Supercharge Your Innovation With Domain-Expert AI Agents!

Fuel cell electrode catalyst layer slurry preparation method, catalyst slurry and application thereof

A fuel cell electrode and catalyst slurry technology, which is applied in the direction of battery electrodes, circuits, electrical components, etc., can solve the problem of unreasonable electrode catalytic layer and gas diffusion layer structure, high resistance to reaction gas and liquid water transfer, and difficulty in large-scale batch production Production and other problems, to achieve the effect of high particle size distribution consistency, not easy to aggregate, wide range of adjustable viscosity and viscoelasticity

Active Publication Date: 2020-06-12
DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
View PDF5 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current research on MEA shows that its existing problems are mainly concentrated in: the structure of the electrode catalytic layer and the gas diffusion layer is unreasonable, resulting in low catalyst utilization, high transfer resistance of reaction gas and liquid water, and extreme concentration difference in the high current density area. Large chemical loss; battery output performance needs to be improved; electrode preparation process is cumbersome and the degree of automation is not high, it is difficult to achieve large-scale mass production

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Fuel cell electrode catalyst layer slurry preparation method, catalyst slurry and application thereof
  • Fuel cell electrode catalyst layer slurry preparation method, catalyst slurry and application thereof
  • Fuel cell electrode catalyst layer slurry preparation method, catalyst slurry and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] a, pretreatment of catalyst:

[0039] Fully wet the Pt / C (60%) catalyst powder used in the electrode with 2 times of deionized water, add a mixed solution of water and ethanol with a mass ratio of 1:5, the mass is 5 times that of the catalyst, and disperse with ultrasonic stirring 1 hour until uniform; add polybenzimidazole and polytetrafluoroethylene 1:1 additive, the mass is 0.3 times that of the catalyst, and fully ultrasonically stir for 2 hours until uniform to obtain a mixed slurry; add dimethylformamide with a mass of 50 times the mixed slurry base formamide solvent, reflux and stir at 120 degrees centigrade for 5 hours; filter after natural cooling, and keep the filter cake for subsequent use;

[0040] b, preparation of catalyst slurry

[0041] Add the filter cake obtained in step a to water with 5 times the mass of the catalyst, and ultrasonically stir evenly; add methanol with 5 times the mass of the catalyst, and stir ultrasonically; add dimethylacetamide wi...

Embodiment 2

[0063] a, pretreatment of catalyst:

[0064] Fully wet the PtCo / C (50%) catalyst powder used in the electrode with 1 times deionized water, add a mixed solution of water and cyclohexane with a mass ratio of 1:1, the mass is 10 times that of the catalyst, and ultrasonically Stir and disperse for 4 hours until uniform; add a mixture of sodium dodecylbenzenesulfonate and perfluorosulfonic acid polymer with a molar ratio of 1:1, the mass of which is 0.05 times that of the catalyst, and fully ultrasonically stir for 2 hours until uniform to obtain a mixed slurry; Add a formamide solvent whose mass is 50 times that of the mixed slurry, reflux and stir at 100 degrees Celsius for 4 hours; filter after natural cooling, and keep the filter cake for later use;

[0065] b, preparation of catalyst slurry

[0066] Add the filter cake obtained in step a to water with 2 times the mass of the catalyst, and ultrasonically stir evenly; add acetone with 3 times the mass of the catalyst, and ultr...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

A preparation method of fuel cell electrode catalyst layer slurry comprises the steps that an additive is added in the catalyst slurry pretreatment process, and a filter cake is prepared; in the preparation of the catalyst slurry, water, a low-boiling-point solvent, a high-boiling-point solvent and a high-viscosity solvent are sequentially or simultaneously added into the obtained filter cake respectively, and ultrasonic stirring is performed to obtain catalyst slurry to be treated; the catalyst accounts for 0.5-15% of the mass of the catalyst slurry; the obtained catalyst slurry to be treatedis sufficiently stirred in an inert atmosphere forstanding, supernatant is removed, and repeatedly filtering is performed until the slurry is fine and uniform; and stirring is performed again to obtain catalyst slurry. The slurry prepared by adopting the method is good in uniformity, high in stability, wide in adjustable range of viscosity and viscoelasticity and high in practicability, components in the slurry can be adjusted according to requirements of application targets, the applicable range is wide, and the slurry can be applied to various electrode systems.

Description

technical field [0001] The invention relates to a catalyst slurry preparation method suitable for fuel cell membrane electrodes, in particular to a slurry preparation method that can be used to prepare fuel cell gas diffusion electrodes or solid electrolyte membrane-carrying catalytic layer electrodes by coating methods. [0002] The present invention also relates to the application of the method for preparing the above-mentioned thermal catalyst slurry. Background technique [0003] In recent years, the development of new clean energy, the rational use of existing energy and the coordinated development of environmental protection have become the basis for the development of the world economy in this century. Fuel cells (Fuel Cells) are a power generation device that directly converts chemical energy into electrical energy without a combustion process. It has the outstanding advantages of high energy conversion efficiency, low pollution, and environmental friendliness. Powe...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): H01M4/88H01M4/90
CPCH01M4/88H01M4/90Y02E60/50
Inventor 王素力夏章讯景粉宁陈曦孙公权
Owner DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
Features
  • R&D
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More