Lead-removal nontoxic environment-friendly PVC (polyvinyl chloride) profile raw material formula and preparation method

A non-toxic and environmentally friendly, PVC resin technology, applied in the field of building materials, can solve the problems of polluting the environment, failing to achieve, and failing to achieve environmental protection

A non-toxic and environmentally friendly, PVC resin technology, applied in the field of building materials, can solve the problems of polluting the environment, failing to achieve, and failing to achieve environmental protection

CN110240768AInactive Publication Date: 2019-09-17WUHAN YIHUA PLASTIC IND CO LTD
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  • Lead-removal nontoxic environment-friendly PVC (polyvinyl chloride) profile raw material formula and preparation method
  • Lead-removal nontoxic environment-friendly PVC (polyvinyl chloride) profile raw material formula and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] S1. Selection and weighing of raw materials: First, measure 55 parts of PVC resin, 7 parts of fatty acid heat stabilizer, 3 parts of light stabilizer, 3 parts of polyol ingredients, and 3 parts of phosphorous acid by weighing equipment ester, 7 parts of organotin heat stabilizer and 3 parts of antioxidant, and store the measured components through the storage tank for preparation. The fatty acid heat stabilizer is organic fatty acid, naphthenic acid, oleic acid, benzene A composition of formic acid and salicylic acid, a polyol ingredient of glycerin, trimethylolethane, pentaerythritol, xylitol and sorbitol, a light stabilizer of carbon black, zinc oxide and titanium dioxide, an antioxidant For the composition of tea polyphenols and butylated hydroxyanisole:

[0032]S2. Preparation of composite heat stabilizer: Add the fatty acid heat stabilizer, polyol ingredients and phosphite measured in step S1 into the mixing and stirring equipment in sequence, and stir for 35 minut...

Embodiment 2

[0037] S1. Selection and weighing of raw materials: First, measure 50 parts of PVC resin, 10 parts of fatty acid heat stabilizer, 5 parts of light stabilizer, 5 parts of polyol ingredients, and 5 parts of phosphorous acid by weighing equipment ester, 10 parts of organotin heat stabilizer and 5 parts of antioxidant, and store the measured components through storage tanks for preparation. The fatty acid heat stabilizer is a composition of organic fatty acid and salicylic acid. The alcohol ingredient is a composition of glycerin and sorbitol, the light stabilizer is a composition of carbon black and titanium dioxide, and the antioxidant is tea polyphenols:

[0038] S2. Preparation of composite heat stabilizer: Add the fatty acid heat stabilizer, polyol ingredients and phosphite measured in step S1 into the mixing and stirring equipment in sequence, and stir for 30 minutes at a speed of 400r / min and a temperature of 30°C. , capable of forming a heat stabilizer mixture, then adding...

Embodiment 3

[0043] S1. Selection and weighing of raw materials: First, measure 60 parts of PVC resin, 5 parts of fatty acid heat stabilizer, 1 part of light stabilizer, 1 part of polyol ingredients, and 1 part of phosphorous acid by weighing equipment ester, 5 parts of organotin heat stabilizer and 1 part of antioxidant, and store the measured components through storage tanks for preparation. The fatty acid heat stabilizer is organic fatty acid, and the polyol ingredient is glycerol, which is light stable The agent is carbon black, and the antioxidant is butyl hydroxyanisole:

[0044] S2. Preparation of composite heat stabilizer: Add the fatty acid heat stabilizer, polyol ingredients and phosphite measured in step S1 into the mixing and stirring equipment in sequence, and stir for 40 minutes at a speed of 600r / min and a temperature of 35°C. , capable of forming a heat stabilizer mixture, then adding the organotin heat stabilizer measured in step S1 to the heat stabilizer mixture, stirring...

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Abstract

The invention discloses a lead-removal nontoxic environment-friendly PVC (polyvinyl chloride) profile raw material formula and a preparation method. The formula comprises the following raw materials in parts by weight: 50-60 parts of a PVC resin, 5-10 parts of a fatty acid thermal stabilizer, 1-5 parts of a light stabilizer, 1-5 parts of a polyhydric alcohol material, 1-5 parts of phosphite ester, 5-10 parts of an organic tin thermal stabilizer and 1-5 parts of an antioxidant. By adopting the lead-removal nontoxic environment-friendly PVC profile raw material formula and the preparation method, a conventional toxic and environment-harmful thermal stabilizer can be replaced by a leadless nontoxic environment-friendly composite thermal stabilizer, production processing of a PVC material is implemented with an organic composite thermal stabilizer, then the purpose of a PVC environment-friendly effect can be achieved, the material is nontoxic and friendly to the environment, the purpose of environment protection can be very well achieved, and the prepared PVC material does not pollute the environment in the waste treatment process, and has beneficial effects on production and use of PVC profiles.

Description

technical field [0001] The invention relates to the technical field of building materials, in particular to a raw material formula and a preparation method of a lead-removing, non-toxic and environment-friendly PVC profile. Background technique [0002] PVC is a white powder with an amorphous structure, a small degree of branching, a relative density of about 1.4, a glass transition temperature of 77-90°C, and begins to decompose at about 170°C. It has poor stability to light and heat. When exposed to sunlight, it will decompose to produce hydrogen chloride, and further autocatalyze the decomposition, causing discoloration and rapid decline in physical and mechanical properties. In practical applications, stabilizers must be added to improve the stability to heat and light. [0003] PVC heat stabilizer should be a multifunctional substance, or a mixture of some materials, which can achieve the following functions: one is to replace active and unstable substituents; the other...

Claims

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Application Information

Patent Timeline
17 Sep 2019
Publication
CN110240768A
IPC
C08L27/06; C08K13/02; C08K5/09; C08K5/13; C08K5/053; C08K3/04; C08K3/22; C08K5/1545
CPC
C08K3/04; C08K3/22; C08K5/053; C08K5/09; C08K5/13; C08K5/1545; C08K13/02; C08K2003/2241
Inventors
邓伟玲; 唐化武