Adhesive composition and adhesive film
A technology of adhesives and compositions, applied in the direction of adhesives, amide/imide polymer adhesives, adhesive types, etc., can solve the problem of re-operability, durability and curl resistance of the adhesive layer at the same time , Insufficient durability, etc., to achieve excellent reworkability or durability, excellent dent resistance, and good coating properties
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Embodiment 1
[0131] Nitrogen gas was introduced into a reaction apparatus equipped with a reaction vessel, a stirrer, a thermometer, a reflux condenser, and a nitrogen delivery pipe, and the air in the reaction vessel was replaced with nitrogen gas. Then, 50 parts by weight of isononyl acrylate, 35 parts by weight of butyl acrylate, 10 parts by weight of methyl acrylate, 0.2 parts by weight of 8-hydroxyoctyl acrylate, 5 parts by weight of benzyl acrylate and a solvent (ethyl acetate) were added to the reaction vessel. ester) 60 parts by weight. Then, 0.1 part by weight of azobisisobutyronitrile as a polymerization initiator was added dropwise over 2 hours, and the mixture was reacted at 65°C for 6 hours to obtain the acrylic polymer solution of Example 1.
Embodiment 2~8 and comparative example 1~5
[0133] Examples were carried out in the same manner as in Example 1 above, except that the types and blending ratios of the monomers constituting the acrylic polymer were respectively as shown in the descriptions of Groups (A) to (D) in Table 1. The acrylic polymer solutions of Examples 2 to 8 and Comparative Examples 1 to 5.
[0134]
[0135] [Example 1]
[0136] To the acrylic polymer solution of Example 1 in the reaction vessel prepared as described above was added an adduct of xylylene diisocyanate (XDI) (Takenate (registered trademark) D-110N; Mitsui Chemicals, Inc. production) 0.05 parts by weight, 0.05 parts by weight of a silane coupling agent (KBM-403; 3-glycidyloxypropyltrimethoxysilane: manufactured by Shin-Etsu Chemical Co., Ltd.), and stirring and mixing to obtain an implementation Adhesive composition of Example 1. This adhesive composition was applied on a release film (polyethylene terephthalate (PET) film coated with a silicone resin) so that the thickness...
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