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Method for simultaneously improving corrosion resistance and heat resistance of aluminum-copper-magnesium alloy oil well pipe

A technology of corrosion resistance and heat resistance, which is applied in the field of simultaneously improving the corrosion resistance and heat resistance of aluminum-copper-magnesium alloy oil well pipes, can solve the problem of lack of heat resistance, etc. The effect of corrosion resistance

Active Publication Date: 2021-01-29
CENT SOUTH UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, 5000-series aluminum alloys do not have sufficient heat resistance, which is generally accepted

Method used

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  • Method for simultaneously improving corrosion resistance and heat resistance of aluminum-copper-magnesium alloy oil well pipe
  • Method for simultaneously improving corrosion resistance and heat resistance of aluminum-copper-magnesium alloy oil well pipe
  • Method for simultaneously improving corrosion resistance and heat resistance of aluminum-copper-magnesium alloy oil well pipe

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The alloy composition is: 3.6% Cu, 1.7% Mg, 0.6% Ag, 0.6% Mn, 0.05% Ti, the balance is Al, and the sum of each component is 100%, the alloy Cu / Mg is 2.12.

[0029] The preparation process of the alloy follows the following steps: (1) prepare the alloy ingot according to the above formula, the alloy melting temperature is 720 ° C, (2) the ingot is first kept at 400 ° C for 24 hours, and then the temperature is raised to 490 ° C for 24 hours, (3) remove the head, cut the tail, and mill the face of the ingot after the homogenization annealing, and hot-roll it into a 2mm thick plate after being kept at 430 ° C for 2 hours. 15%, or hot-extruded into rods or pipes after being kept at 430°C for 2 hours, and the extrusion ratio is ≥10; Hours later, it was quenched with water at room temperature, and then aged at 170°C for 3 hours.

[0030] According to the GB / T228.1-2010 national standard, room temperature and high temperature tensile tests and corrosion strength loss tests we...

Embodiment 2

[0033] The alloy composition is: 3.8% Cu, 1.6% Mg, 0.5% Ag, 0.6% Mn, 0.05% Ti, the balance is Al, and the sum of each component is 100%, the alloy Cu / Mg is 2.38.

[0034]The preparation process of the alloy follows the following steps: (1) prepare the alloy ingot according to the above formula, the alloy melting temperature is 750 ° C, (2) the ingot is first kept at 400 ° C for 24 hours, and then the temperature is raised to 480 ° C for 36 hours, (3) Remove the head, cut the tail, and mill the face of the ingot after homogenization annealing, and heat it at 440°C for 1.5h, and then hot-roll it into a plate with a thickness of 2mm. 40%, or hot-extruded into rods or pipes after heat preservation at 440°C for 1.5 hours, with an extrusion ratio of ≥10; After 0.5 hour, water quenching, and aging at 180°C for 2 hours.

[0035] According to the GB / T228.1-2010 national standard, room temperature and high temperature tensile tests and corrosion strength loss tests were carried out on ...

Embodiment 3

[0038] The alloy composition is: 4.0% Cu, 1.5% Mg, 0.45% Ag, 0.6% Mn, 0.05% Ti, the balance is Al, and the sum of each component is 100%, the alloy Cu / Mg is 2.67.

[0039] The preparation process of the alloy follows the following steps: (1) prepare the alloy ingot according to the above formula, the alloy melting temperature is 725 ° C, (2) the ingot is first kept at 400 ° C for 24 hours, and then the temperature is raised to 470 ° C for 36 hours, (3) remove the head, cut the tail, and mill the face of the ingot after the homogenization annealing, and hot-roll it into a 2mm thick plate after being kept at 450°C for 1h. 20%, or hot-extruded into rods or pipes after heat preservation at 450°C for 1 hour, with an extrusion ratio of ≥10; After 1 hour, it was quenched in water, and then aged at 190°C for 1 hour.

[0040] According to the GB / T228.1-2010 national standard, room temperature and high temperature tensile tests and corrosion strength loss tests were carried out on the ...

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Abstract

The invention discloses a method for simultaneously improving corrosion resistance and heat resistance of an aluminum-copper-magnesium alloy oil well pipe. The corrosion resistance of an alloy is greatly improved by greatly reducing the mass ratio of Cu to Mg in an Al-Cu-Mg alloy and adopting an alloying method of adding a trace amount of Ag element for reducing the potential difference between amatrix and a second phase. Meanwhile, a composite addition alloying method of various dispersed phase forming elements (Mn, Zr, Ti and Cr) is adopted, and a proper secondary homogenizing annealing, hot rolling or hot extrusion deformation processing method is matched, so that a uniform dispersed phase and a small-angle low-energy grain boundary are formed, and the corrosion resistance of the Al-Cu-Mg alloy is improved. Meanwhile, the added trace Ag element is dissolved into the S'phase to improve the thermal stability of the alloy, and the heat resistance of the alloy is improved together withthe dispersed phase separated out in the homogenization stage. Finally, the prepared novel corrosion-resistant heat-resistant aluminum alloy is comparable with 6061 alloy in corrosion resistance, hashigh thermal strength, and is suitable for oil well pipes for oil drilling and production operation and other industrial applications.

Description

technical field [0001] The invention relates to the technical field of oil well pipes, in particular to a method for simultaneously improving the corrosion resistance and heat resistance of an aluminum-copper-magnesium alloy oil well pipe. Background technique [0002] Acid fracturing technology is the most common method used in the oil and gas development process. With the development of the petroleum industry, the number of deep wells, ultra-deep wells, high-sulfur wells and horizontal wells is increasing, and the working conditions are becoming more and more complicated. Traditional steel OCTG cannot realize the cost and time of safety operation and workover brought by workover operations such as later secondary reconstruction or sidetracking, and later salvage tubing. The aluminum alloy tubing has good drillability (or solubility), which can better solve this problem. However, in the environment of deep wells and ultra-deep wells, aluminum alloys are required to have bo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C21/16C22C1/02C22F1/057
CPCC22C1/026C22C21/16C22F1/057
Inventor 刘志义贾鹏翔颜鹏飞郭帅柏松
Owner CENT SOUTH UNIV