A kind of ni-cu-c electrocatalyst and its preparation method and application
An electrocatalyst, ni-cu-c technology, applied in the field of electrocatalysis, can solve problems such as high cost and instability, and achieve the effects of convenient operation, low cost and short cycle
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
preparation example Construction
[0019] The invention provides a method for preparing a Ni-Cu-C electrocatalyst, comprising the following steps: electro-depositing a nickel sheet in an electrolytic solution to obtain a Ni-Cu-C electrocatalyst; the electrolytic solution includes ammonium chloride, Nickel Metal Salts, Copper Metal Salts, Sodium Chloride, Dextrose and Water.
[0020] In the present invention, without special instructions, the raw materials used are commercially available products well known in the art. When a certain raw material can also contain crystal water, the raw material in the present invention also includes its crystal hydrate, for example, when the present invention When nickel chloride is used, the nickel chloride also includes nickel chloride hexahydrate, which will not be repeated hereafter.
[0021] The present invention has no special requirements on the size of the nickel sheet, which can be selected by those skilled in the art according to actual needs. Before the electrodeposi...
Embodiment 1
[0027] The nickel sheet is placed in acetone (purity 99.5%), ethanol solution (volume concentration 95%) and hydrochloric acid (mass concentration 20%) to carry out ultrasonic cleaning for 30 minutes, rinse with deionized water and soak in ethanol solution to obtain Pure nickel sheet electrode; the composition of the electrolyte is 0.2M ammonium chloride, 0.1M nickel chloride hexahydrate, 0.2M sodium chloride, 0.03M copper chloride, glucose 0.005M, assemble the electrolytic cell, select carbon rod for the electrode, Seal one side of the nickel sheet with insulating tape, use a DC power supply for single-sided deposition, the current density is 10mA, and the time is 600s; the prepared sample is cleaned with distilled water, and then placed in a vacuum drying oven and kept at 60°C After 5h, the Ni-Cu-C electrocatalyst was obtained, which was denoted as Ni-Cu-C1.
Embodiment 2
[0029] The nickel sheet is placed in acetone (purity 99.5%), ethanol solution (volume concentration 95%) and hydrochloric acid (mass concentration 20%) to carry out ultrasonic cleaning for 30 minutes, rinse with deionized water and soak in ethanol solution to obtain Pure nickel sheet electrode; the composition of the electrolyte is 0.2M ammonium chloride, 0.1M nickel chloride hexahydrate, 0.2M sodium chloride, 0.03M copper chloride, glucose 0.01M, assemble the electrolytic cell, and select the carbon rod for the electrode. Seal one side of the nickel sheet with insulating tape, use a DC power supply for single-sided deposition, the current density is 10mA, and the time is 600s; the prepared sample is cleaned with distilled water, and then placed in a vacuum drying oven and kept at 60°C After 5h, the Ni-Cu-C electrocatalyst was obtained, which was denoted as Ni-Cu-C2.
PUM
Login to View More Abstract
Description
Claims
Application Information
Login to View More