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A kind of white carbon black/natural rubber composite material preparation method

A technology of natural rubber and composite materials, applied in the field of continuous preparation of silica/natural rubber composite materials, can solve problems such as affecting the health of operators, lag in vulcanization time, affecting the performance of rubber products, etc., to achieve physical properties and dynamic performance. The effect of improved mechanical properties, shortened production cycle, and continuous processing methods

Active Publication Date: 2021-12-14
QINGDAO UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The study found that although the wet mixing process can improve the microscopic dispersion of fillers, because the flocculation and drying methods are mostly chemical means such as acid flocculation, it will affect the performance of rubber products.
The acidic flocculation method has irreversible defects, which will not only affect the health of the operators, but also corrode the equipment. The long-term drying after flocculation is likely to produce acid gas that affects the environment. If the strong acid is not cleaned, it will also affect the subsequent vulcanization time, and , in the acidic environment, the vulcanization time of the rubber compound will produce hysteresis, which will easily cause overvulcanization and affect the performance of rubber products.

Method used

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  • A kind of white carbon black/natural rubber composite material preparation method
  • A kind of white carbon black/natural rubber composite material preparation method
  • A kind of white carbon black/natural rubber composite material preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] The preparation method of the silica / natural rubber composite material involved in this embodiment is a high-temperature atomization method, and the process includes four steps of preparing an aqueous solution of silica, preparing an aqueous solution of auxiliary agents, preparing a silica masterbatch, and continuous mixing:

[0016] (1) Preparation of white carbon black aqueous solution: add 40 parts by mass of SiO in No. 1 beaker 2 (silicon dioxide), 5 parts by mass of liquid Si69 (silane coupling agent) solution and deionized water are mixed with 25wt% white carbon black aqueous solution, and the white carbon black aqueous solution is placed in an ultrasonic oscillator with a frequency of 1000 Hz for ultrasonic 10min, Then the solution after the ultrasonic wave is placed in a planetary ball mill for secondary crushing and grinding for 4 hours;

[0017] (2) Preparation of auxiliary agent aqueous solution: add 20 parts by mass of SiO in No. 2 beaker 2 (silicon dioxide...

Embodiment 2

[0021] This example involves the comprehensive performance test of silica / natural rubber composite material vulcanized rubber. The silica / natural rubber composite material will be prepared by using smoked sheet glue-dry method, acid flocculation method-wet method and high temperature atomization method respectively. Prepare into sizing material, wherein, the preparation process of high-temperature atomization method sizing material is: the white carbon black / natural rubber composite material prepared in step (4) and 1 mass part S (sulfur) and 1.2 mass parts CZ (N-ring Hexyl-2-benzothiazole sulfenamide) is placed in the mill and passed through 6 times to obtain the sizing material; three parts of the sizing material are tested for mechanical properties respectively, and the results are as follows:

[0022]

[0023]

[0024] According to the data of tensile strength and tear strength, it can be seen that the rubber compound prepared by high temperature atomization method has ...

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Abstract

The invention belongs to the technical field of natural rubber wet mixing, and relates to a preparation method of white carbon black / natural rubber composite material, which uses a wet mixing process to prepare white carbon black into a uniform dispersion solution through mechanical grinding, and mixes with natural latex After mixing, stir at a slow speed to fully contact the natural rubber latex and white carbon black, use the positive charge generated by the high-temperature atomization method to flocculate the negatively charged natural rubber latex, wrap the white carbon black in it, and make white carbon black after dehydration and drying. The innovation of carbon black / natural rubber composite material lies in: First, adding other rubber additives in the formula except filler and latex together to realize the premixing of the materials in the formula, which is convenient for later processing and reduces mixing time and mixing time. Second, the processing method is continuous, and the prepared masterbatch is put into the continuous mixer to realize continuous production.

Description

Technical field: [0001] The invention belongs to the technical field of natural rubber wet mixing, and relates to a continuous preparation method of white carbon black / natural rubber composite material, which has the advantages of environmental protection and low energy consumption, can shorten the production cycle, and makes white carbon black in natural rubber It achieves micro-dispersion and improves the performance of rubber. Background technique: [0002] Mixing is the most critical process in the processing of rubber products. The purpose is to fully mix the rubber additives in the formula with the rubber, and to disperse the rubber additives as evenly as possible. Rather than saying that the quality of the mixing result directly determines the rubber The performance and service life of the product, rather than the degree of dispersion and distribution of rubber additives in rubber determine the performance and service life of rubber products, so how to improve the dis...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L7/00C08K13/06C08K9/06C08K7/26C08K5/09C08K3/22B29B7/00
CPCC08K13/06C08K9/06C08K7/26C08K5/09C08K3/22B29B7/007C08K2003/2296C08L7/00B29B7/90B29B7/48B29B7/7461B29B7/885B29B7/905B29B7/60B29B7/7495
Inventor 汪传生朱东林边慧光宋凤鹏
Owner QINGDAO UNIV OF SCI & TECH
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