Nano-composite coating liquid for fertilizer, coated controlled-release fertilizer and preparation method of coated controlled-release fertilizer

A coated controlled-release fertilizer and nano-composite technology, which is applied in fertilizer mixtures, layered/coated fertilizers, solid/semi-solid fertilizers, etc., can solve the problem that the average utilization rate of chemical fertilizers is less than 40%, which limits large-scale promotion and application. The complex price of membrane materials and other issues can achieve the effect of shortening the preparation time, uniform size and reducing dependence

Inactive Publication Date: 2021-02-12
SOUTH SUBTROPICAL CROPS RES INST CHINESE ACAD OF TROPICAL AGRI SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

According to statistics, the role of chemical fertilizers in increasing crop yields accounts for 40%-60%. my country is a country with a large production capacity of chemical fertilizers and a large consumption of chemical fertilizers, but the average utilization rate of chemical fertilizers in the current season is less than 40%.
[0003] The advent of coated controlled-release fertilizers solves the above two problems at the same time. However, the complicated process and high-cost raw materials of the coated materials make it expensive. At present, it can only be used on high-value lawns and flowers, and has not been widely used. Another major reason is that the residual film of traditional coated controlled-release fertilizers cannot be degraded, which will cause secondary pollution to the environment
[0004] Although there are some studies on the use of degradable natural polymer materials as fertilizer coating materials, natural polymer materials are easily affected by the environment, so they are easily degraded, and the controlled release performance of fertilizers is poor. The mechanical properties of the material-coated fertilizer are not strong, the core fertilizer dissolves and easily forms a high pressure in the film, and the film material cannot withstand the pressure in the film and easily forms cracks or ruptures to release the fertilizer quickly, thus limiting its large-scale application

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] (1) Preparation of coating solution

[0036] Pulverize 50g of rice straw, pass through a 30-mesh sieve, mix it with 500g of liquefier (300g of polyethylene glycol 400 and 200g of glycerol), 2g of 3% concentrated sulfuric acid, and heat at 150°C for 1 hour , cooled to room temperature to obtain straw liquefaction;

[0037] 3.6 g of straw liquefaction, 0.12 g of halloysite nanotubes and 6.6 g of isophorone diisocyanate were uniformly mixed and solidified to obtain a coating solution.

[0038] (2) Preparation of coated controlled-release fertilizer

[0039] 1kg urea granule fertilizer is preheated 10min under the condition of 50 ℃, then under the magnetic field effect of 6000 gauss, account for the addition of 1% of fertilizer granule weight according to coating agent, the coating solution prepared in step (1) is sprayed on After the surface of the preheated granular fertilizer was heated at 75°C for 4 minutes, 1 drop of dibutyltin dilaurate was added dropwise for curing...

Embodiment 2

[0042] (1) Preparation of coating solution

[0043] 80g of corn stalks were pulverized and passed through a 30-mesh sieve, mixed evenly with 150g of liquefier (120g of polyethylene glycol 600 and 30g of glycerol), 1.5g of 3% concentrated hydrochloric acid, and heated at 130°C for 2 hours, cooled to room temperature to obtain straw liquefaction;

[0044] Mix 3g of straw liquefaction, 0.08g of oyster shell powder and 6.2g of diphenylmethane diisocyanate evenly, and solidify to obtain the coating solution.

[0045] (2) Preparation of coated controlled-release fertilizer

[0046] 1kg of urea granule fertilizer was preheated at 75°C for 8min, then under the action of a magnetic field of 8000 gauss, according to the addition of the coating agent accounting for 7% of the weight of the fertilizer granules, the coating solution prepared in step (1) was sprayed onto the After the surface of the preheated granular fertilizer was heated at 50°C for 5 minutes, 1 drop of dibutyltin dilaur...

Embodiment 3

[0049] (1) Preparation of coating solution

[0050] 100g of peanut stalks were pulverized and passed through a 30-mesh sieve, mixed evenly with 300g of liquefier (160g of ethylene carbonate and 140g of ethylene glycol), 3g of 3% concentrated hydrochloric acid, heated and reacted at 120°C for 2.3 hours, cooled to room temperature to obtain straw liquefaction;

[0051] Mix 3.2g of straw liquefaction, 0.1g of montmorillonite and 6.4g of PM-200 evenly, and solidify to obtain the coating solution.

[0052] (2) Preparation of coated controlled-release fertilizer

[0053]Preheat 1 kg of potassium dihydrogen phosphate granule fertilizer at 65°C for 9 minutes, then under the action of a magnetic field of 8000 gauss, according to the addition of coating agent accounting for 5% of the weight of the fertilizer granules, the coating prepared in step (1) is Spray the solution onto the surface of the preheated granular fertilizer, heat it at 65°C for 6 minutes, add 1 drop of dibutyltin dil...

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PUM

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Abstract

The invention discloses a nano-composite coating liquid for a fertilizer, a coated controlled-release fertilizer and a preparation method of the coated controlled-release fertilizer, and belongs to the field of fertilizer preparation. The coating liquid is prepared from the following raw materials in parts by mass: 30-36 parts of liquefied straw, 0.8-1.2 parts of a natural nano material and 62-66parts of a curing agent. According to the invention, under the action of an external magnetic field, the coating liquid is sprayed onto the surface of preheated granular fertilizer, coating treatmentis performed at 50-75 DEG C, and curing is performed to obtain the coated controlled-release fertilizer; and the coated controlled-release fertilizer prepared by the method has excellent mechanical properties, the coating material has a proper degradation period, the fertilizer has excellent controlled-release performance, and the coated controlled-release fertilizer is wide in raw material sourceand simple in preparation process, and has important popularization significance in the aspect of controlled-release fertilizers.

Description

technical field [0001] The invention relates to the technical field of fertilizer preparation, in particular to a nanocomposite coating liquid for fertilizer, coated controlled-release fertilizer and a preparation method thereof. Background technique [0002] Fertilizer is an important means of production to ensure the increase of output in agricultural production. With the increasing food demand of human beings, the amount of chemical fertilizer is also increasing. According to statistics, the role of chemical fertilizers in increasing crop yields accounts for 40%-60%. my country is a country with a large production capacity of chemical fertilizers and a large consumption of chemical fertilizers, but the average utilization rate of chemical fertilizers in the current season is less than 40%. The low fertilizer utilization rate not only wastes resources, but also causes serious pollution to the environment. Therefore, there is an urgent need to develop a new type of green f...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05G3/40C05G5/30C05G5/12
CPCC05G3/40C05G5/12C05G5/30
Inventor 王超李普旺杜丽清谢江辉杨子明宋书会阮湘梅刘运浩何祖宇周闯
Owner SOUTH SUBTROPICAL CROPS RES INST CHINESE ACAD OF TROPICAL AGRI SCI
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