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AlSi/h-BN modified cladding material, metal-based composite coating and preparing method thereof

A metal matrix composite and cladding material technology, applied in the direction of metal material coating process, coating, etc., can solve the problems of unsatisfactory improvement of wear resistance of laser cladding layer, difficulty in meeting wear resistance, etc. Hardness, wear resistance improvement, hardness improvement effect

Active Publication Date: 2020-03-06
SHANDONG AGRI & ENG UNIV +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Moreover, the improvement of wear resistance of some laser cladding layers is not ideal, and it is difficult to meet some places with high wear resistance requirements.

Method used

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  • AlSi/h-BN modified cladding material, metal-based composite coating and preparing method thereof
  • AlSi/h-BN modified cladding material, metal-based composite coating and preparing method thereof
  • AlSi/h-BN modified cladding material, metal-based composite coating and preparing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] The preparation method of the AlSi / h-BN modified metal matrix composite coating comprises the steps:

[0054] 1) Using Ti-6Al-4V titanium alloy as the base material, cut the Ti-6Al-4V titanium alloy plate into sample pieces;

[0055] 2) with SiO 2 Grind the surface of the sample with sandpaper to remove the scale on the surface of the sample, clean the sample with alcohol, and dry it for later use;

[0056] 3) Use an electronic balance to weigh cladding powder with a certain mass ratio, pour the weighed powder into a plastic bottle, and use a vortex mixer to mix the powder evenly. The composition of the cladding material is as follows: 97.5wt.% Ni60A+2.5wt.% AlSi / h-BN, the composition of AlSi / h-BN powder is as follows: h-BN 30wt.%, Si 14wt.%, the balance is Al , coating the mixed powder on the surface of the substrate with a thickness of 1 mm;

[0057] 4) Adopt TFL-H6000 type cross-flow CO 2 The gas laser is used for laser alloying treatment, the laser power is 2.5k...

Embodiment 2

[0067] The preparation method of alloyed coating is identical with embodiment 1, and control concrete parameter is:

[0068] P=2.5kW, v=300mm / min, 95wt.% Ni60A+5wt.% AlSi / h-BN, the composition of AlSi / h-BN powder is h-BN 30wt.%, Si 14wt.%, the balance is Al, the morphology of the prepared cladding layer is as follows Figure 12 As shown in a and b, there are obvious fusion lines in the bonding area, the cladding layer and the substrate form a good metallurgical bond, and the bottom structure is mainly fine dendrites with low density. The middle and upper parts are dominated by rods and fine dendrites. Due to the long existence of the upper molten pool, the structure is more coarse.

[0069] The hardness and wear resistance of the prepared alloyed coating were tested. The results showed that when the composition of the cladding material was 95wt.%Ni60A+5wt.%AlSi / h-BN, the surface quality of the coating was good and the hardness was high. Good wear resistance.

Embodiment 3

[0071] The preparation method of the metal matrix composite coating is the same as that of Example 1, the difference is that the composition of the cladding material is as follows: 90wt.%Ni60A+10wt.%AlSi / h-BN, and the hardness and Wear resistance test results show that when the composition of the cladding material is 90wt.% Ni60A+10wt.% AlSi / h-BN, the surface quality of the coating is good, more wear-resistant phases are formed in the coating, and the hardness is higher. The wear resistance is better, so the cladding material with this composition has better performance.

[0072] The X-ray diffraction of the prepared coating shows that the cladding layer is mainly composed of TiB, AlN, TiB 2 、Cr 7 C 3 , CrC, TiC, CrN, NiTi, AlNi 2 Ti, Al and other phase composition, such as figure 2 shown. The X-ray diffraction results of AlSi / h-BN powder are as follows figure 1 shown. The morphology of the prepared cladding layer is as follows Figure 14 as shown, Figure 14 In Fig....

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Abstract

The invention discloses an AlSi / h-BN modified cladding material, a metal-based composite coating and a preparing method thereof. The cladding material is formed through mixing of Ni60A nickel-based alloy powder and AlSi boron nitride powder. The mass percent of the AlSi boron nitride powder ranges from 2.5 to 40%. In the laser cladding process, TiB2 is formed on the upper portion of a cladding layer, meanwhile, TiC carries nucleation growth on the TiB2 surface, in the TiC nucleation growth process, the TiB2 coats primary TiC to form a TiB2 / TiC composite structure, the TiB2 and TiC are ceramicphases with the extremely high hardness, the TiB2 / TiC composite structure is integrated with advantages of two kinds of ceramic phases, and hardness and wear resistance are obviously improved. Ni andAl are easily in solid solution in crystal lattices of Ti, a supersaturation solid solution is formed, distortion of the crystal lattices is caused to achieve the solid solution reinforcing effect, and the hardness and the wear resistance of the cladding layer are further improved. The friction coefficient of the surface of the cladding layer can be obviously reduced, the antifriction effect is generated, the wear resistance of the cladding layer can be improved, and the wear resistance of 10wt.% AlSi / h-BN cladding layer is improved to 16.45 times of a base body.

Description

technical field [0001] The invention belongs to the technical field of material surface modification, and in particular relates to an AlSi / h-BN modified cladding material, a metal matrix composite coating and a preparation method thereof. Background technique [0002] The information disclosed in this background section is only intended to increase the understanding of the general background of the present invention, and is not necessarily taken as an acknowledgment or any form of suggestion that the information constitutes the prior art already known to those skilled in the art. [0003] As a new type of structural metal developed in the 1950s, titanium alloy has the advantages of low density, high specific strength, good biocompatibility, and good performance at medium and low temperatures. Therefore, titanium alloy is widely used in aerospace, biomedical, Automobile industry, sports equipment and other fields. However, titanium alloys have problems such as low hardness, ...

Claims

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Application Information

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IPC IPC(8): C23C24/10
CPCC23C24/103
Inventor 陈传忠路璐于慧君
Owner SHANDONG AGRI & ENG UNIV