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An etching solution system and an etching method for an aluminum nitride substrate

An etching solution and system technology, used in chemical instruments and methods, surface etching compositions, semiconductor/solid-state device manufacturing, etc., can solve the problems of few etching methods and low practicability, and achieve strong etching ability, high Selectivity and excellent etching quality

Active Publication Date: 2022-07-12
江苏富乐华半导体科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But at present, there are few etching solution systems and etching methods for the solder bonding layer and the practicability is low.

Method used

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  • An etching solution system and an etching method for an aluminum nitride substrate
  • An etching solution system and an etching method for an aluminum nitride substrate
  • An etching solution system and an etching method for an aluminum nitride substrate

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] The preparation of embodiment 1 etching solution system

[0037] The formula of the first etching solution is shown in Table 1 below.

[0038] Table 1 The mass percentage of each component of the first etching solution

[0039]

[0040] The configuration raw materials of the first etching solution:

[0041] Ammonia water selects the ammonia water solution of 5%-15% mass fraction;

[0042] The strong oxidant is configured with 20%-40% mass fraction of hydrogen peroxide solution or potassium permanganate solution / potassium permanganate that achieves the same effect;

[0043] The complexing agent is an amino hydroxy acid salt compound, including one or more of sodium ammonium triacetate, ethylenediaminetetraacetate, and diethylenetriaminepentacarboxylate, and a complexing agent with a mass fraction > 95% is selected. agent.

[0044] The first etching solution configuration steps are as follows:

[0045] Add pure water to the glass container; then add the formula am...

Embodiment 2

[0056] Embodiment 2 Etching method of aluminum nitride ceramic substrate

[0057] The structure of the etched aluminum nitride ceramic substrate is as follows figure 1 As shown, a solder bonding layer 2 and a copper foil 3 are formed on the aluminum nitride substrate 1 in sequence. The solder bonding layer 2 and the copper foil 3 have a solder bonding layer etching area 20 and a copper foil etching area 30 that need to be removed by etching. like figure 2 As shown, the solder bonding layer 2 includes a copper-silver eutectic layer 21, a nitrogen-titanium reaction layer 22 and an aluminum-titanium intermetallic compound 23, and the corresponding etching regions are 201, 202 and 203, respectively.

[0058] The etching process of aluminum nitride ceramic substrate is as follows image 3 shown, including the following steps:

[0059] (a) Etching of metal copper layer

[0060] After the aluminum nitride ceramic substrate is filmed, exposed and developed, the exposed metal copp...

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Abstract

The invention discloses an etching solution system and an etching method for an aluminum nitride substrate. The etching solution system includes: the first etching solution, in terms of mass percentage, includes 1%-5% ammonia water, 3%-8% strong oxidizing agent, 0.5%-5% complexing agent and the balance of water; The etching solution, in terms of mass percentage, includes 1%-5% alkali, 2%-8% hydrogen peroxide and the balance of water. In the etching method of the aluminum nitride substrate, the etching of the solder bonding layer is carried out in two steps. The first step is to use the first etching solution of the present invention to etch the copper-silver eutectic layer and the nitrogen-titanium reaction layer. In the second step, the aluminum-titanium intermetallic compound is etched using the second etching solution of the present invention. The etching solution system of the present invention has high selectivity and strong etching ability; the etching method of the present invention has high etching efficiency and excellent etching quality;

Description

technical field [0001] The invention belongs to the technical field of semiconductor processing, and relates to an etching solution system and an etching method for an aluminum nitride substrate, in particular to an etching solution system and an etching method for an active alloy brazing material bonding layer. Background technique [0002] A power module is a power semiconductor device that is re-potted into a module according to a certain functional combination. With the increasing integration of power modules and increasing power, the current density and ambient temperature of semiconductor chips are getting higher and higher, and the effective heat dissipation of devices has become high-power LEDs, automotive headlights and high-power components. A vital foundation for normal operation. Because of its good thermal conductivity and thermomechanical properties, ceramic substrates are widely used in the lining of power modules, which can effectively solve the heat dissipa...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23F1/34C23F1/36C23F1/32C09K13/00H01L21/48
CPCC23F1/34C23F1/36C23F1/32C09K13/00H01L21/4846
Inventor 王斌贺贤汉欧阳鹏孙泉葛荘戴洪兴
Owner 江苏富乐华半导体科技股份有限公司