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Method for purifying flue gas desulfurization agent

A purification treatment and desulfurization agent technology, applied in gas treatment, chemical instruments and methods, gaseous effluent wastewater treatment, etc., can solve the problems of poor removal of impurity ions, etc., to overcome the low load of resin deacidification radicals and reduce sodium ions Concentration, improve the effect of load removal

Inactive Publication Date: 2019-03-29
PANZHIHUA IRON & STEEL RES INST OF PANGANG GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The technical problem to be solved by the present invention is that the removal effect of impurity ions in the existing purification treatment method for flue gas desulfurizer solution is poor

Method used

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  • Method for purifying flue gas desulfurization agent
  • Method for purifying flue gas desulfurization agent
  • Method for purifying flue gas desulfurization agent

Examples

Experimental program
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Effect test

Embodiment 1

[0037] Flue gas desulfurization of a sintering machine in a large iron and steel plant, the sulfur dioxide content in the sintering flue gas is 3000-7000mg / Nm 3 , the concentration of sulfur trioxide is 200~350mg / Nm 3, the dust content is 50~100mg / m 3 , The flue dust contains iron, lead, magnesium, cadmium, cobalt, chromium, calcium and other elements. After the flue gas desulfurization agent solution is recycled for a long time, sulfate, iron, chlorine and other ions in the solution are accumulated. The desulfurization effect of the desulfurization agent solution Reduced, the concentration of sulfur dioxide at the flue gas inlet is 6000mg / m 3 , the desulfurization efficiency is 92.15%.

[0038] Purify the desulfurizer solution, wherein the sulfate concentration in the desulfurizer solution is 125g / L, the sodium ion concentration is 26g / L, and the concentrations of other ions are shown in Table 1 below.

[0039] The temperature of the desulfurizer solution is reduced to 15°...

Embodiment 2

[0044] Flue gas desulfurization of a non-ferrous ring collection, the sulfur dioxide content in the flue gas is 1000-3000mg / Nm 3 , the concentration of sulfur trioxide is 200~500mg / Nm 3 , the dust content is 20~100mg / m 3 , The soot contains iron, lead, magnesium, cadmium, cobalt, chromium, calcium and other elements. After the flue gas desulfurizer solution has been recycled for a long time, sulfate, iron, chlorine and other ions in the solution have accumulated, and the desulfurization effect of the desulfurizer solution has decreased. The concentration of sulfur dioxide at the flue gas inlet is 3000mg / m 3 , the desulfurization efficiency is 93.5%.

[0045] Purify the desulfurizer solution, wherein the sulfate concentration in the desulfurizer solution is 95g / L, the sodium ion concentration is 20g / L, and the concentrations of other ions are shown in Table 2 below.

[0046] The temperature of the desulfurizer solution is lowered to 17°C through the heat exchange system, and...

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Abstract

The invention belongs to the technical field of inorganic chemical industry, and concretely relates to a method for purifying a flue gas desulfurization agent. The technical problem to be solved by the present invention is poor removal effect of impurity ions in existing methods for purifying a flue gas desulfurization solution. The method for purifying the flue gas desulfurization agent comprisesthe following steps: reducing the temperature of the flue gas desulfurization agent solution to 10-20 DEG C, adjusting the pH value of the cooled solution to 10.0-12.0, adding a metal ion precipitating agent, reducing the temperature of the obtained solution to -10-0 DEG C, performing stirring and reacting for 4-8 h, and centrifuging the obtained reaction product to obtain a solid material sodiumsulfate and a purified desulfurization solution. The method for purifying the flue gas desulfurization agent solution can effectively remove sulfate radicals and sodium ions, can remove multiple types of elements in the desulfurization solution, has a high separation efficiency, and has a desulfurization efficiency reaching 99.32% or more.

Description

technical field [0001] The invention belongs to the technical field of inorganic chemical industry, and in particular relates to a method for purification treatment of flue gas desulfurization agent. Background technique [0002] Aqueous solutions of basic compounds such as organic amine solutions are widely used in the removal and recovery of acid gases (including hydrogen sulfide, carbon dioxide, sulfur dioxide, etc.). The principle is that low-concentration acid gas reacts with lye to generate decomposed organic amine salts to form rich liquid, and then heats and desorbs in the desorption tower to release high-concentration acid gas for recycling. The amine liquid can be reused after purification. This desulfurization technology has been widely used in desulfurization of sintering flue gas, non-ferrous smelting flue gas, ring collection flue gas, sulfuric acid tail gas, coal-fired boiler flue gas, and petroleum refining flue gas. [0003] The flue gas contains sulfur di...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/04B01D53/96B01D53/52B01D53/50B01D53/48C02F101/10C02F101/20C02F103/18
CPCB01D53/48B01D53/50B01D53/52B01D53/523B01D53/526B01D53/96B01D2258/0283C02F1/38C02F1/62C02F1/66C02F9/00C02F2101/101C02F2101/20C02F2103/18C02F2301/08
Inventor 邱正秋黎建明王建山刘鹏举
Owner PANZHIHUA IRON & STEEL RES INST OF PANGANG GROUP