Acrylate emulsion for high-gloss water-based finish varnish with lotus leaf effect and preparation method of acrylate emulsion

A technology of lotus leaf effect and acrylate, which is applied in paints containing biocide, anti-fouling/underwater coatings, coatings, etc., can solve the problems of poor polymer stability and achieve low film-forming temperature, good stability and The effect of versatility and simple operation process

Active Publication Date: 2019-05-03
佛山市顺德区巴德富实业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In order to solve the problem that the polymer with the "lotus leaf effect" structure synthesized by organic-inorganic compounding is prone to poor stability, the purpose of the present invention is to provide an acrylate emulsion for high-gloss water-based finish varnish with lotus leaf effect synthesized by all organic matter, It does not need to add modified inorganic compound materials, and the compatibility and reactivity between organic raw materials are good. In practical industrial applications, it has the advantages of low cost, stable production batches, high storage stability and broad application prospects.

Method used

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  • Acrylate emulsion for high-gloss water-based finish varnish with lotus leaf effect and preparation method of acrylate emulsion
  • Acrylate emulsion for high-gloss water-based finish varnish with lotus leaf effect and preparation method of acrylate emulsion
  • Acrylate emulsion for high-gloss water-based finish varnish with lotus leaf effect and preparation method of acrylate emulsion

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] An acrylic ester emulsion for a high-gloss water-based finish varnish with a lotus leaf effect, consisting of the following raw materials in parts by weight: 30 parts of methyl methacrylate, 14 parts of isooctyl acrylate, crosslinking monomers (including dimethyl Ethylene glycol acrylate and glycidyl methacrylate) 2 parts, carboxyl monomer (methacrylic acid) 1 part, silicone monomer (vinyltrimethoxysilane) 1.6 parts, emulsifier (including lauryl Sodium sulfate, 2 parts of 2-acrylamido-2-sodium methylpropanesulfonate and SR-10 of Japan Adike Company), 0.3 part of initiator (ammonium persulfate), film-forming aid (2, 2, 4-trimethyl-1,3-pentanediol monoisobutyrate) 5 parts, pH adjuster (ammonia water) 0.8 part, deionized water 55 parts.

[0030] The preparation method of the acrylate emulsion for the high-gloss finish varnish with the lotus leaf effect comprises the following steps:

[0031] (1) Under normal temperature and pressure conditions, 12 parts of methyl methacry...

Embodiment 2

[0040] An acrylic ester emulsion for a high-gloss water-based finish varnish with a lotus leaf effect, consisting of the following raw materials in parts by weight: 25 parts of methyl methacrylate, 10 parts of isooctyl acrylate, crosslinking monomer (dimethacrylic acid Ethylene glycol ester) 1 part, carboxyl monomer (including methacrylic acid and acrylic acid) 0.8 parts, silicone monomer (including vinyltrimethoxysilane and methacryloxypropyltrimethoxysilane) 1.4 parts , 2.2 parts of emulsifier (including sodium dodecylbenzenesulfonate, sodium 2-acrylamido-2-methylpropanesulfonate and SR-10 of Japan Adike Company), initiator (ammonium persulfate) 0.4 2.5 parts of film-forming aid (2,2,4-trimethyl-1,3-pentanediol monoisobutyrate), 0.7 parts of pH regulator (ammonia water), and 60 parts of deionized water.

[0041] The preparation method of the acrylate emulsion for the high-gloss finish varnish with the lotus leaf effect comprises the following steps:

[0042] (1) Under norma...

Embodiment 3

[0051] An acrylic ester emulsion for a high-gloss water-based finish varnish with a lotus leaf effect, consisting of the following raw materials and parts by weight: 28 parts of methyl methacrylate, 16 parts of isooctyl acrylate, crosslinking monomers (including dimethyl ethylene glycol acrylate and hydroxyethyl methacrylate) 1.5 parts, carboxyl monomer (methacrylic acid) 1.5 parts, silicone monomer (including vinyltrimethoxysilane and methacryloxypropyltrimethoxy base silane) 2 parts, emulsifier (including sodium lauryl sulfate, alkyl polyoxyethylene ether sulfate, 2-acrylamido-2-methyl propane sulfonate and SR-10 from Japan Adike Company ) 1.9 parts, 0.5 parts of initiator (potassium persulfate), 1 part of film-forming aid (2,2,4-trimethyl-1,3-pentanediol monoisobutyrate), pH regulator (ammonia ) 1.05 parts, 65 parts of deionized water.

[0052] The preparation method of the acrylate emulsion for the high-gloss finish varnish with the lotus leaf effect comprises the followi...

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Abstract

The invention discloses an acrylate emulsion for the high-gloss water-based finish varnish with a lotus leaf effect and a preparation method of the acrylate emulsion. The acrylate emulsion is composedof the following raw materials in parts by weight: 20-30 parts of methyl methacrylate, 10-20 parts of isooctyl acrylate, 0.1-3 parts of cross-linking monomers, 1-3 parts of carboxyl monomers, 1-3 parts of organic silicon monomers, 1.1-3 parts of an emulsifier, 0.2-1 part of an initiator, 1-5 parts of a coalescing agent, 0.5-5.5 parts of a pH regulator and 50-65 parts of deionized water. Through aproper core-shell ratio, Tg difference, complete hydrophobicity of a hard core and relative hydrophobicity of a soft shell, a paint film is provided with a structure of ''lotus leaf effect'', and useof inorganic compounds is completely avoided, so that the finish varnish prepared from the emulsion has excellent water resistance, stain resistance, yellowing resistance, stability and universality.

Description

technical field [0001] The invention relates to the technical field of organic polymer polymerization, in particular to an acrylate emulsion for high-gloss water-based finish varnish with lotus leaf effect and a preparation method thereof. Background technique [0002] In recent years, with the development of technology and the improvement of living standards, people's requirements for architectural coatings for exterior walls have become more and more stringent, not only to meet the needs of use, but also to further improve the coatings while controlling costs. All aspects of performance, such as simpler and more convenient construction, more natural and harmonious color, longer service life, better water resistance, easier cleaning and cleaning of surface dust and dirt, etc. The exterior wall coating represented by real stone paint and colorful paint is very popular among users because of its beautiful appearance, natural color, and three-dimensional effect. However, real ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/14C08F220/18C08F222/14C08F220/06C08F230/08C08F220/56C08F222/02C09D133/12C09D5/16
Inventor 朱超唐兵杨文涛
Owner 佛山市顺德区巴德富实业有限公司
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