Molten steel deoxidizing and microalloying method

A technology of micro-alloying and molten steel, which is used in the improvement of process efficiency, electric furnaces, furnaces, etc., to achieve the effects of smooth blowing, uniform molten pool temperature, and improved micro-alloying effect.

Pending Publication Date: 2019-04-26
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] As early as the 1940s, Japan, the United States, Germany, etc. successively studied and applied tungsten ore powder instead of tungsten-iron alloy in electric furnaces, open hearth furnaces and induction furnaces for direct reduction alloying, and the research on direct microalloying kicked off; in the 20th century In the 1970s, the United States used molybdenum oxide instead of ferromolybdenum for alloying in steelmaking in industrial production; in the 1980s, Japan took the lead in conducting a large number of research on chromium ore smelting reduction and applied it to industrial production; Masahiro Kawakami Si and C were used to reduce powdered chromium ore on the induction furnace; Ida Yuki and others used coke to reduce chromium ore on the top-bottom double-blown converter; from the 1990s to the present, research on direct alloying has been carried out in China ; Gao Yunming and others simulated the direct alloying process of molybdenum oxide in the converter tapping process in the laboratory. Miao Zhimin and others used the direct alloying process of chrome ore when smelting GCr15 bearing steel in the 30t electric furnace of the No. 5 Plant of Shanghai Iron and Steel. When smelting steel 06VTi for enamel, vanadium slag was used instead of ferrovanadium for direct alloying in the converter. Jinan Iron and Steel Co., Ltd. used

Method used

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  • Molten steel deoxidizing and microalloying method

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0018] Example 1

[0019] This example adopts the top-bottom combined blowing K-OBM-S converter, the volume of the furnace is 90t, and the maximum flow rate of top-blowing oxygen is 200m 3 / min; the maximum flow rate of bottom blowing gas is 60m 3 / min.

[0020] This embodiment provides a method for deoxidation and microalloying of molten steel, which includes the following steps: mixing molten iron with a temperature ≥ 1200°C into a top-bottom re-blowing converter, sampling and analyzing molten steel, C, Si, Mn, P and The mass percentages of S are: C4.0%; Si 0.60%; Mn0.70%; P 0.02%; When [O] in molten steel is ≤ 200ppm, nitrogen is used as the carrier gas at the bottom to spray vanadium alloy powder into molten steel for microalloying treatment, and the oxygen flow rate of top blowing is 2.0m 3 / (t·min), the bottom blowing nitrogen flow rate is 2.5m 3 / (t·min); wherein, the total amount of alloy powder added is 5kg / t molten steel.

Example Embodiment

[0021] Example 2

[0022] This embodiment provides a method for deoxidation and microalloying of molten steel, which includes the following steps: mixing molten iron with a temperature ≥ 1200°C into a top-bottom re-blowing converter, sampling and analyzing molten steel, C, Si, Mn, P and The mass percentages of S are: C4.0%; Si 0.60%; Mn0.70%; P 0.02%; When [O] in molten steel is ≤ 200ppm, nitrogen is used as the carrier gas at the bottom to spray vanadium alloy powder into molten steel for microalloying treatment, and the oxygen flow rate of top blowing is 2.0m 3 / (t·min), the bottom blowing nitrogen flow rate is 2.5m 3 / (t·min); wherein, the total amount of alloy powder added is 0.03kg / t molten steel.

Example Embodiment

[0023] Example 3

[0024] This embodiment provides a method for deoxidation and microalloying of molten steel, which includes the following steps: mixing molten iron with a temperature ≥ 1200°C into a top-bottom re-blowing converter, sampling and analyzing molten steel, C, Si, Mn, P and The mass percentages of S are: C4.0%; Si 0.60%; Mn0.70%; P 0.02%; When [O] in molten steel is ≤ 200ppm, nitrogen is used as the carrier gas at the bottom to spray vanadium alloy powder into molten steel for microalloying treatment, and the oxygen flow rate of top blowing is 2.0m 3 / (t·min), the bottom blowing nitrogen flow rate is 2.5m 3 / (t·min); wherein, the total amount of alloy powder added is 10kg / t molten steel.

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Abstract

The invention provides a molten steel deoxidizing and microalloying method. The molten steel deoxidizing and microalloying method comprises the following steps of blowing oxygen to the top of a top-bottom combined blowing converter, blowing inert gas to the bottom of the top-bottom combined blowing converter for smelting, or blowing inert gas to the bottom of molten steel in an electric furnace for smelting; after main chemical components are qualified, blowing a deoxidizing agent to the bottom with inert gas as a carrier for refining; and when the oxygen content in the molten steel is less than or equal to 200 ppm, blowing alloyed powder into the molten steel with inert gas as a carrier for microalloying treatment, wherein the blowing amount of the alloyed powder is less than or equal to10 kg/t of the molten steel.According to the molten steel deoxidizing and microalloying method, the inert gas is blown to the bottom, and after the deoxidizing agent is blown into the molten steel todeoxidize the molten steel, the alloyed powder is blown for direct microalloying, so that components of the molten steel can be more uniform; a brand new concept is provided for directly microalloyingmicroalloy elements in the steel material production process; the microalloy elements existing in the form of solid solution can be effectively obtained out of a steel material, and thus, the steel performance is improved.

Description

technical field [0001] The invention relates to the technical field of top-bottom combined blowing converter steelmaking technology, in particular to a method for deoxidation and microalloying of molten steel. Background technique [0002] Micro-alloying elements usually refer to the addition of trace carbonitride-forming elements such as niobium, vanadium, titanium, rare earth elements, and boron elements on the basis of the original main alloying elements, thereby affecting mechanical properties, or affecting corrosion resistance, Heat resistance plays a role; in the modern steel production process, due to the continuous development of low-oxygen, low-sulfur and high-purity smelting technology, it provides the necessary prerequisites for the microalloying of microalloying elements. [0003] As early as the 1940s, Japan, the United States, Germany, etc. successively studied and applied tungsten ore powder instead of tungsten-iron alloy in electric furnaces, open hearth furn...

Claims

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Application Information

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IPC IPC(8): C21C5/35C21C5/52C21C7/06
CPCC21C5/35C21C5/52C21C7/0037C21C7/06Y02P10/20
Inventor 周建安张翔王宝宋伟明
Owner WUHAN UNIV OF SCI & TECH
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