Bicontinuous phase micro-emulsion, preparation method thereof, drilling fluid containing micro-emulsion and preparation method thereof

A dual-continuous phase and microemulsion technology is applied to drilling fluid and its preparation, and its preparation, in the field of dual-continuous phase microemulsion, can solve the problems of complicated procedures, increased cost, increased environmental pollution, etc., and achieves good inhibition and easy removal. , Easy to remove oil effect

Active Publication Date: 2019-07-05
SOUTHWEST PETROLEUM UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In order to solve the problem that even if the most advanced reversible emulsified drilling fluid is used in the prior art, it still needs to add special chemical additives to modify it, and special equipment is needed to solve the problem of temperature control, speed control and anti-corrosion of the acid liquid delivery system. For the problems of increased cost, complicated procedures, and increased environmental pollution, the present invention provides a dual-continuous phase microemulsion, its preparation method, and a drilling fluid containing the microemulsion and its preparation method. The purpose of realization is to obtain a Good viscoelasticity, high dynamic shear force, low plastic viscosity dual-continuous phase microemulsion, the drilling fluid prepared by using this microemulsion can avoid bit sticking, effectively inhibit the hydration expansion of shale formation, and thus benefit the borehole wall Stable and at the same time easily removed by neutral aqueous solutions

Method used

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  • Bicontinuous phase micro-emulsion, preparation method thereof, drilling fluid containing micro-emulsion and preparation method thereof
  • Bicontinuous phase micro-emulsion, preparation method thereof, drilling fluid containing micro-emulsion and preparation method thereof
  • Bicontinuous phase micro-emulsion, preparation method thereof, drilling fluid containing micro-emulsion and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0034] Embodiment 1: a kind of double continuous phase microemulsion provided by the present invention, raw material comprises emulsifier, water-soluble acid, oil phase, and water phase, and emulsifier is amine nonionic emulsifier, and water-soluble acid is hydrochloric acid, acetic acid , propionic acid mixture, the oil phase is a mixture of mineral oil and diesel oil, and the water phase is a mixture of seawater, organic salt brine such as ammonium salt;

[0035] The hydrophilic-lipophilic balance value of the amine nonionic emulsifier is 4 to 6, and has the general molecular structure formula shown in Formula 1;

[0036]

[0037] In formula 1, R is a hydrophobic carbon chain with a chain length of C8-C20, containing at least one unsaturated bond, R' is H, C 1 、C 2 or C 3 , A is O or NH, 1≤m+n≤3.

[0038] For example, the emulsifier is an ethoxylated higher fatty alkylamine, which has a general molecular structure formula shown in Formula 2;

[0039]

[0040] In fo...

Embodiment 2

[0048] Embodiment two: a kind of bicontinuous phase microemulsion provided by the present invention, raw material comprises emulsifier, water-soluble acid, oily phase, and water phase, and emulsifier is amine nonionic emulsifier, and water-soluble acid is lactic acid, halogen Acetic acid and glycolic acid are mixed, the oil phase is a mixture of gas oil and synthetic base liquid, the water phase is a mixture of inorganic salt brine such as sodium chloride, and a water phase containing water-soluble organics such as glycerol;

[0049] The hydrophilic-lipophilic balance value of the amine nonionic emulsifier is 4 to 6, and has the general molecular structure formula shown in Formula 1;

[0050]

[0051] In formula 1, R is a hydrophobic carbon chain with a chain length of C8-C20, containing at least one unsaturated bond, R' is H, C 1 、C 2 or C 3 , A is O or NH, 1≤m+n≤3.

[0052] For example, the emulsifier is aliphatic propylene diamine, which has a molecular structure gene...

Embodiment 3

[0061] Embodiment three: a kind of dual continuous phase microemulsion provided by the present invention, raw material comprises emulsifier, water-soluble acid, oil phase and water phase, emulsifier is amine nonionic emulsifier, water-soluble acid is tartaric acid, oil The phase is mineral oil, and the water phase is a mixture of inorganic salt brine such as calcium chloride and sea water;

[0062] The hydrophilic-lipophilic balance value of the amine nonionic emulsifier is 4 to 6, and has the general molecular structure formula shown in Formula 1;

[0063]

[0064] In formula 1, R is a hydrophobic carbon chain with a chain length of C8-C20, containing at least one unsaturated bond, R' is H, C 1 、C 2 or C 3 , A is O or NH, 1≤m+n≤3.

[0065] For example, the emulsifier is an ethoxylated higher fatty alkylamine, which has a general molecular structure formula shown in Formula 2;

[0066]

[0067] In formula 2, R is a hydrophobic carbon chain, containing at least one un...

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Abstract

The invention provides a bicontinuous phase micro-emulsion which comprises an emulsifier, a water soluble acid, an oil phase and a water phase. The emulsifier is an amine nonionic emulsifier. The invention further discloses a drilling fluid containing the micro-emulsion. The drilling fluid comprises the micro-emulsion, an oil base stabilizer, organic soil and a weighing material. The invention further discloses a preparation method of the micro-emulsion and the drilling fluid. The method comprises the steps that other raw materials are mixed, the water soluble acid is added for induction to obtain the bicontinuous phase micro-emulsion and the drilling fluid, or the other raw materials and the water soluble acid are mixed at first to obtain the bicontinuous phase micro-emulsion, a drillingfluid additive is added, and the bicontinuous drilling fluid is obtained. The bicontinuous phase micro-emulsion has the advantages that the unique oil phase and water phase bicontinuous characteristics, high shearing force, low plastic viscosity and viscoelasticity rheologic characteristics are achieved, the advantages of the oil phase and water phase drilling fluids can be shown at the same timewhen the micro-emulsion is used for the drilling fluid, and the water power transmission, suspension, rock debris carrying and well cleaning capability of the drilling fluid are enhanced.

Description

technical field [0001] The invention belongs to the field of oilfield chemistry and colloid technology, in particular to a dual continuous phase microemulsion, a preparation method thereof, a drilling fluid containing the microemulsion and a preparation method thereof. Background technique [0002] During the drilling process, the drilling fluid reaches the formation through the drill string, then is sprayed out by the drill bit into the annular space between the drill string and the well wall, and finally returns to the ground. During this process, the drilling fluid mainly provides the functions of suspending and carrying cuttings, balancing formation pressure and stabilizing the well wall, cooling and lubricating the drill bit and drilling tools, transmitting hydrodynamic force, etc., and minimizing the impact on oil and gas reservoirs and the ecological environment, etc. , Therefore, the drilling fluid is called the blood of drilling. [0003] In the prior art, commonly...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/36C07C233/78C07C231/02C07C231/14
CPCC07C231/02C07C231/14C09K8/36C09K2208/30C07C233/78
Inventor 任妍君任泽琛王浩男张颖耿一然伍连松
Owner SOUTHWEST PETROLEUM UNIV
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