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Plastic master batch, preparation method thereof and plastic

A technology of plastic masterbatch and alkaline earth metal, which is applied in the field of degradable plastic products, can solve the problems of low addition amount of degradation, limited degradation performance, high price, etc., and achieves good degradation controllability, good product stability, and easy degradation Effect

Pending Publication Date: 2020-06-12
李守本
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the above-mentioned products have many limitations: First, the degradation performance is limited, such as the widely used plastic products produced by photodegradable masterbatch, which cannot be induced in the absence of light (such as buried parts, garbage filling sites, etc.) degradation
Second, the price is high, which greatly increases the production cost and pushes up the price of plastic products.
Third, poor formability in the production process (such as blown film, wire drawing, injection molding, etc.) requires special processing equipment
Fourth, if the amount of addition is too low, it will be difficult to meet the needs of degradation. A large amount of addition will lead to an increase in cost, so the popularity is low. This is an important reason why the current production and consumption of degradable masterbatches have not reached the expected growth, which directly leads to It is difficult to promote degradable plastics, so it is an urgent need for the current plastics production industry to produce a degradable masterbatch that is easy to degrade, good in formability, easy to process, high in quality and low in price.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Take 15 parts of polyethylene resin, 55 parts of anhydrous sodium chloride, 20 parts of modified starch, 7 parts of polyethylene wax, 1 part of zinc stearate, 1 part of coupling agent, 0.3 parts of photosensitizer, 0.7 parts of prooxidant, 1.0 parts of degradation agent. The degradable masterbatch 1 is produced, and the plastic film products with more than 2.5 filaments can be produced according to the addition ratio of 50% when used. Under normal conditions (normal temperature, humidity, air), it can degrade 98% in about 5 months. % above, and the rest can continue to degrade.

Embodiment 2

[0032]Take 15 parts of polyethylene resin, 55 parts of anhydrous sodium sulfate, 20 parts of modified starch, 7 parts of polyethylene wax, 1 part of zinc stearate, 1 part of coupling agent, 0.3 parts of photosensitizer, 0.7 parts of prooxidant, degrade 1.0 parts. The degradable masterbatch 2 is produced, and the plastic film product with a thickness of 2.5 filaments is produced according to the addition ratio of 50% when used. It can degrade 98% in about 6 months under normal conditions (normal temperature, humidity, air). % above, and the rest can continue to degrade.

Embodiment 3

[0034] Take 15 parts of polyethylene resin, 55 parts of calcium oxide, 20 parts of modified starch, 7 parts of polyethylene wax, 1 part of zinc stearate, 1 part of coupling agent, 0.3 parts of photosensitizer, 0.7 parts of prooxidant, and 1.0 parts of degradation agent share. The degradable masterbatch 3 is produced, and the plastic film products with more than 2.5 filaments are produced according to the addition ratio of 50% when used. Under normal conditions (normal temperature, humidity, air), it can degrade 98% in about 7 months. % above, and the rest can continue to degrade.

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PUM

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Abstract

The invention discloses a plastic master batch. The plastic master batch comprises, by weight, 10 to 50 parts of polyethylene resin, 10 to 70 parts of inorganic salt or oxide of alkali metal or alkaline earth metal, 5 to 45 parts of modified starch, 5 to 25 parts of polyethylene wax, 1 to 10 parts of zinc stearate, 1 to 8 parts of a coupling agent, 0.01 to 2.0 parts of a photosensitizer, 0.01 to 2.5 parts of a pro-oxidant and 0.02 to 3.0 parts of a degradation agent. The defects in the prior art are overcome, and the master batch with multiple degradation functions of light, moisture and biology is provided. The master batch disclosed by the invention is easy to degrade, good in formability, convenient to process, high in quality and low in price, and can be used for producing plastic products with excellent degradation thoroughness, degradation controllability and product stability.

Description

technical field [0001] The invention relates to the field of degradable plastic products, in particular, a degradable plastic masterbatch, a preparation method and plastic. Background technique [0002] Plastic is a polymer material composed of synthetic resins and fillers, plasticizers, stabilizers, lubricants, colorants and other additives. Due to the strong stability of plastic products, it takes hundreds or even hundreds of years in the natural environment. to degrade. Global plastic production exceeds 350 million tons per year, generating more than 100 million tons of plastic waste. [0003] Random discarding of plastic waste will pollute the environment, deep burial will encroach on the land, pollute the soil, and burning will pollute the air. These are not scientific methods of solving problems. [0004] With the country's increasing requirements for environmental protection, on January 19, 2020, the National Development and Reform Commission and the Ministry of Ec...

Claims

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Application Information

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IPC IPC(8): C08L3/04C08L23/06C08K3/16C08K5/098C08K3/30C08K3/22C08J3/22C08J5/18
CPCC08J3/226C08J5/18C08J2403/04C08J2423/06C08K3/16C08K5/098C08K2003/3045C08K2003/2206
Inventor 李守约李守本卢衍梅
Owner 李守本