Photosensitive resin composition, and color filter and image display device prepared by using same
A technology of photosensitive resin and composition, applied in the field of photosensitive resin composition, can solve the problems of reduced color filter performance, increased manufacturing cost, decreased color reproduction, etc., and achieves the effect of reducing manufacturing cost, ensuring quality and high quality
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Synthetic example
[0232] Synthesis example: Synthesis of alkali-soluble resin
Synthetic example 1
[0233] Synthesis Example 1: Alkali Soluble Resin
[0234] A flask equipped with a stirrer, a thermometer, a reflux condenser, a dropping funnel, and a nitrogen introduction tube was prepared. On the other hand, as a monomer dropping funnel, 74.8 g (0.20 moles) of benzylmaleimide and 43.2 g of acrylic acid were charged (0.30 mol), vinyl toluene 118.0g (0.50 mol), peroxy-2-ethylhexanoic acid tert-butyl ester 4g, propylene glycol monomethyl ether acetate (PGMEA) 40g, stir and mix and prepare as chain transfer The dropping tank of the agent was prepared by putting 6 g of n-dodecanethiol and 24 g of PGMEA, stirring and mixing. Then, 395 g of PGMEA was introduced into the flask, and the atmosphere in the flask was changed from air to nitrogen, and then the temperature of the flask was raised to 90° C. while stirring. Next, drop the monomer and chain transfer agent from the dropping funnel. Dropping is carried out for 2 hours while maintaining 90°C, and after 1 hour, the temperat...
Synthetic example 2
[0235] Synthesis Example 2: Synthesis of Compounds of Chemical Formula 1
[0236] In a three-necked round flask of 3000ml, 3', 6'-dihydroxyspiro (fluorene-9,9-xantene) (3', 6''-dihydroxyspiro(fluorene-9,9-xantene) 364.4 of chemical formula 3 g and 0.4159g of tert-butylammonium bromide are mixed, and 2359g of epichlorohydrin is charged, and heated to 90°C to make it react. Analyzed by liquid chromatography, if 3,6-dihydroxy spiro (fluorene-9,9-xanthene ) disappears completely, then cool to 30 ℃, add 50% NaOH aqueous solution (3 equivalents) slowly.Use liquid chromatography analysis, if epichlorohydrin disappears completely, then after extracting with dichloromethane, after washing 3 times with water, will After the organic layer was dried over magnesium sulfate, dichloromethane was distilled off under reduced pressure, and recrystallization was performed using a mixing ratio of dichloromethane and methanol of 50:50.
[0237] After mixing 1 equivalent of epoxy compound thus s...
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