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A kind of magnesium oxide-based desulfurizer and preparation method thereof

A magnesium oxide-based desulfurizer technology, applied in chemical instruments and methods, separation methods, ceramic products, etc., can solve the problems of high cost of magnesium oxide desulfurizers, low desulfurization efficiency of calcium-based desulfurizers, and large pollution emissions. To achieve the effect of good economic benefits, excellent performance and excellent performance

Active Publication Date: 2021-12-28
LIAONING DONGHE NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The object of the present invention is to provide a kind of magnesia-based desulfurizer, which uses low-grade magnesite with low magnesia content as raw material, and the high-activity light-burned magnesium powder obtained by sintering the raw material through suspension kiln and The pore-forming agent is mixed, and the obtained magnesium oxide-based desulfurizer has a good desulfurization effect, thereby solving the problems of high cost of magnesium oxide desulfurizer, large amount of pollution discharge and low desulfurization efficiency of the existing calcium-based desulfurizer in the prior art

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  • A kind of magnesium oxide-based desulfurizer and preparation method thereof
  • A kind of magnesium oxide-based desulfurizer and preparation method thereof
  • A kind of magnesium oxide-based desulfurizer and preparation method thereof

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Embodiment 1

[0031] This embodiment provides a magnesium oxide-based desulfurizer, and the preparation method of the magnesium oxide-based desulfurizer includes the following steps:

[0032] (1) Take magnesite tailings with a magnesium oxide content of ≤43.0%, crush them with a jaw crusher, put them into a ball mill for ball milling, add chemicals for desiliconization and decalcification, and obtain tailings slurry with a fineness of 120 mesh ;

[0033] (2) The tailings slurry is fed into the flash dryer through the raw material feeder for drying, and the dried powder is fed into the suspension kiln, and is suspended and calcined at 1100°C for 50 minutes to obtain a fineness of 200 mesh with a pass rate of 95%, activity ≥75% active lightly burned magnesia powder (citric acid method activity measurement time 18 seconds) (wherein, such as figure 2 Shown, the fineness distribution of the activated light-burned magnesia powder that obtains is uniform);

[0034] (3) Add 500 parts by weight o...

Embodiment 2

[0036] This embodiment provides a magnesium oxide-based desulfurizer, and the preparation method of the magnesium oxide-based desulfurizer includes the following steps:

[0037](1) Take magnesite tailings with a magnesium oxide content of ≤43.0%, crush them with a jaw crusher, put them into a ball mill for ball milling, add chemicals for desiliconization and decalcification, and obtain tailings slurry with a fineness of 120 mesh ;

[0038] (2) The tailings slurry is fed into the flash dryer for drying through the raw material feeder, and the dried powder is fed into the suspension kiln, and is suspended and calcined at 850°C for 30 minutes to obtain a fineness of 200 mesh with a pass rate of 95%, activity ≥75% active light-burned magnesia powder;

[0039] (3) Add 500 parts by weight of activated light-burned magnesia powder obtained in step (2), 20 parts by weight of pore-forming agent talcum powder, and 480 parts by weight of water, and mix uniformly to prepare a magnesium o...

Embodiment 3

[0041] This embodiment provides a magnesium oxide-based desulfurizer, and the preparation method of the magnesium oxide-based desulfurizer includes the following steps:

[0042] (1) Take magnesite tailings with a magnesium oxide content of ≤43.0%, crush them with a jaw crusher, put them into a ball mill for ball milling, add chemicals for desiliconization and decalcification, and obtain tailings slurry with a fineness of 120 mesh ;

[0043] (2) The tailings slurry is fed into the flash dryer through the raw material feeder for drying, and the dried powder is fed into the suspension kiln, and is suspended and calcined at 1100°C for 50 minutes to obtain a fineness of 200 mesh with a pass rate of 95%, activity ≥75% active light-burned magnesia powder;

[0044] (3) Add 500 parts by weight of active light-burned magnesia powder obtained in step (2), 50 parts by weight of pore-forming agent talcum powder, and 520 parts by weight of water, and mix uniformly to prepare a magnesium ox...

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Abstract

The invention provides a magnesium oxide-based desulfurizer and a preparation method thereof. The magnesium oxide-based desulfurizer is prepared from the following raw materials: light-burned magnesium powder, pore-forming agent and water; the light-burned magnesium powder is oxidized magnesite with a magnesium oxide content of ≤43.0% and sintered in a suspension kiln. Activated lightly burned magnesium powder with magnesium content ≥ 75%. The magnesia-based desulfurizer provided by the present invention uses low-grade magnesite with low magnesia content as a raw material, and the high-activity light-burned magnesium powder obtained by sintering the raw material in a suspension kiln is mixed with a pore-forming agent and water to obtain magnesia The desulfurization effect of the base desulfurizer is good, and the problems of high cost of the magnesium oxide desulfurizer, large pollution discharge and low desulfurization efficiency of the existing calcium-based desulfurizer are solved in the prior art.

Description

technical field [0001] The invention relates to the technical field of waste treatment environment, and more specifically relates to a magnesium oxide-based desulfurizer and a preparation method thereof. Background technique [0002] About 90% of SO in my country 2 Emissions come from the combustion of coal fuel, causing great harm to the environment. Currently controls SO 2 The main method of emission is to desulfurize the flue gas through desulfurizers. Among them, the most widely used process is "calcium desulfurization", that is, lime is used for wet desulfurization, but there is no good treatment method for its desulfurization products. On the other hand, my country's magnesite industry has adopted a relatively extensive production method in recent years. The reverberatory kiln is currently the main light-fired magnesite kiln in Liaoning, China, and its quantity accounts for more than 99% of the light-fired kiln. The equipment is very backward. At the same time, the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B2/10C04B38/00C04B28/10B01D53/50B01D53/81C04B111/40
CPCC04B2/102C04B38/00C04B28/10B01D53/81B01D53/50C04B2111/40C04B22/08
Inventor 毕万利毕胜民赵九野吴山王梓涵关岩孙美硕
Owner LIAONING DONGHE NEW MATERIAL CO LTD