Biodegradable Mg-Zn-Cu laminar composite and preparing method thereof
A layered composite material, mg-zn-cu technology, applied in the field of biodegradable Mg-Zn-Cu layered composite materials and its preparation, can solve the problems of slow degradation, fast corrosion, high elastic modulus, etc., to achieve Ease of mass production, low cost, good mechanical properties and corrosion resistance
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Embodiment 1
[0068] This example provides a biodegradable Mg-Zn-Cu layered composite material, which has an outer layer, a middle layer and an inner layer connected in sequence, the outer layer is a copper alloy, and the middle layer is a zinc alloy. The inner layer is a magnesium alloy, and the composite material includes the following components in volume percentage:
[0069] 10-25% of the copper alloy,
[0070] 20-35% of the zinc alloy,
[0071] The balance is the magnesium alloy.
[0072] The composite material in this example has a total of 3-layer structure, namely the inner layer, the middle layer and the outer layer. The form of the 3-layer structure makes the composite material have a more complete functional level, and each layer in the composite material is made of alloy , Compared with pure metals, alloys have better performance and use effects. The elements used in each layer alloy of the composite material of the present application are Ca, Zr and Sr, and each layer alloy ...
Embodiment 2
[0074] This example provides a biodegradable Mg-Zn-Cu layered composite material, which has an outer layer, a middle layer and an inner layer connected in sequence, the outer layer is a copper alloy, and the middle layer is a zinc alloy. The inner layer is a magnesium alloy, and the composite material includes the following components in volume percentage:
[0075] 10-25% of the copper alloy, 20-35% of the zinc alloy and the rest of the magnesium alloy.
[0076] Wherein, the copper alloy includes at least one alloying element in Ca, Zr and Sr, specifically:
[0077] Ca 0.1-3.5%, and / or Zr 0.1-1.5%, and / or Sr 0.1-5.0%, and the balance is Cu.
[0078] As a preferred version, the copper alloy comprises the following components in mass percent:
[0079] Ca 0.3-0.8%, Zr 0.3-0.8%, Sr 1.0-2.0%, and the balance is Cu.
[0080] Zinc alloys include at least one alloying element of Ca, Zr and Sr, specifically:
[0081] Ca 0.1-3.5%, and / or Zr 0.1-1.5%, and / or Sr 0.1-5.0%, and the bala...
Embodiment 3
[0089] This example provides the preparation method of biodegradable Mg-Zn-Cu layered composite material, and the steps include:
[0090] After melting the zinc alloy, casting it into the copper alloy hollow round ingot to obtain a Zn-Cu composite material round ingot;
[0091] Processing the Zn-Cu composite ingot into a Zn-Cu hollow ingot;
[0092] After melting the magnesium alloy, casting it into the Zn-Cu hollow round ingot to obtain a Mg-Zn-Cu composite material round ingot;
[0093] The Mg-Zn-Cu composite ingot is hot-extruded and then annealed to obtain the biodegradable Mg-Zn-Cu layered composite material.
[0094] Among them, the preparation method of the copper alloy hollow round ingot is as follows: under vacuum conditions, argon gas is introduced as a protective atmosphere, the copper alloy is heated to 550-650 ° C, melted, mechanically stirred for 5-10 minutes, and then allowed to stand for 3-5 minutes. Then cast it into a stainless steel mold at 600°C to obtain...
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