Comprehensive treatment method and device for flue gas
A comprehensive treatment, flue gas technology, applied in the direction of separation methods, chemical instruments and methods, climate sustainability, etc., can solve the problems of long treatment process, high energy consumption and complicated treatment process, and achieve low treatment cost, solid High carbon efficiency and good removal effect
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Embodiment 1
[0052] In the soda residue of oil refining in a certain enterprise, the COD is about 2.83×10 5 mg / L, the sulfide is 1.68×10 4 mg / L, volatile phenol 7.19×10 4 mg / L, the free base is about 2%-3%.
[0053] The flue gas emitted by an enterprise mainly consists of: CO2 content of 14v%, NOx content of 0.06v% (of which NO accounts for 90%), SO 2 The content is 0.04v%.
[0054] Pass the flue gas into the desulfurization absorption tower, use refining alkali slag as the absorbent, circulate and absorb in the desulfurization tower, control the pH of the absorption liquid to 4.5-5.5, when the pH is lower than 4.5, discharge part of the desulfurization absorption liquid, and start Supplement the refining alkali residue, when the pH reaches 5.5, stop supplementing to obtain desulfurization flue gas. The desulfurization absorption liquid is discharged to stand still to recover the oil phase, and the desulfurization waste liquid mainly composed of sodium bisulfite is obtained, and slaked...
Embodiment 2
[0059] In the soda residue of oil refining in a certain enterprise, the COD is about 3.53×10 5 mg / L, sulfide is 2.0×10 4 mg / L, volatile phenol 5.33×10 4 mg / L, the free base is about 2%-3%.
[0060] The flue gas emitted by an enterprise mainly consists of: CO 2 content of 10v%, NOx content of 0.04v% (of which NO accounts for 90%), SO 2 The content is 0.035v%.
[0061] Pass the flue gas into the desulfurization absorption tower, use refining alkali slag as the absorbent, circulate and absorb in the desulfurization tower, control the pH of the absorption liquid to 5-6, when the pH is lower than 5, discharge part of the desulfurization absorption liquid, and start Supplement the refining alkali residue, when the pH reaches 6, stop supplementing to obtain desulfurization flue gas. The desulfurization absorption liquid is discharged to stand still to recover the oil phase, and the desulfurization waste liquid mainly composed of sodium bisulfite is obtained, and slaked lime is a...
Embodiment 3
[0066] In the soda slag of an oil refining enterprise, the COD is about 2.33×10 5 mg / L, the sulfide is 1.28×10 4 mg / L, volatile phenol 4.65×10 4 mg / L, the free base is about 2%-3%.
[0067] The flue gas emitted by an enterprise mainly consists of: CO 2 content of 20v%, NOx content of 0.05v% (of which NO accounts for 90%), SO 2 The content is 0.02v%.
[0068] Pass the flue gas into the desulfurization absorption tower, use refining alkali slag as the absorbent, circulate and absorb in the desulfurization tower, control the pH of the absorption liquid to 5-6, when the pH is lower than 5, discharge part of the desulfurization absorption liquid, and start Supplement the refining alkali residue, when the pH reaches 6, stop supplementing to obtain desulfurization flue gas. The desulfurization absorption liquid is discharged to stand still to recover the oil phase, and the desulfurization waste liquid mainly composed of sodium bisulfite is obtained, and slaked lime is added to c...
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