Resin composition, resin sheet, multilayer printed circuit board, and semiconductor device
A resin composition, resin technology, applied in the direction of printed circuit, printed circuit parts, circuit substrate materials, etc., can solve the problem of long processing time, and achieve the effect of excellent heat resistance and excellent developability
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[0232] Hereinafter, the present invention will be described in more detail through examples, but the present invention is not limited by these examples.
Synthetic example 1
[0234] (Synthesis of Cyanate Compounds)
[0235] 300 g (1.28 moles in terms of OH group) and 194.6 g (1.92 moles) of triethylamine (1.5 moles relative to 1 mole of hydroxyl groups) of 1-naphthol aralkyl resin (manufactured by Nippon Steel Sumitomo Chemical Co., Ltd.) were dissolved in distilled water. 1800 g of methyl chloride was used as solution 1.
[0236] 125.9 g (2.05 moles) of cyanogen chloride (1.6 moles relative to 1 mole of hydroxyl), 293.8 g of dichloromethane, 194.5 g (1.92 moles) of 36% hydrochloric acid (1.5 moles relative to 1 mole of hydroxyl), and 1205.9 g of water , while keeping the liquid temperature at -2 to -0.5°C under stirring, solution 1 was poured over 30 minutes. After solution 1 was poured, after stirring at the same temperature for 30 minutes, pour 65 g (0.64 moles) of triethylamine (0.5 moles relative to 1 mole of hydroxyl) in 65 g of dichloromethane over 10 minutes. Solution 2). After solution 2 was injected, it was stirred at the same temperat...
Embodiment 1
[0240] (Manufacture of resin composition and resin sheet)
[0241] Dicyclopentadiene type epoxy resin (n in formula (1) is 1 to 3. XD-1000 (trade name) , manufactured by Nippon Kayaku Co., Ltd.) 22.4 parts by mass, 2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)-butanone-1 as a photocuring initiator (B) (Irgacure (registered trademark) 369, manufactured by BASFJapan Ltd.) 6.5 parts by mass, propylene glycol monomethyl ether acetate (hereinafter sometimes abbreviated as PGMEA) solution of TrisP-PA epoxy acrylate compound (C) (KAYARAD (registered trademark) ZCR-6007H, non-volatile content 65% by mass, acid value: 70 mgKOH / g, manufactured by Nippon Kayaku Co., Ltd.) 77.5 parts by mass (50.4 parts by mass in terms of non-volatile content), other than (C) component 17.4 parts by mass of dipentaerythritol hexaacrylate (KAYARAD (registered trademark) DPHA, manufactured by Nippon Kayaku Co., Ltd.) of the compound (D) having an ethylenically unsaturated group, maleimide compound (E) ...
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