Method for modifying oil and fat and application of method
A grease and modification technology, applied in the field of grease modification, can solve the problems of high price of polyisocyanate, increase of agricultural production cost, unfavorable cost control, etc., achieve strong hydrophobicity, beneficial to cost control, and short preparation cycle Effect
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Embodiment 1
[0088] A method for modifying grease, comprising the steps of:
[0089] Take 80mL of waste oil (acid value 46.45mgKOH / g, water mass fraction less than 5%), and use an air source ozone machine to continuously inject ozone at a flow rate of 10g / h for 5h at 20-30°C to obtain ozonated waste oil ;
[0090] 2) Preparation of modified ozonated waste oil:
[0091] Add CuSO to 30mL ozonated waste oil 4 , to get the reaction solution, CuSO in the reaction solution 4 The concentration was 0.033 mol / L, and the reaction solution was heated at 120°C for 12 hours to obtain modified ozonated waste oil.
[0092] In order to clarify the effect of heating and adding catalyst on the structure of ozonated waste oil, the infrared comparison of ozonated waste oil and modified ozonated waste oil was carried out, and the results are as follows figure 1 shown. Depend on figure 1 It can be seen that compared with the ozonated waste oil, the modified ozonated waste oil is 3699cm -1 The absorption ...
Embodiment 2~5
[0094] The preparation method of Examples 2-5 is the same as that of Example 1, except that the heating time of the ozonated waste oil in Step 2) of Examples 2-5 is 24h, 36h, 48h, and 60h, respectively.
Embodiment 6
[0096] A method for modifying grease, comprising the steps of:
[0097] Take 80mL of waste oil (acid value 46.45mgKOH / g, water mass fraction less than 5%), and use an air source ozone machine to continuously inject ozone at a flow rate of 10g / h for 5h at 20-30°C to obtain ozonated waste oil ;
[0098] 2) Preparation of modified ozonated waste oil:
[0099] Add Fe to 30mL ozonated waste oil 2 (SO 4 ) 3 , to get the reaction solution, Fe in the reaction solution 2 (SO 4 ) 3 The concentration is 0.033mol / L, and then the reaction solution is heated at 120°C for 12 hours to obtain modified ozonated waste oil.
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