A kind of transformation method of rare ginsenoside
A kind of ginsenoside, a rare technology, applied in the field of high-efficiency biotransformation of rare ginsenosides, high-speed countercurrent chromatography reactor, can solve the problems of cumbersome steps, undisclosed reverse micellar system, etc., achieve high flexibility, reduce product inhibition effect, The effect of easy operation
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Embodiment 1
[0053] 1. Preparation of reverse micellar solvent system and preparation of sample solution
[0054] Take by weighing certain quality sodium dioctyl succinate sulfonate (AOT), triton (Triton) X-100, dissolve with isooctane, settle to a certain volume, be mixed with total surfactant concentration and be 0.10 mol / L AOT / Triton X-100 / iso-octane solution. Prepare 50 μmol / L β-glucosidase solution with phosphate-potassium dihydrogen phosphate buffer solution with a pH value of 5, in 0.10 mol / L AOT / Add a certain volume of β-glucosidase solution to the Triton X-100 / isooctane reverse micelles system to prepare a certain volume of enzyme-reverse micelles system. The above-mentioned enzyme-reverse micelles system was subjected to saturation partitioning with phosphate-potassium dihydrogen phosphate buffer solution with a pH value of 5, and the upper and lower phases were separated. The upper phase is a stationary phase containing enzyme solution, and 1.2 g / L of ginsenoside Rb1 substrate...
Embodiment 2
[0063] 1. Preparation of reverse micellar solvent system and preparation of sample solution
[0064] Take by weighing certain quality sodium dioctyl succinate sulfonate (AOT), triton (Triton) X-100, dissolve with isooctane, settle to a certain volume, be mixed with total surfactant concentration and be 0.10 mol / L AOT / Triton X-100 / iso-octane solution. Prepare a 50 μmol / L β-glucosidase solution with a phosphate-potassium dihydrogen phosphate buffer solution with a pH value of 5, and add a certain volume of β-glucosidase solution to prepare a certain volume of enzyme-reverse micelles system. The above-mentioned enzyme-reverse micelles system was subjected to saturation partitioning with phosphate-potassium dihydrogen phosphate buffer solution with a pH value of 5, and the upper and lower phases were separated. The upper phase is a stationary phase containing enzyme solution, and 1.5 g / L of ginsenoside Re substrate solution is added below, and part of the blank lower phase solut...
Embodiment 3
[0073] 1. Preparation of reverse micellar solvent system and preparation of sample solution
[0074] Take by weighing certain quality sodium dioctyl succinate sulfonate (AOT), triton (Triton) X-100, dissolve with isooctane, settle to a certain volume, be mixed with total surfactant concentration and be 0.10 mol / L AOT / Triton X-100 / iso-octane solution. Prepare 50 μmol / L β-glucosidase solution with phosphate-potassium dihydrogen phosphate buffer solution with a pH value of 5, in 0.10 mol / L AOT / Add a certain volume of β-glucosidase solution to the Triton X-100 / isooctane reverse micelles system to prepare a certain volume of enzyme-reverse micelles system. The above-mentioned enzyme-reverse micelles system was subjected to saturation partitioning with phosphate-potassium dihydrogen phosphate buffer solution with a pH value of 5, and the upper and lower phases were separated. The upper phase is a stationary phase containing enzyme solution, and 1.0 g / L ginsenoside Rg1 substrate so...
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