A kind of fluorine-free antibacterial transparent superhydrophobic coating, preparation method and application thereof
A super-hydrophobic coating, transparent technology, applied in antifouling/underwater coatings, coatings, paints containing biocide, etc., can solve the complex preparation process, harsh preparation method conditions, and few reports on the stability of hydrophobic properties, etc. problem, achieve excellent superhydrophobic performance and antibacterial performance, good mechanical/physical/chemical stability, and ensure the effect of superhydrophobic stability
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Embodiment 1
[0049] A preparation method for a fluorine-free antibacterial transparent superhydrophobic coating, specifically comprising the steps of:
[0050] (1) Preparation of inorganic / organic nanoparticles modified by quaternary ammonium salt silane coupling agent: disperse 0.5g of silica nanoparticles with a size of about 50 nanometers into a mixed solution of 22g of water and 27.28g of absolute ethanol, and then Add 0.22g of dimethyloctadecyl [3-(trimethoxysilyl) propyl] ammonium chloride, stir for 24h and then separate and wash to obtain silica nanometer modified by quaternary ammonium silane coupling agent. particles.
[0051] (2) Preparation of fluorine-free antibacterial transparent superhydrophobic coating: the silica nanoparticles modified by the quaternary ammonium salt silane coupling agent prepared in 0.2g step (1) are dispersed in 150g cyclohexane solution, and then added 0.2g thermoplastic elastomer styrene-ethylene-butylene-styrene block copolymer (SEBS), after mixing u...
Embodiment 2
[0055] A preparation method for a fluorine-free antibacterial transparent superhydrophobic coating, specifically comprising the steps of:
[0056] (1) Preparation of inorganic / organic nanoparticles modified by quaternary ammonium salt silane coupling agent: disperse 0.05g of titanium dioxide nanoparticles with a size of about 200 nanometers into a mixed solution of 22g of water and 27.8g of absolute ethanol, and then add 0.15 g dimethyloctadecyl[3-(trimethoxysilyl)propyl]ammonium bromide, stirred for 36 hours, separated and washed to obtain titanium dioxide nanoparticles modified with quaternary ammonium salt silane coupling agent.
[0057] (2) Preparation of fluorine-free antibacterial transparent superhydrophobic coating: 0.0453g of titanium dioxide nanoparticles modified by quaternary ammonium salt silane coupling agent prepared in step (1) were dispersed into 150.3237g of cyclohexane solution, and then 0.031 g thermoplastic elastomer styrene-ethylene-butylene-styrene block...
Embodiment 3
[0061] A preparation method for a fluorine-free antibacterial transparent superhydrophobic coating, specifically comprising the steps of:
[0062] (1) Preparation of inorganic / organic nanoparticles modified by quaternary ammonium salt silane coupling agent: disperse 1.5g of silica nanoparticles with a size of about 900 nm into a mixed solution of 18g of water and 23g of absolute ethanol, and then add 3.5 g dimethyltetradecyl[3-(trimethoxysilyl)propyl]ammonium chloride and 4g dimethyloctadecyl[3-(trimethoxysilyl)propyl]ammonium bromide A mixed quaternary ammonium salt silane coupling agent, stirred for 32 hours, separated and washed to obtain silica nanoparticles modified by a quaternary ammonium salt silane coupling agent.
[0063] (2) Preparation of fluorine-free antibacterial transparent superhydrophobic coating: disperse the silica nanoparticles modified by the quaternary ammonium salt silane coupling agent prepared in 14.81g step (1) into 30.78g dichloromethane and 90g n-h...
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