Production method of silicon carbide single crystal
A technology of silicon carbide single crystal and manufacturing method, applied in chemical instruments and methods, single crystal growth, single crystal growth and other directions, can solve the problems of slow growth speed and long time growth, etc.
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Embodiment 1
[0063] Under the following growth conditions, according to image 3 In the process shown, a SiC single crystal with a diameter of 100 mm is grown.
[0064]
[0065] Inner diameter of growth container 105mm
[0066] Seed crystal substrate··· SiC single crystal with a main surface of {0001} plane, a diameter of 100 mm (the diameter of the seed crystal substrate / the inner diameter of the growth vessel is 95%), and a maximum thickness of 8 mm including the end face of the growth ingot of a convex shape Substrate
[0067] Growth temperature···2200℃
[0068] Pressure···10Torr(13hPa)
[0069] Atmosphere...Argon, Nitrogen
[0070] After the SiC single crystal was grown, the straightness ratio (straight body portion / total length) was investigated, and the result was 90%. In addition, a multi-wire saw (multi-wire saw) is used to cut the wafer, and after grinding, mirror polishing and CMP polishing, observe the surface of the wafer, such as Figure 4 As shown, it can be judged that there is no he...
Embodiment 2
[0076] The SiC single crystal was grown under the same conditions as in Example 1, except that a seed crystal substrate with a diameter of 84 mm (the diameter of the seed crystal substrate / the inner diameter of the growth vessel was 80%) was used.
[0077] After the SiC single crystal was grown, the straightness ratio (straight body portion / total length) was investigated, and the result was 85%. After the SiC single crystal grows, the wafer is cut with a multi-wire saw, and after grinding, mirror polishing and CMP polishing, the surface of the wafer is observed, and it can be judged that there is no abnormal polytype. In addition, a total of five batches of manufacturing were carried out. The results are shown in Table 2. As shown in Table 2, none of the five batches produced allopolytypes (that is, the allopolytype generation rate was 0%).
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