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Methanol-water steam and hydrogen mixed gas integrated high-pressure hydrogen production system and method thereof

A technology of mixed gas and water vapor, applied in chemical instruments and methods, hydrogen, hydrogen separation, etc., can solve problems such as inability to realize cyclic hydrogen production and complicated hydrogen production process, and achieve improved hydrogen production efficiency, optimized and simplified structure, and efficient operation Stable and reliable effect

Pending Publication Date: 2020-03-27
中科液态阳光(苏州)氢能科技发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] At the same time, it provides a high-pressure hydrogen method, which solves the problem that the current hydrogen production process is complicated and cannot achieve circular hydrogen production.

Method used

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  • Methanol-water steam and hydrogen mixed gas integrated high-pressure hydrogen production system and method thereof
  • Methanol-water steam and hydrogen mixed gas integrated high-pressure hydrogen production system and method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0045] Such as figure 1 figure 2 As shown, a methanol water vapor and hydrogen mixed gas integrated high-pressure hydrogen system includes a three-phase heat exchange device 2, a reforming device 3, a steam trap 7, a hydrogen separation device 4, a water-cooled heat exchanger 5, a refrigerator and Carbon dioxide liquefaction device6.

[0046] The reforming device 3 includes a reaction chamber, and a heating chamber 33 is arranged outside the reaction chamber; the reaction chamber includes an upper reaction chamber 31 suitable for reforming methanol water vapor and an upper reaction chamber 31 suitable for reforming hydrogen mixed residual gas. A complete lower reaction chamber 32, the upper reaction chamber 31 communicates with the lower reaction chamber 32;

[0047] The upper reaction chamber 31 is filled with copper-based fillers or zirconium-based fillers, the lower reaction chamber 32 is filled with copper-based fillers or zirconium-based fillers, and the upper reaction...

Embodiment 2

[0062] In yet another aspect, a high-pressure hydrogen method is provided, using the above-mentioned high-pressure hydrogen system, comprising the following steps:

[0063] S1. The liquid pump 1 sends methanol water into the methanol water vapor pipe, the pump pressure is 18-50 MPa, the methanol water is heated and vaporized into methanol water vapor and enters the reaction chamber 31 of the reformer 3, and the methanol water vapor flows in the reformer 3 The reforming reaction is carried out in the upper reaction chamber 31 to generate a mixed gas of hydrogen, carbon dioxide and carbon monoxide, and then the mixed gas of hydrogen, carbon dioxide and carbon monoxide is sent into the hydrogen separation device 4;

[0064] Methanol water vapor is catalyzed under the corresponding temperature and catalyst packing, which is a multi-component, multi-reaction gas-solid catalytic reaction system;

[0065] The reaction equation is: CH 3 OH→CO+2H 2 ;(Reversible reaction)

[0066] h ...

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Abstract

The invention relates to a methanol-water steam and hydrogen mixed gas integrated high-pressure hydrogen production system. The system comprises a three-phase heat exchange device, a reforming device,a hydrogen separation device, a steam trap, a water-cooled heat exchanger, a refrigerating machine and a carbon dioxide liquefaction device; and the pump pressure of a liquid pump is 18-50 MPa. A high-pressure hydrogen production method comprises the following steps: methanol-water steam is subjected to a reforming reaction in an upper reaction cavity to generate a mixed gas of hydrogen, carbon dioxide and carbon monoxide, hydrogen separation is carried out, and the obtained carbon dioxide mixed residual gas undergoes carbon dioxide liquefaction separation to prepare liquid carbon dioxide anda hydrogen mixed residual gas in a carbon dioxide separator, wherein the hydrogen mixed residual gas is close to the hydrogen, carbon dioxide and carbon monoxide mixed gas in hydrogen, carbon dioxideand carbon monoxide proportions; and the hydrogen mixed residual gas and the hydrogen, carbon dioxide and carbon monoxide mixed gas enter a hydrogen separation cavity together and undergo hydrogen separation operation. The hydrogen production efficiency of the hydrogen production system is improved, and the structure of the whole hydrogen production system is optimized and simplified, so the hydrogen production system can be processed to form a small hydrogen production apparatus.

Description

technical field [0001] The invention relates to an integrated high-pressure hydrogen system and a method thereof. Background technique [0002] Hydrogen energy is the most ideal energy source in the 21st century. As a fuel for automobiles, it is easy to start at low temperature, and has little corrosion effect on the engine, which can prolong the service life of the engine. Because hydrogen and air can be mixed evenly, the carburetor used in general cars can be completely omitted, thereby simplifying the structure of existing cars. Even more interesting, just add 4% hydrogen to gasoline. Using it as a vehicle engine fuel can save fuel by 40%, and there is no need to make much improvement to the gasoline engine. Hydrogen fuel cell as power generation system. [0003] No pollution, the fuel cell has no pollution to the environment. It uses electrochemical reaction instead of combustion (gasoline, diesel) or energy storage (battery) - the most typical traditional backup pow...

Claims

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Application Information

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IPC IPC(8): C01B3/32C01B3/12C01B3/50C01B32/50
CPCC01B3/323C01B3/12C01B3/50C01B32/50C01B2203/0233
Inventor 岳锌李佳毅吕双江韩涤非赵纪军岳野陈芳
Owner 中科液态阳光(苏州)氢能科技发展有限公司
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