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Three-zone parallel co-control multistage catalytic cracking method according to raw material types

A technology for catalytic cracking and raw materials, applied in catalytic cracking, chemical instruments and methods, molecular sieve catalysts, etc., can solve the problems of high dry gas and coke yield, complex cracking products, unfavorable industrial applications, etc., to reduce dry gas and coke. Yield, improve conversion rate, improve the effect of utilization rate

Inactive Publication Date: 2021-02-05
CHINA UNIV OF PETROLEUM (BEIJING)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

More importantly, this method requires the use of different catalysts to participate in the cracking reaction in the first riser reactor and the second riser reactor, so different regeneration paths need to be set when regenerating the reacted catalyst , the installation is complicated, which is not conducive to industrial application
[0010] At present, most of the catalytic cracking research focuses on heavy oil feedstocks, or catalytic cracking of light hydrocarbon (gasoline) feedstocks at the same time, but the cracking products are complex and the propylene selectivity is low, and in the process of pursuing relatively high propylene selectivity, it will also lead to The yield of dry gas and coke is relatively high, which is still a common problem that is difficult to overcome

Method used

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  • Three-zone parallel co-control multistage catalytic cracking method according to raw material types
  • Three-zone parallel co-control multistage catalytic cracking method according to raw material types
  • Three-zone parallel co-control multistage catalytic cracking method according to raw material types

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Experimental program
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Effect test

preparation example Construction

[0090] In the preparation of the catalyst, too much or too little loading of non-metal elements and metal elements will affect the catalytic effect of the catalyst. For example, if the loading of metal elements / non-metal elements is too much, the dispersion is not good, and it is easy to gather at the pores of the catalyst and coke. If the loading of metal elements / non-metal elements is too small, even if the catalytic reaction time is extended, the expected catalytic effect cannot be achieved. Therefore, the loading amount of each metalloid element in the catalyst is about 0.05-5 wt%, and the loading amount of each metal element is about 0.1-10 wt%, both based on the mass of the catalyst.

[0091] When carrying out non-metal modification and metal modification, regardless of the order, hydrothermal treatment is required between the second type of modification to dredge the molecular sieve channel and facilitate the loading of the next type of modifying elements. The conditio...

Embodiment 1

[0110] figure 1 It is a schematic diagram of a three-zone parallel coordinated multi-stage catalytic cracking system according to feedstock type according to an embodiment of the present invention. Such as figure 1 As shown, the system includes a first riser 1 , a second riser 2 , a third riser 3 , a fluidized bed reactor 4 , a regenerator 5 and a supplementary heat generator 6 outside the regenerator 5 . Wherein, the outlet of the first riser 1, the outlet of the second riser 2 and the outlet of the third riser 3 are respectively communicated with the inlet of the fluidized bed reactor 4 through pipelines, and the outlet of the spent catalyst of the fluidized bed reactor 4 is It is connected with the standby catalyst inlet of the regenerator 5 through a pipeline, the standby catalyst outlet of the regenerator 5 is connected with the standby catalyst inlet of the supplementary heater 6 through the standby catalyst delivery pipeline, and the pre-combustion catalyst outlet of t...

Embodiment 2

[0122] figure 2 It is a schematic diagram of a three-zone parallel coordinated multi-stage catalytic cracking system according to feedstock type according to another embodiment of the present invention. Such as figure 2 As shown, the system of this embodiment and figure 1 The difference of the shown system is that the regenerated catalyst outlet of the regenerator 5 is not only communicated with the inlets of the first riser 1, the second riser 2 and the third riser 3, but also communicated with the inlet of the fluidized bed reactor 4 , used to input and return the regenerated catalyst a to the first riser 1 , the second riser 2 , the third riser 3 and the fluidized bed reactor 4 for recycling.

[0123] use figure 2 The difference between the method shown in the system for catalytic cracking of light hydrocarbons and that of Example 1 is that the regenerated catalyst a in the regenerator 5 is returned to the first riser 1 and the second riser 2 respectively through the ...

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Abstract

The invention provides a three-zone parallel co-control multistage catalytic cracking method according to raw material types, the raw materials comprise a first raw material rich in C4 hydrocarbon, asecond raw material rich in C5-C6 hydrocarbon and a third raw material rich in C7-C8 hydrocarbon, a reaction device comprising a first lifting pipe, a second lifting pipe and a third lifting pipe is adopted, and the method comprises the following steps: enabling the first raw material to enter the first lifting pipe for a first catalytic cracking reaction; enabling the second raw material to enterthe second lifting pipe for a second catalytic cracking reaction; enabling the third raw material to enter the third lifting pipe for a third catalytic cracking reaction; carrying out gas-solid separation on the reactant flows from the first lifting pipe, the second lifting pipe and the third lifting pipe to obtain an oil-gas product and a spent catalyst; and enabling the spent catalyst to be subjected to steam stripping and regeneration, and then returning thespent catalyst to participate in each catalytic cracking reaction. According to the cracking characteristics of various hydrocarbon raw materials, the cracking process is adjusted, so that different light hydrocarbon raw materials are cracked by using one system, and the production of high-yield light olefins is realized.

Description

technical field [0001] The invention relates to a catalytic cracking method for light hydrocarbons, in particular to a three-zone parallel coordinated multi-stage catalytic cracking method according to raw material types, belonging to the technical field of petroleum processing. Background technique [0002] With the improvement of technology and production capacity, the trend of excess oil refining and supply capacity has emerged. Taking my country as an example, in 2018, the oil refining capacity reached 840 million tons, processed crude oil 610 million tons, produced a total of 364 million tons of gasoline, diesel and kerosene, and the average operating load was 7.24 billion tons. %, it is expected that there will be a surplus of 110 million tons in 2020. At the same time, with the further stringent environmental protection requirements, the development of new energy represented by electricity, hydrogen energy, and biofuels, and the improvement of vehicle fuel efficiency, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G11/06C10G11/18B01J29/48B01J29/16
CPCC10G11/06C10G11/182C10G11/187B01J29/48B01J29/166C10G2400/20
Inventor 赵亮白宇恩高金森郝天臻张宇豪孟庆飞徐春明李德忠
Owner CHINA UNIV OF PETROLEUM (BEIJING)