A kind of functional urea based on modified wax retaining agent and preparation method thereof

A bioactivator and functional technology, which is applied in the field of functional urea and its preparation based on modified wax activator, can solve the problem of inability to achieve the best effect of functional components, simple method of adding functional components, and no direct access to functional substances. Protection and other issues, to achieve the effect of saving field operation time, reducing labor intensity of farmers, and excellent moisture resistance

Active Publication Date: 2022-03-25
SHANDONG AGRICULTURAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Patent CN104371473A discloses a new type of paraffin, whose glass transition temperature is 70-100°C. The high temperature is mainly to improve the high-temperature exudation performance of existing paraffin-based coatings, although the new type of paraffin has good heat resistance and wear resistance. It can effectively improve the high-temperature exudation performance of existing paraffin-based coatings, but this new type of paraffin has no direct protective effect on functional substances, and functional substances cannot be efficiently combined with urea to play a synergistic effect
Patent CN106631480A discloses a functional fertilizer, which can effectively transform heavy metals in the soil and achieve the double benefits of high yield and repairing heavy metals in the soil. However, a large amount of modified functional substances are simply mixed in the compound fertilizer, which is cumbersome and expensive.
Patent CN109748718A discloses a functional compound fertilizer, which has a good fertilizer source, can effectively kill germs in the soil, and effectively reduce crop root pests, but the method of adding functional components is simple, and direct mixing cannot make the functional components effective. achieve the best

Method used

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  • A kind of functional urea based on modified wax retaining agent and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Embodiment 1: the preparation of auxiliary agent for keeping alive

[0034] Add composite wax 85g under inert gas protection and heating and stirring condition, under heating and stirring, described composite wax is melted, then under stirring, add dropwise in the acrylonitrile that is dissolved with dicumyl peroxide, then add dropwise 5 , 6-dicarboxyindole melanin, heated at 40°C, stirring at a speed of 30 rpm for 1.0h, wherein 4g of dicumyl peroxide, 10g of acrylonitrile, 5,6-dicarboxyindole Indole melanin is 1g. The mixture containing the graft copolymer was obtained, and after hot filtration, methanol was added for precipitation separation, washing, and drying to obtain grafted modified paraffin, and the grafting rate was measured to be 45%.

[0035] In the present invention, the composite wax is a commercially available composite wax product produced by Henan Yuyang Wax Industry Co., Ltd.

Embodiment 2

[0036] Embodiment 2: the preparation of auxiliary agent for keeping alive

[0037] Add 85g of composite wax under inert gas protection and heating and stirring conditions, make the composite wax melt under heating and stirring, then add dropwise in the butadiene that is dissolved in cumene hydroperoxide under stirring, then add dropwise Iron oxide black, heated at 50°C, stirring and reacting for 1.0h under the condition of rotating speed of 35 rpm, to obtain a new type of grafted modified paraffin; wherein cumene hydroperoxide is 4.5g, butadiene is 10g, iron oxide Black is 0.5g. The mixture containing the graft copolymer was obtained, and after hot filtration, methanol was added for precipitation separation, washing and drying to obtain the graft modified paraffin wax, and the grafting rate was measured to be 50%.

Embodiment 3

[0038] Embodiment 3: the preparation of auxiliary agent for keeping alive

[0039]Add 80g of composite wax under inert gas protection and heating and stirring conditions, make described composite wax melt under heating and stirring, then add dropwise in the styrene that is dissolved with benzoyl peroxide under stirring, then add dropwise 5, 6-dicarboxyindole carboxylic acid melanin was heated at 60°C and stirred for 0.5h at a rotational speed of 20 rpm to obtain a new type of grafted modified paraffin; wherein benzoyl peroxide was 3.5g and styrene was 10g, 5,6-dicarboxyindolecarboxylic acid melanin is 1.5g. The mixture containing the graft copolymer was obtained, and after hot filtration, methanol was added for precipitation separation, washing and drying to obtain the graft modified paraffin wax, and the grafting rate was measured to be 55%.

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Abstract

The invention discloses a functional urea based on a modified wax retaining aid and a preparation method thereof. The modified wax retaining aid is prepared by the following method: melting the composite wax under the protection of an inert gas and heating and stirring , then drip the grafted monomer that dissolves the initiator under stirring, then add eumelanin dropwise, the mass ratio of composite wax, initiator, grafted monomer and eumelanin is (80-90): (1.5-4.5 ): (5-15): (0.5-3.5), heated and reacted with stirring to obtain a modified wax retention assistant. The life-preserving auxiliary agent prepared by the present invention has low melting point and good light-shielding property, and the mixing of the life-keeping auxiliary agent and melatonin can better isolate melatonin from the air, avoiding directly adding melatonin to urea The risk of oxidative inactivation of the element.

Description

technical field [0001] The invention relates to the technical field of fertilizers, in particular to a functional urea based on a modified wax retention assistant and a preparation method thereof. Background technique [0002] Chemical fertilizers are important means of production in agricultural production to ensure increased yields. With the increase of human food demand, the amount of chemical fertilizers is also increasing. At present, urea is the solid nitrogen fertilizer with the widest spectrum and the largest amount of use. After being applied to the soil, under various conditions, there will be a large amount of residue, volatilization, and loss, and a small amount will be absorbed by crops, resulting in a waste of resources. negative impact on the environment and sustainable agricultural development. On the basis of reducing the amount of common urea, improving the absorption rate of crops, reducing the damage to environmental resources, and improving the comprehe...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C05G3/00C05G5/12C08F289/00C08F220/44C08F236/06C08F212/08
CPCC08F289/00C05G3/00C08F220/44C08F236/06C08F212/08
Inventor 刘之广李泽丽贾春花巩彪张民邹朋贾波孙玲丽马强
Owner SHANDONG AGRICULTURAL UNIVERSITY
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