Nano-composite coating liquid for fertilizer, coated controlled-release fertilizer and preparation method of coated controlled-release fertilizer
A coated controlled-release fertilizer and nano-composite technology, which is applied in fertilizer mixtures, layered/coated fertilizers, solid/semi-solid fertilizers, etc., can solve the problem that the average utilization rate of chemical fertilizers is less than 40%, which limits large-scale promotion and application. The complex price of membrane materials and other issues can achieve the effect of shortening the preparation time, uniform size and reducing dependence
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Embodiment 1
[0035] (1) Preparation of coating solution
[0036] Pulverize 50g of rice straw, pass through a 30-mesh sieve, mix it with 500g of liquefier (300g of polyethylene glycol 400 and 200g of glycerol), 2g of 3% concentrated sulfuric acid, and heat at 150°C for 1 hour , cooled to room temperature to obtain straw liquefaction;
[0037] 3.6 g of straw liquefaction, 0.12 g of halloysite nanotubes and 6.6 g of isophorone diisocyanate were uniformly mixed and solidified to obtain a coating solution.
[0038] (2) Preparation of coated controlled-release fertilizer
[0039] 1kg urea granule fertilizer is preheated 10min under the condition of 50 ℃, then under the magnetic field effect of 6000 gauss, account for the addition of 1% of fertilizer granule weight according to coating agent, the coating solution prepared in step (1) is sprayed on After the surface of the preheated granular fertilizer was heated at 75°C for 4 minutes, 1 drop of dibutyltin dilaurate was added dropwise for curing...
Embodiment 2
[0042] (1) Preparation of coating solution
[0043] 80g of corn stalks were pulverized and passed through a 30-mesh sieve, mixed evenly with 150g of liquefier (120g of polyethylene glycol 600 and 30g of glycerol), 1.5g of 3% concentrated hydrochloric acid, and heated at 130°C for 2 hours, cooled to room temperature to obtain straw liquefaction;
[0044] Mix 3g of straw liquefaction, 0.08g of oyster shell powder and 6.2g of diphenylmethane diisocyanate evenly, and solidify to obtain the coating solution.
[0045] (2) Preparation of coated controlled-release fertilizer
[0046] 1kg of urea granule fertilizer was preheated at 75°C for 8min, then under the action of a magnetic field of 8000 gauss, according to the addition of the coating agent accounting for 7% of the weight of the fertilizer granules, the coating solution prepared in step (1) was sprayed onto the After the surface of the preheated granular fertilizer was heated at 50°C for 5 minutes, 1 drop of dibutyltin dilaur...
Embodiment 3
[0049] (1) Preparation of coating solution
[0050] 100g of peanut stalks were pulverized and passed through a 30-mesh sieve, mixed evenly with 300g of liquefier (160g of ethylene carbonate and 140g of ethylene glycol), 3g of 3% concentrated hydrochloric acid, heated and reacted at 120°C for 2.3 hours, cooled to room temperature to obtain straw liquefaction;
[0051] Mix 3.2g of straw liquefaction, 0.1g of montmorillonite and 6.4g of PM-200 evenly, and solidify to obtain the coating solution.
[0052] (2) Preparation of coated controlled-release fertilizer
[0053]Preheat 1 kg of potassium dihydrogen phosphate granule fertilizer at 65°C for 9 minutes, then under the action of a magnetic field of 8000 gauss, according to the addition of coating agent accounting for 5% of the weight of the fertilizer granules, the coating prepared in step (1) is Spray the solution onto the surface of the preheated granular fertilizer, heat it at 65°C for 6 minutes, add 1 drop of dibutyltin dil...
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