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Fluorinated aliphatic ring structure epoxy resin and preparation method thereof

A technology of epoxy resin and fluorinated fat, which is applied in the direction of coating, etc., can solve the problems of unsatisfactory water absorption and dielectric constant, difficult and fast microelectronic packaging field, low UV radiation curing activity, etc., and achieve short preparation route , easy to operate, fast curing effect

Active Publication Date: 2021-03-19
SHANGHAI INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Epoxy resin refers to a resin containing two or more epoxy groups in its molecule. Due to its good heat resistance, solvent resistance, physical, mechanical and electrical insulation properties, and good adhesion to various materials , Good chemical stability and widely used as adhesives, coatings, resin-based composite materials, widely used in the field of electronic packaging, but its water absorption and dielectric constant are not ideal, the dielectric constant value is 3 to 4, And the usual epoxy resin is bisphenol A type epoxy resin, because UV radiation curing activity is low, and it is difficult to meet the rapid microelectronic packaging field.

Method used

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  • Fluorinated aliphatic ring structure epoxy resin and preparation method thereof
  • Fluorinated aliphatic ring structure epoxy resin and preparation method thereof
  • Fluorinated aliphatic ring structure epoxy resin and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0038] A fluorinated alicyclic structure epoxy resin, calculated in parts by weight, its composition and content are as follows:

[0039]

[0040] Wherein, the acrylate monomer is a mixture of methyl acrylate and butyl acrylate in a mass ratio of 2:1.

[0041] The cycloaliphatic epoxy acrylate compound is provided by Jiangsu Taitel Chemical Co., Ltd.;

[0042] Described glycidyl methacrylate is provided by Nanjing Lanbai Chemical Co., Ltd.;

[0043] Described solvent is ethyl acetate;

[0044] The initiator is dibenzoyl peroxide.

[0045] The preparation method of above-mentioned fluorinated aliphatic ring structure epoxy resin, the steps are as follows:

[0046] Add the solvent into a 500mL four-necked flask equipped with a stirring blade, a condenser tube, a dropping funnel, and a thermometer, and shrink the fluorinated acrylate, acrylate monomer, alicyclic epoxy acrylate compound, and methacrylic acid Add the mixed monomers of glyceride dropwise into the four-necked ...

Embodiment 2

[0051] A fluorinated alicyclic structure epoxy resin, calculated in parts by weight, its composition and content are as follows:

[0052]

[0053] Wherein, the acrylate monomer is a mixture of methyl acrylate and butyl acrylate in a mass ratio of 5:5.

[0054] The cycloaliphatic epoxy acrylate compound is provided by Jiangsu Taitel Chemical Co., Ltd.;

[0055] Described glycidyl methacrylate is provided by Nanjing Lanbai Chemical Co., Ltd.;

[0056]Described solvent is the mixture of ethyl acetate and butanone by volume ratio 1:1;

[0057] The initiator is azobisisobutyronitrile.

[0058] The preparation method of above-mentioned fluorinated aliphatic ring structure epoxy resin, the steps are as follows:

[0059] Add the solvent into a 500mL four-necked flask equipped with a stirring blade, a condenser tube, a dropping funnel, and a thermometer, and shrink the fluorinated acrylate, acrylate monomer, alicyclic epoxy acrylate compound, and methacrylic acid Add the mixed m...

Embodiment 3

[0064] A fluorinated alicyclic structure epoxy resin, calculated in parts by weight, its composition and content are as follows:

[0065]

[0066] Wherein, the acrylate monomer is a mixture of methyl acrylate and butyl acrylate in a mass ratio of 5:5.

[0067] The cycloaliphatic epoxy acrylate compound is provided by Jiangsu Taitel Chemical Co., Ltd.;

[0068] Described glycidyl methacrylate is provided by Nanjing Lanbai Chemical Co., Ltd.;

[0069] Described solvent is the mixture of ethyl acetate and butanone by volume ratio 1:1;

[0070] The initiator is azobisisobutyronitrile.

[0071] The preparation method of above-mentioned fluorinated aliphatic ring structure epoxy resin, the steps are as follows:

[0072] Add the solvent into a 1000mL four-necked flask equipped with a stirring blade, a condenser, a dropping funnel, and a thermometer, and shrink the fluorinated acrylate, acrylate monomer, alicyclic epoxy acrylate compound, and methacrylic acid Add the mixed mono...

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Abstract

The invention discloses fluorinated aliphatic ring structure epoxy resin and a preparation method thereof. The epoxy resin comprises the following raw materials: an acrylate monomer, fluorinated acrylate, an alicyclic epoxy acrylate compound, glycidyl methacrylate, an initiator and a solvent. The preparation method comprises the following steps of: mixing the acrylate monomer, the fluorinated acrylate, the alicyclic epoxy acrylate compound and the glycidyl methacrylate, dropwise adding the mixture into the solvent, and heating an obtained solution to 70-80 DEG C to obtain a mixture; dropwise adding the initiator into the mixture,carrying out a reaction while performing stirring, and heating to continue the reaction, thereby obtaining the fluorinated aliphatic ring structure epoxy resin. The fluorinated aliphatic ring structure epoxy resin has a UV rapid curing capability; a cured product has a low dielectric constant; and the fluorinated aliphatic ring structure epoxy resin can be widely applied to a super-large-scale integrated circuit process;.

Description

technical field [0001] The invention relates to a fluorinated aliphatic ring structure epoxy resin and a preparation method thereof, belonging to the technical field of polymer materials. Background technique [0002] The integration of integrated circuit components continues to increase, and the feature size continues to shrink, especially when the line width is reduced to sub-micron size. The corresponding signal delay and crosstalk between signals have become the bottleneck problem that limits the overall performance of the integrated circuit. The greatest challenge to connection reliability. In the traditional process, aluminum is used as metal interconnection and SiO 2 The resistance-capacitance interconnection delay brought by the interconnection metal dielectric layer is already greater than the gate delay of the signal itself. The parasitic capacitance effect between metal lines can be reduced by using low dielectric constant materials. Low dielectric constant inte...

Claims

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Application Information

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IPC IPC(8): C08F220/32C08F220/14C08F220/18C08F220/22C09D133/14
CPCC08F220/32C09D133/068C08F220/14C08F220/1804C08F220/22C08F220/325
Inventor 高楠张英强王晓瑞
Owner SHANGHAI INST OF TECH