Fluorinated aliphatic ring structure epoxy resin and preparation method thereof
A technology of epoxy resin and fluorinated fat, which is applied in the direction of coating, etc., can solve the problems of unsatisfactory water absorption and dielectric constant, difficult and fast microelectronic packaging field, low UV radiation curing activity, etc., and achieve short preparation route , easy to operate, fast curing effect
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Embodiment 1
[0038] A fluorinated alicyclic structure epoxy resin, calculated in parts by weight, its composition and content are as follows:
[0039]
[0040] Wherein, the acrylate monomer is a mixture of methyl acrylate and butyl acrylate in a mass ratio of 2:1.
[0041] The cycloaliphatic epoxy acrylate compound is provided by Jiangsu Taitel Chemical Co., Ltd.;
[0042] Described glycidyl methacrylate is provided by Nanjing Lanbai Chemical Co., Ltd.;
[0043] Described solvent is ethyl acetate;
[0044] The initiator is dibenzoyl peroxide.
[0045] The preparation method of above-mentioned fluorinated aliphatic ring structure epoxy resin, the steps are as follows:
[0046] Add the solvent into a 500mL four-necked flask equipped with a stirring blade, a condenser tube, a dropping funnel, and a thermometer, and shrink the fluorinated acrylate, acrylate monomer, alicyclic epoxy acrylate compound, and methacrylic acid Add the mixed monomers of glyceride dropwise into the four-necked ...
Embodiment 2
[0051] A fluorinated alicyclic structure epoxy resin, calculated in parts by weight, its composition and content are as follows:
[0052]
[0053] Wherein, the acrylate monomer is a mixture of methyl acrylate and butyl acrylate in a mass ratio of 5:5.
[0054] The cycloaliphatic epoxy acrylate compound is provided by Jiangsu Taitel Chemical Co., Ltd.;
[0055] Described glycidyl methacrylate is provided by Nanjing Lanbai Chemical Co., Ltd.;
[0056]Described solvent is the mixture of ethyl acetate and butanone by volume ratio 1:1;
[0057] The initiator is azobisisobutyronitrile.
[0058] The preparation method of above-mentioned fluorinated aliphatic ring structure epoxy resin, the steps are as follows:
[0059] Add the solvent into a 500mL four-necked flask equipped with a stirring blade, a condenser tube, a dropping funnel, and a thermometer, and shrink the fluorinated acrylate, acrylate monomer, alicyclic epoxy acrylate compound, and methacrylic acid Add the mixed m...
Embodiment 3
[0064] A fluorinated alicyclic structure epoxy resin, calculated in parts by weight, its composition and content are as follows:
[0065]
[0066] Wherein, the acrylate monomer is a mixture of methyl acrylate and butyl acrylate in a mass ratio of 5:5.
[0067] The cycloaliphatic epoxy acrylate compound is provided by Jiangsu Taitel Chemical Co., Ltd.;
[0068] Described glycidyl methacrylate is provided by Nanjing Lanbai Chemical Co., Ltd.;
[0069] Described solvent is the mixture of ethyl acetate and butanone by volume ratio 1:1;
[0070] The initiator is azobisisobutyronitrile.
[0071] The preparation method of above-mentioned fluorinated aliphatic ring structure epoxy resin, the steps are as follows:
[0072] Add the solvent into a 1000mL four-necked flask equipped with a stirring blade, a condenser, a dropping funnel, and a thermometer, and shrink the fluorinated acrylate, acrylate monomer, alicyclic epoxy acrylate compound, and methacrylic acid Add the mixed mono...
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