High-heat-conductivity graphene membrane and preparing method thereof
A composite technology of high thermal conductivity graphite and graphene, which is applied in the direction of modification through conduction heat transfer, cooling/ventilation/heating modification, etc., can solve the problems of low product yield, low production efficiency, low efficiency, etc., and improve product quality. The effect of high efficiency and high thermal conductivity
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[0030] The invention provides a kind of preparation method of high thermal conductivity graphene film, comprises the following steps:
[0031] A) the polyamic acid resin and the graphene oxide solution are coated on the surface of the substrate successively, and the graphene oxide composite film is obtained after drying;
[0032] B) peeling off the graphene oxide composite film from the substrate to obtain a continuous graphene oxide composite film coil;
[0033] C) heat-treating the graphene oxide composite film coil to obtain a carbonized graphene oxide composite film;
[0034] D) graphitizing the carbonized graphene oxide composite film to obtain a graphene film with high thermal conductivity.
[0035] The present invention preferably prepares polyamic acid resin according to the following method:
[0036] Polycondensation reaction of dianhydride and diamine in a strong polar solvent to obtain polyamic acid resin;
[0037] Described dianhydride is preferably one or more ...
Embodiment 1
[0059] It is prepared by polycondensation reaction of biphthalic dianhydride (BPDA), benzophenone tetraacid dianhydride (BTDA), diaminodiphenyl ether (ODA) and p-phenylenediamine (PPDA) in strong polar solvent DMAC Polyamic acid (PAA) matrix resin with a solid content of 20%;
[0060] Using a vacuum ultrasonic stirring disperser, the graphene oxide powder is dispersed in the NMP containing PVA to form a uniform graphene oxide slurry and vacuum defoaming; the concentration of graphene oxide in the prepared graphene oxide slurry is 5wt%, viscosity is 10000cPs, organic surfactant content is 0.02wt%
[0061] The above-mentioned polyimide acid base resin and graphene oxide solution are passed through the coating head of the double feed double coating port, and the polyimide acid and the graphene oxide solution are sequentially coated on the base material to form a certain thickness of oxidation. The graphene composite film is dried in a coating machine oven to remove the solvent a...
Embodiment 2
[0068] It is prepared by polycondensation reaction of biphthalic dianhydride (BPDA), benzophenone tetraacid dianhydride (BTDA), diaminodiphenyl ether (ODA) and p-phenylenediamine (PPDA) in strong polar solvent DMAC Polyamic acid (PAA) matrix resin with a solid content of 15%;
[0069] Using a vacuum ultrasonic stirring disperser, the graphene oxide powder is dispersed in the NMP containing PVA to form a uniform graphene oxide slurry and vacuum defoaming; the concentration of graphene oxide in the prepared graphene oxide slurry is 7wt%, viscosity is 20000cPs, organic surfactant content is 0.03wt%
[0070] The above-mentioned polyimide acid base resin and graphene oxide solution are passed through the coating head of the double feed double coating port, and the polyimide acid and the graphene oxide solution are sequentially coated on the base material to form a certain thickness of oxidation. The graphene composite film is dried in a coating machine oven to remove the solvent a...
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