplastic elastomer olefin-based elastomer TPE, 25 parts of melt-blown polypropylene, 5 parts of graphite, 1 part of dehydrated glyceryl methacrylate grafted polypropylene, 0.5 parts of nano-hydroxyapatite, stearin 0.5 parts of zinc acid, 0.2 parts of silicone powder, 1 part of antioxidant 1010 parts by weight, mixed in a mixer for 1 min, added to a twin-screw extruder through a hopper, granulated at a temperature of 140-190 ° C, the screw speed 200r / min, to obtain the composite material used for battery casing rubber wrapping;

[0031] Step 2: Add foaming agent (0.4 part of ammonium carbonate, 0.1 part of azodicarbonamide) and the encapsulation composite material obtained in step 1 to the barrel of the injection molding machine in parts by weight; Plastic-coating injection molding to obtain a battery case with rubber-coating....

Embodiment 2

[0034] A preparation method of an automotive battery housing rubber covering material, comprising the following steps:

[0035] Step 1: 60 parts of thermoplastic elastomer olefin-based elastomer TPV, 5 parts of melt-blown polyethylene, 20 parts of calcium carbonate, 20 parts of nano-layered double hydroxide, 20 parts of maleic anhydride grafted modified polystyrene, 7 parts of nano-zinc oxide, 3 parts of sodium dodecylbenzenesulfonate, 2 parts of oleic acid amide, 0.2 part of antioxidant 1010 parts by weight are mixed in mixer for 5min, are added in the twin-screw extruder by hopper, Granulate at a temperature of 140-190°C, with a screw speed of 600r / min, to obtain a composite material for battery case encapsulation;

[0036] Step 2: Add foaming agent (10.8 parts of magnesium carbonate, 1.2 parts of N,N-dinitrosopentamethylenetetramine) and the encapsulation composite material obtained in step 1 to the barrel of the injection molding machine in parts by weight; At a temperatu...

Embodiment 3

[0039] A preparation method of an automotive battery housing rubber covering material, comprising the following steps:

[0040] Step 1: Add 70 parts of thermoplastic elastomer olefin elastomer SEBS, 10 parts of melt-blown polypropylene, 10 parts of talcum powder, 30 parts of isobutyl aluminum hypophosphite, 10 parts of dehydrated glyceryl methacrylate grafted polypropylene, nano 5 parts of hydroxyapatite, 1 part of zinc stearate, 1 part of silicone powder, 0.5 parts by weight of 1010 parts of antioxidant are mixed in a mixer for 2 minutes, and added to a twin-screw extruder through a hopper, at 140- Granulating at a temperature of 190°C, with a screw speed of 500r / min, to obtain a composite material for battery case encapsulation;

[0041] Step 2: Add the foaming agent (2.5 parts of calcium bicarbonate, 2.5 parts of azodicarbonamide) and the encapsulation composite material obtained in step 1 to the barrel of the injection molding machine in parts by weight; at a temperature o...

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Abstract

The invention relates to an automobile battery shell rubber coating material, and a preparation method thereof. The material comprises components with the following parts by weight: 60-90 parts of a thermoplastic elastomer, 5-25 parts of a melt-blown polymer, 5-30 parts of a flame retardant, 0-20 parts of a filler, 1-20 parts of an interface modifier, 0.5-12 parts of a foamer, 1-10 parts of a foaming synergist, 0.5-2 parts of a lubricant, and 0.2-1 part of an antioxidant. The invention further discloses the preparation method of the automobile battery shell rubber coating material. The automobile battery shell rubber coating material and the preparation method thereof have the advantages that through high fluidity and extremely high machining formability, a complex battery shell structurecan be accurately replicated, the material can be effectively adhered to the battery shell structure, and the product wall thickness can be optimally reduced, so that high product portability is achieved; the material can be effectively bonded with a metal or engineering plastic shell, so that the problem of high dropping possibility of the conventional market product is effectively solved, and better buffering protection effects for a battery are achieved; and the material has excellent low-temperature-resistant, buffering and flame-retardant performances, so that such problems as unsatisfactory low-temperature falling ball impact performance and unsatisfactory shock-resistant performance of the conventional market product are solved.

Description

technical field [0001] The invention relates to an automobile battery casing rubber covering material and a preparation method thereof, belonging to the field of materials Background technique [0002] As the carrier of the battery module, the car battery case plays a key role in the safe operation and protection of the battery module. It is required (1) to be convenient for maintenance; (2) to play a protective role in the event of accidents such as vehicle collision or spontaneous combustion of the battery. At present, the materials are mainly thermosetting SMC composite materials, PC / ABS alloy materials, etc. These materials have sufficient mechanical strength, but they cannot meet the drop test of the battery case, especially the low temperature drop test at -30°C; therefore, an external package is usually used. Layers of rubberized materials improve the drop resistance of the shell, but the rubberized materials currently on the market have the following problems: 1. Th...

Claims

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Application Information

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IPC IPC(8): C08L23/00C08L67/00C08L53/02C08L23/12C08L51/06C08L83/04C08L23/06C08L51/00C08K13/02C08K3/04C08K5/098C08K3/34C08K3/26C08J9/08C08J9/10H01M2/10H01M50/249
CPCC08J9/0033C08J9/0061C08J9/0066C08J9/0095C08J9/08C08J9/103C08J9/107C08J2451/06C08J2451/00C08J2423/06C08J2483/04C08J2367/00C08J2353/02C08J2203/04C08J2203/02C08J2203/18C08J2323/12C08J2323/00H01M50/20Y02E60/10
Inventor 王滨刘曙阳蒋顶军
Owner NANJING JULONG SCI&TECH CO LTD
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