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Non-porous self-breathing PVC artificial leather and preparation method thereof

A self-breathing, artificial leather technology, applied in polyurea/polyurethane coatings, coatings, etc., can solve the problems of poor ventilation of PVC leather

Active Publication Date: 2020-04-21
清远市美佳乐环保新材股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] In order to solve the above-mentioned problems in the prior art, the present invention provides a non-porous self-breathing PVC artificial leather, which includes a non-porous self-breathing surface layer and a breathable bottom layer with a microporous structure. Steam is discharged from the leather to the outside of the leather to achieve self-breathing to achieve the effect of dehumidification and exhaust. At the same time, the outer layer is a non-porous structure, which has a waterproof effect and effectively solves the problem of poor ventilation of PVC leather.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0067] The invention discloses a non-porous self-breathing PVC artificial leather, which has the characteristics of low price and long service life of ordinary artificial leather, and has the waterproof and breathable function. The waterproof and breathable function comes from the structure and material of the self-breathing PVC artificial leather, wherein the non-porous self-breathing PVC artificial leather includes a non-porous self-breathing surface layer and a breathable bottom layer with a microporous structure.

[0068] The self-breathing surface layer contains hydrophilic polymer functional materials, such as water-soluble polyols and carboxylates; the breathable bottom layer is a breathable PVC foam layer, and the self-breathing surface layer and the breathable bottom layer adopt the transfer method and (or) surface treatment method Combining together, the way of combining generally adopts the way of bonding (fitting).

[0069] In the non-porous self-breathing PVC arti...

Embodiment 2

[0074] A non-porous self-breathing PVC artificial leather, comprising a non-porous self-breathing surface layer and a breathable bottom layer with a microporous structure, wherein the self-breathing surface layer comprises the following components: 174g of isophorone diisocyanate, 1000 g of polycarbonate diol 100 g, polyethylene glycol 1000 80 g, dihydroxybutyric acid 8 g, 1,4-butanediol 26.7 g, bismuth catalyst K24 1 g, antioxidant Irganox 10101 g, propylene glycol methyl ether acetate 100 g, isopropanol 50 g, Isophoronediamine 11.9g, triethanolamine 6g;

[0075] The breathable bottom layer includes the following components: PVC resin 100g, dioctyl phthalate DOP 80g, light calcium carbonate 15g, barium stearate 1g, T-12 1g, AC foaming agent 2.7g, PE micropowder 20g.

[0076] The non-porous self-breathing PVC artificial leather comprises the following steps:

[0077] (1) Preparation of self-breathing surface layer: Take 174g of isophorone diisocyanate, 100 g of polycarbonate ...

Embodiment 3

[0083] A non-porous self-breathing PVC artificial leather, comprising a non-porous self-breathing surface layer and a breathable bottom layer with a microporous structure, wherein the self-breathing surface layer comprises the following components: 174g of isophorone diisocyanate, 1000 g of polycarbonate diol 100 g, polyethylene glycol 1000 80 g, dihydroxybutyric acid 8g, 1,4-butanediol 26.7g, bismuth catalyst K24 1g, antioxidant Irganox 10101g, propylene glycol methyl ether acetate 50g, isophorone di amine 8g, triethanolamine 6g, water 130g, ethylenediamine 6g;

[0084] The breathable bottom layer includes the following components: PVC resin 100g, dioctyl phthalate DOP 80g, light calcium carbonate 15g, barium stearate 1g, T-12 1g, AC foaming agent 2.7g, PE micropowder 20g.

[0085] The non-porous self-breathing PVC artificial leather comprises the following steps:

[0086] (1) Preparation of self-breathing surface layer: Take 174g of isophorone diisocyanate, 100 g of polycar...

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Abstract

The invention provides non-porous self-breathing PVC artificial leather which comprises a non-porous self-breathing surface layer and a breathable bottom layer with a microporous structure, the self-breathing surface layer and the breathable bottom layer are attached together by adopting a transfer method and (or) a direct coating method, the self-breathing surface layer contains water-soluble polyhydric alcohol and carboxylate, and the breathable bottom layer is a breathable PVC foaming layer. According to the non-porous self-breathing PVC artificial leather, water vapor is discharged out ofthe leather through the temperature difference and the humidity difference, self-breathing is achieved, the moisture and air discharging effect is achieved, the outer layer is of a non-porous structure, the waterproof effect is achieved, and the problem that PVC leather is poor in breathability is effectively solved.

Description

technical field [0001] The invention relates to the technical field of artificial leather production, in particular to a non-porous self-breathing PVC artificial leather and a preparation method thereof. Background technique [0002] Artificial leather is a plastic product that looks and feels like leather and can be used instead of it. It mainly includes PVC artificial leather, PU artificial leather and PU synthetic leather. Due to its high strength, easy processing and low cost, artificial leather has been widely used as a substitute for genuine leather. [0003] However, the use of artificial leather is still very different from genuine leather, such as hygiene. Because artificial leather is not breathable or has poor ventilation function, the interior of artificial leather is in a high temperature and high humidity environment for a long time, and bacteria and fungi multiply and cause odor problems. [0004] In some PU artificial leathers, since the substrate (wet proce...

Claims

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Application Information

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IPC IPC(8): C08J9/36C08J9/10C08L27/06C08L23/06C08L27/18C08L1/28C08K13/02C08K5/12C08K3/26C08K5/098C09D175/08C08G18/75C08G18/66C08G18/44C08G18/48C08G18/34C08G18/32C08G18/12C08G18/08
CPCC08J9/365C08J9/103C08J9/0061C08J9/0066C08J9/0023C08J9/0095C08G18/755C08G18/44C08G18/4238C08G18/4277C08G18/4825C08G18/348C08G18/3206C08G18/6692C08G18/12C08G18/0823C08G18/758C08G18/722C08J2203/04C08J2327/06C08J2423/06C08J2427/18C08J2475/08C08J2475/06C08J2401/28C08G18/3234
Inventor 关仲翔姚文佩
Owner 清远市美佳乐环保新材股份有限公司
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