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A Ni mesh-loaded graphene-tio 2 Preparation method of composite nanomaterial

A composite nanomaterial and graphene technology, applied in the field of graphene-TiO2 composite nanomaterial preparation, can solve the problem of inability to maintain catalyst specific surface area, high mechanical strength and high thermal stability, low combustion to CO2 selectivity ratio, and inability to guarantee Catalyst sintering and other problems, to achieve the effect of high catalytic removal efficiency, reduction of reaction activation energy, and improvement of service life

Active Publication Date: 2021-08-03
JIANGSU VOC ENVIRONMENTAL ENG CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The main purpose of the present invention is to provide a kind of graphene-TiO that supports nickel mesh 2 The preparation method of composite nanomaterials can effectively solve the problem of the existing oxide catalysts in the background technology. The activity is not high, and it cannot be applied to various organic waste gases. The selectivity of combustion to CO2 is low, the coating is not firm, and the active components It is easy to fall off. Due to the reason of the carrier, it cannot guarantee that the catalyst will not be sintered, and it cannot maintain the high activity specific surface area, high mechanical strength and high thermal stability of the catalyst.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A graphene-TiO supported nickel mesh 2 Composite nanomaterials, made of the following raw materials in weight percentage: 25% of noble metal oxides, 10% of clay, 5% of quartz, 5% of potassium albite feldspar, 30% of graphene, TiO 2 30% with nickel mesh, TiO 2 It has a three-dimensional ordered macroporous structure, the pore diameter of the macropores is 100nm, and the macropores are connected by 20nm pores, the pore size of the nickel mesh is 40 mesh, and the noble metal oxide can be Pt.

[0022] The present invention also provides a graphene-TiO loaded nickel mesh 2 A method for preparing a composite nanomaterial, comprising the steps of:

[0023] Step 1: Preparation of ceramic nickel mesh carrier: mix 10% clay, 5% quartz, and 5% potassium albite feldspar with water according to the above weight percentage ratio to form a mixture, spread evenly on the nickel mesh, and completely wrap the nickel mesh Then put it on the kiln to bake, so that the ceramic carrier is ba...

Embodiment 2

[0027] A graphene-TiO supported nickel mesh 2 Composite nanomaterials, made of the following raw materials in weight percentage: 30% of noble metal oxides, 15% of clay, 8% of quartz, 8% of potassium albite feldspar, 40% of graphene, TiO 2 35% with nickel mesh, TiO 2 It has a three-dimensional ordered macropore structure, the diameter of the macropores is 1 μm, and the macropores are connected by 60nm pores, the diameter of the nickel mesh is 50 mesh, and the noble metal oxide can be Pd.

[0028] The present invention also provides a graphene-TiO loaded nickel mesh 2 A method for preparing a composite nanomaterial, comprising the steps of:

[0029] Step 1: Preparation of ceramic nickel mesh carrier: mix clay 15%, quartz 8%, and potassium albite feldspar 8% according to the above weight percentage ratio, add water and stir to form a mixture, spread evenly on the nickel mesh, and completely wrap the nickel mesh Then put it on the kiln to bake, so that the ceramic carrier is ba...

Embodiment 3

[0033] A graphene-TiO supported nickel mesh 2 Composite nanomaterials, made of the following raw materials in weight percentage: 35% of noble metal oxides, 20% of clay, 10% of quartz, 10% of potassium albite feldspar, 50% of graphene, TiO 2 40% with nickel mesh, TiO 2 It has a three-dimensional ordered macroporous structure. The pore size of the macropores is 20 μm. The macropores are connected by 100 nm pores. The pore size of the nickel mesh is 60 mesh. The noble metal oxides can be Pt and Pd.

[0034] The present invention also provides a graphene-TiO loaded nickel mesh 2 A method for preparing a composite nanomaterial, comprising the steps of:

[0035] Step 1: Preparation of ceramic nickel mesh carrier: mix 20% clay, 10% quartz, and 10% potassium albite feldspar according to the above weight percentage ratio, add water and stir to form a mixture, evenly spread on the nickel mesh, and completely wrap the nickel mesh Then put it on the kiln to bake, so that the ceramic ca...

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Abstract

The invention discloses a graphene-TiO loaded with nickel mesh 2 Composite nanomaterials, made of the following raw materials in weight percentage: 25-35% of noble metal oxides, 10-20% of clay, 5-10% of quartz, 5-10% of potassium albite feldspar, and 30-50% of graphene %, TiO 2 30‑40% with nickel mesh. The present invention can ensure that the catalyst is not sintered by baking the ceramic carrier on the nickel net, and maintain the high activity specific surface area, high mechanical strength and high thermal stability of the catalyst, and at the same time add noble metal oxides, graphene and TiO to the catalyst 2 , the noble metal active sites have high dispersion and high catalytic activity. When the gel is loaded, the prepared ceramic nickel mesh carrier is first soaked in the first soaking sol, then dried, and then soaked in the second soaking sol, which can realize coating Strong, to ensure that the active components do not fall off, improve the service life, and the normal operating life is more than 3 years.

Description

technical field [0001] The invention relates to the field of oxide catalysts, in particular to a graphene-TiO loaded nickel mesh 2 Preparation methods of composite nanomaterials. Background technique [0002] Photocatalytic oxidation technology has been widely used in the field of VOCs waste gas treatment. The efficiency and stability of photocatalytic oxidation technology in the process of VOCs exhaust gas treatment are affected by many factors such as pollutant adsorption performance, photocatalytic oxidation contact time, humidity, catalyst activity, photon utilization efficiency, and catalyst attachment stability. [0003] In the treatment of VOCs, zeolite runners are usually used to condense low-concentration and large-volume organic waste gas into high-concentration and small-volume organic waste gas, thereby reducing equipment investment and operating costs, and realizing economical and effective organic waste gas treatment; CO furnace is a catalytic The oxidation r...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/89B01J37/02B01J35/10C04B33/13F23G7/07
CPCB01J23/8946B01J23/002B01J37/0205C04B33/13F23G7/07B01J2523/00C04B2235/3418C04B2235/3472C04B2235/656B01J35/40B01J35/61B01J2523/41B01J2523/47B01J2523/828B01J2523/824
Inventor 袁亮袁振
Owner JIANGSU VOC ENVIRONMENTAL ENG CO LTD
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