A fluorescent copper nanocluster, its preparation method and its application
A nano-cluster and fluorescent copper technology, applied in the field of preparation and fluorescent copper nano-clusters, can solve the problems of poor water solubility and stability, and achieve the effects of good water solubility and stability, short reaction time and simple operation.
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Embodiment 1
[0049] First take a clean 25.0mL colorimetric tube, then add 2.0mL copper chloride (CuCl 2 , 1.0mM), 6.0mL polyvinylpyrrolidone (PVP 0.069mM), 6.0mL 2-mercaptobenzothiazole (MBT, 0.1mM) and 4.0mL ascorbic acid (Vc, 0.1mM), and dilute to the mark with ultrapure water and mix Homogenize, then place in an ultrasonic cleaner to seal the reaction. The reaction parameters were set as: 20°C, 60W, 20min, 80Uwl. After the reaction was completed, the reaction solution was transferred to a 30KDa ultrafiltration tube and centrifuged at 4500rpm for purification. The orange fluorescent copper nanoclusters were prepared and stored in a refrigerator at 4°C in the dark for future use. Synthesis schematic as figure 1 shown. figure 2 In order to change the amount of PVP, MBT, VC, reaction temperature, time, power and pH when preparing copper nanoclusters to determine the best reaction conditions. Depend on figure 2 It can be seen that the orange copper nanocluster solutions prepared unde...
Embodiment 2
[0050] Example 2 Stability test of polyvinylpyrrolidone-coated fluorescent copper nanoclusters (PVP-CuNCs)
[0051] In order to explore the stability of the prepared PVP-CuNCs, the effects of time effect, ultraviolet radiation effect and salt effect on the fluorescence intensity were studied respectively. Specifically:
[0052] Time effect: Store the PVP-CuNCs prepared under the optimal conditions in Example 1 in a 5.0mL EP tube, store them in a refrigerator at 4°C in the dark, and measure their excitation wavelength at 340nm and emission wavelength is the fluorescence spectrum at 580nm.
[0053] Ultraviolet radiation effect: The PVP-CuNCs prepared in Example 1 were placed in 12 tubes of 5.0mL EP tubes for different times of ultraviolet irradiation, and then their fluorescence spectra were measured at 340nm excitation wavelength and 580nm emission wavelength.
[0054] Salt effect: Dilute 0.2mL of PVP-CuNCs prepared under the optimal conditions in Example 1 with 1.8mL (0.05M,...
Embodiment 3
[0056] Example 3 UV and fluorescence characterization of polyvinylpyrrolidone-coated fluorescent copper nanoclusters (PVP-CuNCs)
[0057] In order to confirm whether PVP-CuNCs were successfully prepared, the PVP-CuNCs prepared in Example 1, CuCl 2 , PVP, MBT and Vc solutions, and measure the corresponding ultraviolet spectrum and fluorescence spectrum in a quartz cuvette.
[0058] Figure 4 A shows the ultraviolet absorption spectrum of the PVP-CuNCs prepared in Example 1. It can be observed from the figure that there is an ultraviolet absorption peak around 350nm, while the raw material has no absorption peak here. Figure 4 In B, under the excitation of 340nm, each reaction material has no fluorescence emission peak at 580nm, but PVP-CuNCs has an emission peak, which is fully separated from the spectral region where endogenous fluorescence occurs. The inset is a picture taken of PVP-CuNCs and each reaction raw material mixture under a UV lamp (λmax=365nm). It can be seen t...
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