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High-wear-resistance heat-conduction nylon composite material and preparation method thereof

A nylon composite material and high wear-resistant technology, applied in the field of nylon composite materials, can solve the problems that other properties of the material are not fundamentally improved, reduce the thermal conductivity of the material, etc. sexual effect

Active Publication Date: 2020-11-10
HENAN SHENMA HUAWEI PLASTIC CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In order to improve the surface corrosion resistance of thermally conductive materials, methods such as metallurgy and anti-corrosion coatings are usually used, but this method greatly reduces the thermal conductivity of the material and other properties of the material have not been fundamentally improved

Method used

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  • High-wear-resistance heat-conduction nylon composite material and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0028] A high wear-resistant and thermally conductive nylon composite material, which is composed of the following raw materials in parts by weight: 100 parts of nylon 6 resin, 10 parts of hydroxyl-terminated polydimethylsiloxane, an average outer diameter of 400nm, an average inner diameter of 320nm, mesoporous 15 parts of hollow porous carbon microspheres with a diameter of 45nm, 10 parts of nanometer β-silicon nitride with an average particle size of 20nm, 10 parts of nano-magnesia powder with an average particle size of 30nm, 10 parts of silicon-aluminum porous microspheres with an average particle size of 5 parts of 80nm nano-silicon carbide, 5 parts of nano-silicon dioxide with an average particle diameter of 80nm, 0.05 part of glyceryl stearate, and 0.05 part of 2,6-di-tert-butyl-p-cresol.

[0029] The preparation method of the above-mentioned high wear-resistant and thermally conductive nylon composite material comprises the following steps:

[0030] (1) Ultrasonic mix...

Embodiment 2

[0034] A high wear-resistant and thermally conductive nylon composite material, consisting of the following raw materials in parts by weight: 105 parts of nylon 66 resin, 12 parts of hydroxyl-terminated polydimethylsiloxane, with an average outer diameter of 430nm, an average inner diameter of 340nm, and mesoporous 20 parts of hollow porous carbon microspheres with a diameter of 48nm, 12 parts of nano-β-silicon nitride with an average particle size of 30nm, 12 parts of nano-magnesia powder with an average particle size of 40nm, 12 parts of silicon-aluminum porous microspheres with an average particle size of 8 parts of 150nm nano-silicon carbide, 8 parts of nano-silicon dioxide with an average particle diameter of 90nm, 0.04 part of butyl stearate, 0.04 part of methyl stearate, and 0.08 part of dilauryl alcohol ester.

[0035] The preparation method of the above-mentioned high wear-resistant and thermally conductive nylon composite material comprises the following steps:

[00...

Embodiment 3

[0040] A high wear-resistant and thermally conductive nylon composite material, which is composed of the following raw materials in parts by weight: 110 parts of nylon 6 resin, 15 parts of hydroxyl-terminated polydimethylsiloxane, an average outer diameter of 450nm, an average inner diameter of 350nm, mesoporous 25 parts of hollow porous carbon microspheres with a diameter of 50nm, 15 parts of nanometer β-silicon nitride with an average particle size of 50nm, 15 parts of nano-magnesia powder with an average particle size of 50nm, 15 parts of silicon-aluminum porous microspheres with an average particle size of 10 parts of 200nm nano-silicon carbide, 10 parts of nano-silicon dioxide with an average particle size of 100nm, 0.1 part of calcium stearate, and 0.1 part of phosphite.

[0041] The preparation method of the above-mentioned high wear-resistant and thermally conductive nylon composite material comprises the following steps:

[0042] (1) Ultrasonic mixing of hollow porous...

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Abstract

The invention discloses a high-wear-resistance heat-conduction nylon composite material, which is prepared from the following raw materials in parts by weight: 100-110 parts of nylon resin, 10-15 parts of hydroxyl-terminated polydimethylsiloxane, 15-25 parts of hollow porous carbon microspheres, 10-15 parts of nano beta-silicon nitride, 10-15 parts of nano magnesium oxide powder, 10-15 parts of silicon-aluminum porous microspheres, 5-10 parts of nano silicon carbide, 5-10 parts of nano silicon dioxide, 0.05-0.1 part of a lubricant and 0.05-0.1 part of an antioxidant, wherein the average outerdiameter of the hollow porous carbon microspheres is 400-450 nm, the average inner diameter of the hollow porous carbon microspheres is 320-350 nm, and the mesoporous diameter of the hollow porous carbon microspheres is 45-50 nm. According to the invention, the hollow porous carbon microspheres, the nano beta silicon nitride, the nano magnesium oxide powder and the hydroxyl-terminated polydimethylsiloxane are added into the nylon composite material to form a plurality of uniformly distributed heat-conducting channels, so that the uniform distribution of the heat-conducting filler is facilitated, and the heat-conducting property of the nylon composite material is improved; and silicon-aluminum porous microspheres, nano silicon carbide and nano silicon dioxide are added to enhance the wear resistance of the nylon composite material.

Description

technical field [0001] The invention relates to a nylon composite material, in particular to a high wear-resistant and thermally conductive nylon composite material. Background technique [0002] Thermally conductive materials are widely used in heat transfer engineering, electronic information engineering and other fields. For a long time, most heat-conducting materials are metal materials, but due to many factors such as poor corrosion resistance, poor processing performance, and low product design freedom of metal materials, its application range is limited. As an engineering plastic, nylon has excellent comprehensive properties such as good mechanical properties, good flexibility, wear resistance, oil resistance, and self-lubricating properties. There are many types of nylon products, including PA6, PA66, PA46, PA612, etc. , are widely used in the automotive industry, electronic and electrical industry, mechanical equipment, construction and other fields. [0003] Sinc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08L77/06C08L83/04C08K13/06C08K9/12C08K7/24C08K3/34C08K3/22C08K7/26C08K3/36C01B32/05
CPCC08L77/02C08L77/06C01B32/05C08K2201/011C08K2201/014C08K2003/222C08L83/04C08K13/06C08K9/12C08K7/24C08K3/34C08K3/22C08K7/26C08K3/36
Inventor 郭恒杰崔保平李联峰舒航黄铎徐宁顾可可熊伟谢县委
Owner HENAN SHENMA HUAWEI PLASTIC CO LTD