Method for preparing corrosion-resistant super hydrophobic membrane layer on surface of aluminum alloy

An aluminum alloy surface, super-hydrophobic technology, applied in the preparation of corrosion-resistant super-hydrophobic film, in the field of preparation of corrosion-resistant super-hydrophobic film on the surface of aluminum alloy, can solve the problems of long duration, poor scalability, complex preparation process, etc. , to achieve the effects of high stability and durability, easy processing and simple preparation method

Active Publication Date: 2020-01-24
JIANGSU UNIV OF SCI & TECH
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  • Abstract
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  • Claims
  • Application Information

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Problems solved by technology

However, most of these methods have the problems of complex preparation process, long duration, poor scalability and inability to implement on a large scale, which seriously restrict the application in actual production.

Method used

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  • Method for preparing corrosion-resistant super hydrophobic membrane layer on surface of aluminum alloy
  • Method for preparing corrosion-resistant super hydrophobic membrane layer on surface of aluminum alloy
  • Method for preparing corrosion-resistant super hydrophobic membrane layer on surface of aluminum alloy

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Embodiment

[0033] The invention provides a method for preparing a corrosion-resistant super-hydrophobic film on the surface of an aluminum alloy, the method comprising the following steps:

[0034] 1) Pretreatment of the aluminum alloy (6061) sample: smooth the surface of the sample with 400-2000# silicon carbide sandpaper, and remove the surface scale. Then place them in deionized water and ethanol for 15 min each ultrasonically to remove surface oil, and dry at room temperature.

[0035] 2) Electrolytic polishing treatment, anodic oxidation treatment and hole expansion treatment are sequentially performed on the aluminum alloy substrate;

[0036] Among them: electrolytic polishing treatment: the pre-grinded aluminum alloy substrate is subjected to electrolytic polishing treatment, the aluminum alloy sample is connected to the anode of a constant current power supply, and the cathode is made of stainless steel as an inert electrode. The polishing liquid proportion is composed of 40% ab...

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Abstract

The invention discloses a method for preparing a corrosion-resistant super hydrophobic membrane layer on a surface of an aluminum alloy. In the method, firstly, a pre milled aluminum alloy matrix is cleaned in turn by deionized water and ethanol in an ultrasonic cleaning instrument; the aluminum alloy matrix is electropolished, anodized and pore-enlarging; the matrix is placed in electrochemical nickel plating liquid to obtain a convex texture on the surface of the matrix, and then the matrix is placed in the electrochemical cobalt plating device to conduct the electrochemical cobalt plating treatment, through the treatment of the above steps, the petal-shaped micro nano rough structure is constructed on the surface of the matrix mainly through the combination of anodizing and electrochemical deposition. Finally, the surface free energy of the treated matrix was reduced by immersion modification in fluorosilane ethanol solution, so that the surface of aluminum alloy obtains the corrosion-resistant super hydrophobic membrane layer, and the corrosion resistance of the aluminum alloy is effectively improved.

Description

technical field [0001] The invention belongs to the technical field of surface modification and anticorrosion of metal materials, and relates to a method for preparing a corrosion-resistant super-hydrophobic film, in particular to a method for preparing a corrosion-resistant super-hydrophobic film on the surface of an aluminum alloy. Background technique [0002] Aluminum and its aluminum alloys are the main structural materials in industry, and the output and consumption are second only to steel. Aluminum alloy has excellent thermal conductivity, machinability, corrosion resistance and high strength, which makes it widely applicable to many industrial fields, and becomes the preferred metal in the fields of aerospace, automobile and ship, electronic machinery and so on. Material. [0003] However, aluminum and aluminum alloys are also inevitably corroded by the influence of corrosive media during use. Common types of aluminum corrosion include: pitting corrosion, exfoliati...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25D11/08C25D11/24C25D3/12C25D5/12C25D5/48C25D11/16C25F3/20
CPCC25D3/12C25D5/12C25D5/48C25D11/08C25D11/16C25D11/24C25F3/20
Inventor 王宇鑫衣秋合关林林何震尹丽郭平义乔岩欣周小卫
Owner JIANGSU UNIV OF SCI & TECH
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