Waste circuit board recycling method
A technology for waste circuit boards and circuit boards, which is applied in chemical instruments and methods, water/sludge/sewage treatment, water pollutants, etc., and can solve problems such as a large amount of iron sludge, difficulty in recycling catalysts, and no waste circuit boards , to achieve the effects of reduced metal content, good catalytic degradation performance, and good cycle stability
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Embodiment 1
[0046] The waste circuit board is carbonized after removing the surface components. The carbonization temperature is 800°C and the carbonization time is 100min. The stroke is 10mm, the stroke frequency is 420 times / min, and the flushing water is 0.5 liters / s. The sorted metal-rich components are recovered as products, and the sorted carbon-rich components are added to 0.1mol / L hydrochloric acid solution and stirred 300min, then add 0.1mol / L sodium borohydride solution and stir for 40min, filter and vacuum dry to obtain a carbon-based catalyst loaded with nanometer zero-valent copper.
[0047] The copper-carbon composite catalyst is applied to the catalytic degradation of rhodamine B dye. Add 0.1g / L copper-carbon catalyst to 5mg / L rhodamine B solution, stir for 100min, add 50mmol / L hydrogen peroxide, the temperature is 10℃, pH 3.5, stirring for 60min, the rhodamine B removal rate reached 92.5%, and the first 30min rhodamine B removal rate was 0.082min -1 (first-order reaction ...
Embodiment 2
[0051] The waste circuit board is carbonized after removing the surface components. The carbonization temperature is 500°C and the carbonization time is 600min. The carbonized circuit board is ground to less than 0.1mm, and then sorted on the shaking table. The stroke is 15mm, the stroke frequency is 300 times / min, and the flushing water is 0.1 liter / s. The sorted metal-rich components are recovered as products, and the sorted carbon-rich components are added to 1.5mol / L sulfuric acid solution, and stirred 30min, then add 1mol / L sodium borohydride solution and stir for 180min, filter and vacuum dry to obtain a carbon-based catalyst loaded with nanometer zero-valent copper.
[0052] Copper-carbon composite catalyst is applied to the catalytic degradation of methylene blue dye. Add 5g / L copper-carbon catalyst to 100mg / L methylene blue solution, stir for 90min, add 500mmol / L hydrogen peroxide, temperature is 60℃, pH is 8.5, stir for 300min , the removal rate of methylene blue rea...
Embodiment 3
[0055] The waste circuit board is carbonized after removing the surface components. The carbonization temperature is 600°C and the carbonization time is 240min. °, the stroke is 12mm, the stroke frequency is 360 times / min, and the flushing water is 0.2 liters / s. The sorted metal-rich components are recovered as products, and the sorted carbon-rich components are added to 1.0mol / L nitric acid solution , stirred for 100 min, then added 0.8 mol / L sodium borohydride solution and stirred for 120 min, filtered, and vacuum-dried to obtain a carbon-based catalyst loaded with nanometer zero-valent copper.
[0056] The copper-carbon composite catalyst is applied to the catalytic degradation of rhodamine B dye. Add 0.5g / L copper-carbon catalyst to 10mg / L rhodamine B solution, stir for 50min, add 120mmol / L hydrogen peroxide, the temperature is 50℃, the pH 7.0, stirring for 120min, the removal rate of Rhodamine B reached 98.7%, and the removal rate of Rhodamine B in the first 60min was 0.0...
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