A kind of fluorine-free antibacterial transparent superhydrophobic coating, preparation method and application thereof

A super-hydrophobic coating, transparent technology, applied in antifouling/underwater coatings, coatings, paints containing biocide, etc., can solve the complex preparation process, harsh preparation method conditions, and few reports on the stability of hydrophobic properties, etc. problem, achieve excellent superhydrophobic performance and antibacterial performance, good mechanical/physical/chemical stability, and ensure the effect of superhydrophobic stability

Active Publication Date: 2020-10-13
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, its preparation process is complicated and there are many steps
[0006] In addition, with the rapid development of stretchable and stretchable functional materials such as flexible electronic devices, sensors, textiles, and filter membranes, superhydrophobic surfaces can The stability of the hydrophobic properties of
Tesler et al. (Nature Communication, 2015, 6, 8649.) used electrodeposition to deposit nanoporous tungsten oxide onto the steel surface, and prepared a superhydrophobic steel material that can withstand 10 times of 180° bending deformation without losing superhydrophobic properties. The preparation process requires complex equipment and special substrates, which is not universal
[0007] Although a large number of methods and processes have been used for the development of mechanically stable superhydrophobic surfaces, the existing preparation methods have problems such as harsh conditions, complicated preparation process, not enough green environmental protection, single choice of substrate, and limited application range.

Method used

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  • A kind of fluorine-free antibacterial transparent superhydrophobic coating, preparation method and application thereof
  • A kind of fluorine-free antibacterial transparent superhydrophobic coating, preparation method and application thereof
  • A kind of fluorine-free antibacterial transparent superhydrophobic coating, preparation method and application thereof

Examples

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Effect test

Embodiment 1

[0049] A preparation method for a fluorine-free antibacterial transparent superhydrophobic coating, specifically comprising the steps of:

[0050] (1) Preparation of inorganic / organic nanoparticles modified by quaternary ammonium salt silane coupling agent: disperse 0.5g of silica nanoparticles with a size of about 50 nanometers into a mixed solution of 22g of water and 27.28g of absolute ethanol, and then Add 0.22g of dimethyloctadecyl [3-(trimethoxysilyl) propyl] ammonium chloride, stir for 24h and then separate and wash to obtain silica nanometer modified by quaternary ammonium silane coupling agent. particles.

[0051] (2) Preparation of fluorine-free antibacterial transparent superhydrophobic coating: the silica nanoparticles modified by the quaternary ammonium salt silane coupling agent prepared in 0.2g step (1) are dispersed in 150g cyclohexane solution, and then added 0.2g thermoplastic elastomer styrene-ethylene-butylene-styrene block copolymer (SEBS), after mixing u...

Embodiment 2

[0055] A preparation method for a fluorine-free antibacterial transparent superhydrophobic coating, specifically comprising the steps of:

[0056] (1) Preparation of inorganic / organic nanoparticles modified by quaternary ammonium salt silane coupling agent: disperse 0.05g of titanium dioxide nanoparticles with a size of about 200 nanometers into a mixed solution of 22g of water and 27.8g of absolute ethanol, and then add 0.15 g dimethyloctadecyl[3-(trimethoxysilyl)propyl]ammonium bromide, stirred for 36 hours, separated and washed to obtain titanium dioxide nanoparticles modified with quaternary ammonium salt silane coupling agent.

[0057] (2) Preparation of fluorine-free antibacterial transparent superhydrophobic coating: 0.0453g of titanium dioxide nanoparticles modified by quaternary ammonium salt silane coupling agent prepared in step (1) were dispersed into 150.3237g of cyclohexane solution, and then 0.031 g thermoplastic elastomer styrene-ethylene-butylene-styrene block...

Embodiment 3

[0061] A preparation method for a fluorine-free antibacterial transparent superhydrophobic coating, specifically comprising the steps of:

[0062] (1) Preparation of inorganic / organic nanoparticles modified by quaternary ammonium salt silane coupling agent: disperse 1.5g of silica nanoparticles with a size of about 900 nm into a mixed solution of 18g of water and 23g of absolute ethanol, and then add 3.5 g dimethyltetradecyl[3-(trimethoxysilyl)propyl]ammonium chloride and 4g dimethyloctadecyl[3-(trimethoxysilyl)propyl]ammonium bromide A mixed quaternary ammonium salt silane coupling agent, stirred for 32 hours, separated and washed to obtain silica nanoparticles modified by a quaternary ammonium salt silane coupling agent.

[0063] (2) Preparation of fluorine-free antibacterial transparent superhydrophobic coating: disperse the silica nanoparticles modified by the quaternary ammonium salt silane coupling agent prepared in 14.81g step (1) into 30.78g dichloromethane and 90g n-h...

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Abstract

The present invention is directed to the problems existing in the prior art, and provides a fluorine-free antibacterial transparent superhydrophobic coating and a preparation method thereof. The fluorine-free antibacterial transparent superhydrophobic coating provided by the invention comprises inorganic / organic nanoparticles modified by quaternary ammonium salt silane coupling agent, a thermoplastic elastomer and an organic solvent. The preparation method has the advantages of simple process, mild conditions and no complicated equipment. The coating can be applied to various substrates by spraying, dipping, etc., including hard substrates such as glass and polymer films, and soft substrates such as textiles and rubber. The resulting superhydrophobic coating has excellent mechanical / physical / chemical stability, antibacterial properties and superhydrophobicity.

Description

technical field [0001] The invention relates to a paint and its preparation method and application, in particular to a fluorine-free antibacterial transparent super-hydrophobic paint, its preparation method and its application. Background technique [0002] A superhydrophobic surface refers to a surface with a water contact angle greater than 150° and a rolling angle less than 10°, which usually has two characteristics including micro / nanoscale surface structure and low surface energy chemical composition. Due to their great applications in self-cleaning, anti-icing, drag reduction, oil-water separation, etc., superhydrophobic surfaces have attracted great attention from material researchers. Many methods including template method, coating method, etching method, photolithography method, and plasma treatment method have been reported for the preparation of superhydrophobic surfaces, but most of the superhydrophobic surfaces prepared by these methods do not have sufficient st...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D153/02C09D5/14C09D7/62
CPCC08K2201/011C08L2201/10C09D5/14C09D7/62C09D153/025C08K9/06C08K3/36
Inventor 王玉忠王芳宋飞皮静
Owner SICHUAN UNIV
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