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Antirust oil used for magnesium alloy and preparation method of antirust oil

A technology of anti-rust oil and magnesium alloy, applied in the petroleum industry, lubricating composition, etc., to achieve the effect of excellent anti-rust protection, long duration of effect and high flash point

Inactive Publication Date: 2019-08-30
上海正玺新材料科技有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are very few anti-rust oils specially developed for magnesium alloys on the market at present. Based on this, the present invention provides a kind of anti-rust oil for magnesium alloys and its preparation method. The product has excellent anti-rust and anti-corrosion effects, and can realize Industrial mass production

Method used

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  • Antirust oil used for magnesium alloy and preparation method of antirust oil

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Experimental program
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Effect test

Embodiment 1

[0033] This embodiment relates to a kind of antirust oil for magnesium alloy and its preparation method;

[0034] The raw material ratio of the anti-rust oil is: 40% of paraffin-based 150SN mineral oil, 40% of dibutyl sebacate, 3% of benzotriazole derivatives, 2,6-di-tert-butyl p-cresol 2 %, compound anti-rust additive 15%.

[0035] The composite antirust additive is a mixture of low base value synthetic calcium sulfonate, 12 alkenyl succinate and 17 imidazolinyl succinate with a mass dosage ratio of 3:0.2:0.8.

[0036] The preparation method is: in the base liquid (paraffin base MVI 150 base oil), add polyol ester synthetic base oil (dibutyl sebacate), benzotriazole derivatives, 2,6-di-tert-butyl p-cresol and composite anti-rust additives are dispersed at 40°C for 80 minutes by high-speed stirring at a speed of 2000-3200rpm / min to obtain a highly refined colloidal solution; the solution is heated to 70°C and dynamically mixed The device dispersion was prepared in base oil (...

Embodiment 2

[0038] This embodiment relates to a kind of antirust oil for magnesium alloy and its preparation method;

[0039] The raw material ratio of the anti-rust oil is: 60% of paraffin-based 75SN mineral oil, 29.5% of pentaerythritol palm kernel ester, 3% of benzotriazole derivatives, 2% of thiadiazole derivatives, 2,6-ditertiary 0.5% butyl p-cresol, 5% compound anti-rust additive.

[0040] The composite antirust additive is a mixture of low base value synthetic calcium sulfonate, 12 alkenyl succinate and 17 imidazolinyl succinate with a mass dosage ratio of 2.2:0.1:0.4.

[0041] The preparation method is: in the base liquid (paraffin-based 75SN mineral oil), pentaerythritol palm kernel ester, benzotriazole derivatives, thiadiazole derivatives, 2,6-di-tert-butyl p-cresol, compound anti-corrosion Rust additives, at the same time at a temperature of 60 ° C, dispersed by high-speed machinery at a speed of 1600-3000 rpm / min for 100 minutes to obtain a highly refined colloidal solution; ...

Embodiment 3

[0043] This embodiment relates to a kind of antirust oil for magnesium alloy and its preparation method;

[0044] The raw material ratio of the anti-rust oil is: 60% of paraffin-based 75SN mineral oil, 20% of polyol ester synthetic base oil (pentaerythritol oleate), 1% of benzotriazole derivatives, 1% of thiadiazole derivatives 2%, 2,6-di-tert-butyl-p-cresol 2%, dehydrated polyol oleate (Span-80) 5%, composite anti-rust additive 10%.

[0045] The composite antirust additive is a mixture of low base value synthetic calcium sulfonate, 12 alkenyl succinate and 17 imidazolinyl succinate with a mass dosage ratio of 6:0.3:1.6.

[0046] The preparation method is: in the base liquid (paraffin-based 75SN mineral oil), synthesize polyol ester base oil (pentaerythritol oleate), benzotriazole derivatives, thiadiazole derivatives, 2,6-bis tert-butyl p-cresol, dehydrated polyol oleate (Span-80), compound anti-rust additive, and at the same time, disperse at 80°C for 120 minutes by high-spe...

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Abstract

The invention discloses antirust oil used for a magnesium alloy and a preparation method of the antirust oil. The antirust oil mainly comprises a benzotriazole derivative, di-tert-butyl-p-cresol, a composite rust inhibitor, mineral base oil and ester synthetic oil; and when the antirust oil is prepared, a colloidal solution containing the composite rust inhibitor is prepared by the steps of addinga certain amount of a dispersing agent and a diluent and performing high-speed mechanical dispersion, after the solution is dispersed into base oil, a dense physical adsorption film can be formed atthe surface of the magnesium alloy, and the adsorption film has excellent oxidation stability and chemical stability. The antirust oil provided by the invention has excellent antirust protection effects, thereby avoiding performance change of the magnesium alloy due to corrosion, rusting and other factors; the antirust oil is weakly alkaline, and avoids a chemical reaction on the surface of the magnesium alloy, so that the antirust oil does not cause erosion to a substrate body and does not have related environmental problems; and the antirust oil contains ester synthetic base oil, has smallerevaporation loss and a higher flash point, is not easy to burn, and is safe, easy and convenient to use and operate.

Description

technical field [0001] The invention relates to the field of surface treatment of metal materials, in particular to an antirust oil for treating magnesium alloy materials and a preparation method thereof. Background technique [0002] Magnesium alloy is known as "the green material facing the 21st century". It has abundant reserves, low density, high specific strength, easy cutting, good damping and shock absorption and electromagnetic protection performance. It has great potential in the fields of automobile, 3C and aerospace. Broad application prospects. However, magnesium is an active metal with poor corrosion resistance, which limits its wide application. Therefore, various surface protection technologies related to it have also obtained considerable development. These technologies include anodic oxidation, surface spray coating, chemical conversion coating, surface laser protection and micro-arc oxidation, etc., but most of these technologies are only applicable to the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10M169/04C10N30/12C10N30/02
CPCC10M169/04C10M2203/1006C10M2207/026C10M2207/282C10M2207/2825C10M2207/283C10M2207/2835C10M2215/223C10M2215/224C10M2219/044C10M2219/106C10N2010/04C10N2030/02C10N2030/12
Inventor 李云良谭戈廖顺知董斌斌任兵
Owner 上海正玺新材料科技有限公司