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Polyamide film and preparation method thereof

A technology of polyamide film and polyamide resin, applied in the field of flexible packaging, can solve the problems of polyamide film toughness being difficult to meet requirements, material waste, etc.

Active Publication Date: 2020-09-18
HUNAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The existing method one is to thicken the polyamide layer, and the other is to improve the composition of the polyamide layer. Although the former method can meet the toughness requirements, it causes a waste of materials, so the latter method is usually used, such as patent CN103319883A describes a high-toughness polyamide, the mass percentage of the required proportioning substances is: polyamide: 60-70%, glass fiber: 20-40%, acrylate ultrafine particles: 2.00-5.00%, bisphenol A Epoxy resin: 1~3%
Although this method improves the toughness of polyamide to a certain extent, with the development of the outer packaging field, the requirements for the toughness of packaging materials are getting higher and higher, which makes it difficult for the toughness of the polyamide film improved by the predecessors to meet the requirements.

Method used

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  • Polyamide film and preparation method thereof
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preparation example Construction

[0071] The present invention also provides a preparation method for the polyamide film described in the above technical solution, comprising the following steps:

[0072] (1) The raw materials of the first surface layer, the first nylon layer, the core layer, the second nylon layer and the second surface layer are melted by respective extruders according to their respective proportions, and then co-extruded to obtain a melt;

[0073] (2) quenching the melt obtained in the step (1) on a chill roll to obtain an unstretched film slab;

[0074] (3) Stretching the unstretched film slab obtained in the step (2) synchronously to obtain a film;

[0075] (4) heat-setting the film obtained in the step (3) to obtain a polyamide film.

[0076] In the present invention, the raw materials of the first surface layer, the first nylon layer, the core layer, the second nylon layer and the second surface layer are melted through respective extruders according to their respective proportions, an...

Embodiment 1

[0086] The first surface layer is prepared from the raw materials of the following components: 85wt% nylon 6, 12wt% polyolefin grafted nylon 6 / 66 copolymer and 3wt% nylon masterbatch; the first nylon layer is prepared from the following components: 65wt% nylon 6, 25wt% combination additives and 10wt% nylon 66 / 610 / MXD6; Polymer obtained by in-situ copolymerization of soil removal; the second nylon layer is prepared from the raw materials of the following components: 55wt% nylon 66, 25wt% combined additives and 20wt% nylon 6I / 6T; the second surface layer is made of the following components Prepared: 87wt% nylon 66 / 6, 10wt% polyolefin grafted nylon 6 and 3wt% nylon masterbatch;

[0087] Among them, the combined additive is composed of a block copolymer composed of nylon 12 as the hard segment and polyether as the soft segment, and a core-shell structure copolymer with the core-acrylic ester as the shell of organosilicone rubber;

[0088] The nylon masterbatch is prepared from th...

Embodiment 2

[0096] The first surface layer is prepared from the raw materials of the following components: 80wt% nylon 610, 15wt% polyolefin grafted nylon 6 / 12 copolymer and 5wt% nylon masterbatch; the first nylon layer is prepared from the following components: 65wt% nylon 11, 20wt% combined additives and 15wt% nylon 66 / 610 / 6I; core material is 81.7wt% nylon 6, 12wt% nylon 66, 6wt% adipate polyether amine salt and 0.3wt% montmorillonite Polymer obtained by in-situ copolymerization of soil; the second nylon layer is prepared from the raw materials of the following components: 60wt% nylon MXD6, 20wt% combined additives and 20wt% nylon 6I / 6T; the second skin layer is prepared from the following components Obtain: 83wt% nylon 6, 12wt% polyolefin grafted nylon 6 / 66 / 610 and 5wt% nylon masterbatch;

[0097] Among them, the combined additive is composed of a block copolymer composed of nylon 11 as the hard segment and polyether as the soft segment, and a core-shell structure copolymer with the c...

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Abstract

The invention provides a polyamide film. The polyamide film sequentially comprises a first surface layer, a first nylon layer, a core layer, a second nylon layer and a second surface layer. The firstsurface layer and the second surface layer are independently prepared from the following raw materials: 77 wt%-87 wt% of polyamide resin, 10 wt%-15 wt% of a nylon graft copolymer and 3 wt%-8 wt% of anylon master batch. The first nylon layer and the second nylon layer are independently prepared from the following raw materials: 55 wt%-78 wt% of polyamide resin, 12 wt%-25 wt% of a combined additiveand 10 wt%-20 wt% of amorphous nylon. The core layer comprises a polymer formed by in-situ copolymerization of nylon 6, nylon 66, adipic acid polyether amine salt and montmorillonite. According to the polyamide film, multi-layer compounding is adopted, each layer adopts polyamide resin as a matrix which is matched with other components, so the toughness of the film is improved, and the cold stamping performance of the film is further improved.

Description

technical field [0001] The invention belongs to the technical field of flexible packaging, and in particular relates to a polyamide film and a preparation method thereof. Background technique [0002] Due to its advantages of miniaturization, thinness, light weight and large capacity, soft-pack lithium-ion batteries are favored in the fields of new energy vehicles and 3C digital consumer electronics products. At present, soft-pack lithium-ion batteries use aluminum-plastic composite film as their outer packaging material, which is mainly composed of five layers: an outer polyamide layer, an adhesive, an intermediate layer of aluminum foil, an adhesive, and an inner heat-sealing layer. [0003] With the continuous development of the pharmaceutical industry, the traditional blister packaging method is difficult to ensure that the quality of the drug will not change during its service life due to the limited barrier properties of the PVC hard sheet. In response to this problem...

Claims

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Application Information

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IPC IPC(8): B32B27/34B32B27/18B32B27/06B32B7/022B32B33/00B65D65/40C08L77/02C08L77/06C08L71/00C08L51/08C08L51/10C08L87/00C08K3/34C08J5/18B29C48/21B29C55/16B29C69/02B29L7/00
CPCB32B27/34B32B27/18B32B27/08B32B7/022B32B33/00B65D65/40C08J5/18B29C48/21B29C55/16B29C69/02B32B2307/558B32B2307/582B32B2377/00B32B2553/00C08J2377/02C08J2377/06C08J2477/06C08J2477/02C08J2471/00C08J2451/08C08J2451/10C08J2487/00C08K3/346B29L2007/00Y02E60/10
Inventor 林新土刘跃军范淑红刘小超石璞郑伟
Owner HUNAN UNIV OF TECH