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Indium-doped N-type organic thin-film transistor and preparation method thereof

An organic thin film and transistor technology, which is applied in the field of indium-doped N-type organic thin-film transistor and its preparation, can solve the problems of limiting the development of flexible electronic devices and organic integrated circuits, high mobility, and shortage of N-type semiconductor materials, etc. Improved switching ratio and carrier mobility, low cost, and improved electrical performance

Active Publication Date: 2019-09-20
EAST CHINA NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there is an extreme shortage of N-type semiconductor materials with high mobility, air stability, and solution preparation, which greatly limits the development of flexible electronic devices and organic integrated circuits based on organic thin film transistors.

Method used

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  • Indium-doped N-type organic thin-film transistor and preparation method thereof
  • Indium-doped N-type organic thin-film transistor and preparation method thereof
  • Indium-doped N-type organic thin-film transistor and preparation method thereof

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Experimental program
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Embodiment

[0058] A1: Configuration of semiconductor solution

[0059] The N-type organic semiconductor material and the organic solvent are configured at a mass volume ratio of 8 mg / ml; wherein, the N-type organic semiconductor material is: [N,N'-bis(2-octyldodecyl)-1 , 4,5,8-naphthalene diimide-2,6-two bases-and-5,5'-(2,2'-bithiophene)] polymer (N2200); the organic solvent is chlorobenzene ;

[0060] A2: Configuration of insulating layer solution

[0061] The insulating layer material and the highly soluble organic solvent are configured with a mass volume ratio of 80mg / ml; wherein, the insulating layer material is polymethacrylate (PMMA); the highly soluble organic solvent is methyl acetate ester;

[0062] A3: Dissolution of the solution

[0063] Place the configured semiconductor solution and insulating layer solution on the heating plate at 60°C for 24 hours to dissolve;

[0064] Step 2: Preparation of Devices

[0065] B1: Cleaning of the substrate

[0066] Select an insulati...

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Abstract

The invention discloses an indium-doped N-type organic thin-film transistor and a preparation method thereof. The N-type organic thin-film transistor has a top gate bottom contact structure. The preparation method comprises the following steps: firstly, preparing a layer of gold on a glass substrate through a mask plate to serve as a source electrode and a drain electrode; secondly preparing a layer of indium on a gold electrode to serve as a doped layer; thirdly forming an N-type organic semiconductor active layer on the surface of a sample subjected to electrode preparation by using a sol-gel method; fourthly spin-coating an active layer with a layer of dielectric material to serve as an insulating layer; and finally, preparing aluminum on the surface of the insulating layer through the mask plate to form a gate electrode. Compared with a traditional organic thin-film transistor, the organic thin-film transistor prepared by the method has the advantages that the switching ratio and the carrier mobility are obviously improved, and the subthreshold swing amplitude and the threshold voltage of a device are greatly reduced. The method improves the electrical property of the N-type organic thin-film transistor with the top gate bottom contact structure, and has the characteristics of low cost, simple process steps and wide applicability to the N-type organic thin-film transistor.

Description

technical field [0001] The invention relates to the fields of microelectronic materials and device technology, information display and the like, in particular to an indium-doped N-type organic thin film transistor and a preparation method thereof. Background technique [0002] The use of organic semiconductors as active layers in thin-film transistors has received widespread attention in the past three decades. Compared with field-effect transistors using inorganic semiconductors, organic thin-film transistors using conjugated polymers, low polymers, and fused aromatics as semiconductor materials There are special advantages, for example, it can be used in the production of large-area, flexible, low-temperature processing (close to room temperature), low-cost and transparent new thin film transistors. Organic thin film transistors can be used in active matrix flat-panel displays, organic electroluminescent diodes and "electronic paper" displays, as well as stickable sensors,...

Claims

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Application Information

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IPC IPC(8): H01L51/40H01L51/05
CPCH10K71/30H10K10/464
Inventor 李文武许洋黄凡铭潘哲成胡志高褚君浩
Owner EAST CHINA NORMAL UNIV
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