Polyamide film and preparation method thereof
A technology of polyamide film and polyamide resin, applied in the field of flexible packaging, can solve the problems of polyamide film toughness being difficult to meet requirements, material waste, etc.
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[0071] The present invention also provides a preparation method for the polyamide film described in the above technical solution, comprising the following steps:
[0072] (1) The raw materials of the first surface layer, the first nylon layer, the core layer, the second nylon layer and the second surface layer are melted by respective extruders according to their respective proportions, and then co-extruded to obtain a melt;
[0073] (2) quenching the melt obtained in the step (1) on a chill roll to obtain an unstretched film slab;
[0074] (3) Stretching the unstretched film slab obtained in the step (2) synchronously to obtain a film;
[0075] (4) heat-setting the film obtained in the step (3) to obtain a polyamide film.
[0076] In the present invention, the raw materials of the first surface layer, the first nylon layer, the core layer, the second nylon layer and the second surface layer are melted through respective extruders according to their respective proportions, an...
Embodiment 1
[0086] The first surface layer is prepared from the raw materials of the following components: 85wt% nylon 6, 12wt% polyolefin grafted nylon 6 / 66 copolymer and 3wt% nylon masterbatch; the first nylon layer is prepared from the following components: 65wt% nylon 6, 25wt% combination additives and 10wt% nylon 66 / 610 / MXD6; Polymer obtained by in-situ copolymerization of soil removal; the second nylon layer is prepared from the raw materials of the following components: 55wt% nylon 66, 25wt% combined additives and 20wt% nylon 6I / 6T; the second surface layer is made of the following components Prepared: 87wt% nylon 66 / 6, 10wt% polyolefin grafted nylon 6 and 3wt% nylon masterbatch;
[0087] Among them, the combined additive is composed of a block copolymer composed of nylon 12 as the hard segment and polyether as the soft segment, and a core-shell structure copolymer with the core-acrylic ester as the shell of organosilicone rubber;
[0088] The nylon masterbatch is prepared from th...
Embodiment 2
[0096] The first surface layer is prepared from the raw materials of the following components: 80wt% nylon 610, 15wt% polyolefin grafted nylon 6 / 12 copolymer and 5wt% nylon masterbatch; the first nylon layer is prepared from the following components: 65wt% nylon 11, 20wt% combined additives and 15wt% nylon 66 / 610 / 6I; core material is 81.7wt% nylon 6, 12wt% nylon 66, 6wt% adipate polyether amine salt and 0.3wt% montmorillonite Polymer obtained by in-situ copolymerization of soil; the second nylon layer is prepared from the raw materials of the following components: 60wt% nylon MXD6, 20wt% combined additives and 20wt% nylon 6I / 6T; the second skin layer is prepared from the following components Obtain: 83wt% nylon 6, 12wt% polyolefin grafted nylon 6 / 66 / 610 and 5wt% nylon masterbatch;
[0097] Among them, the combined additive is composed of a block copolymer composed of nylon 11 as the hard segment and polyether as the soft segment, and a core-shell structure copolymer with the c...
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Abstract
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